Citation: Wang Chen, Chen Rui, Song Lin, Zhang Naidong. Characteristics of Some Typical Inorganic Oxyacid Free Radicals[J]. Acta Chimica Sinica, ;2019, 77(3): 205-212. doi: 10.6023/A18120486 shu

Characteristics of Some Typical Inorganic Oxyacid Free Radicals

Wang Chen ^a ,
Chen Rui ^a ,
Song Lin ^a ,
Zhang Naidong ^a,b,,

a.
College of Environmental Science and Engineering, Dalian Maritime University, Dalian 116026, China
b.
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China

Corresponding author: Zhang Naidong, zhangnd@aliyun.com
Received Date: 6 December 2018
Available Online: 13 March 2019
Fund Project: the Open Project of the State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology QAK201503the National Natural Science Foundation of China 21673061Project supported by the National Natural Science Foundation of China (No. 21673061) and the Open Project of the State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (No. QAK201503)

Figures(2)

Carbonate radical, nitrate radical, phosphate radical and sulfate radical are all important intermediates of chemical reactions with oxidizing ability. They have a significant effect on the transfer of pollutants in natural environment. In this review, the redox potential, modes of production, detection methods of these radicals and the mechanisms of their reactions with organic compounds are introduced. It can be found that:these four radicals have different reaction rates with organic compounds because of their various redox potential; Carbonate radical is not a scavenger of hydroxyl radical. For some easily oxidized compounds, carbonate radical shows higher oxidizing ability than hydroxyl radical; Hydroxyl radicals can be converted into other four types of radicals. Meanwhile, these four types of radicals react with organic matters by electron transfer, hydrogen abstraction and addition, which is basically consistent with hydroxyl radicals. It can be predicted that the mechanism of organic compounds degradation by these four types of free radicals is similar with that of hydroxyl radicals. In the future, it is necessary to study the mutual conversion principles between these free radicals and hydroxyl radicals and the degradation mechanism of these radicals when reacting with some representative organic compounds.
- carbonate radical,
- nitrate radical,
- phosphate radical,
- sulfate radical,
- hydroxyl radical
1. [1]
  Stenman, D.; Carlsson, M.; Reitberger, T. J. Wood. Chem. Technol. 2005, 24, 83. doi: 10.1081/WCT-200026553
2. [2]
  Canonica, S.; Kohn, T.; Mac, M.; Real, F. J.; Wirz, J.; Von, G. U. Environ. Sci. Technol. 2005, 39, 9182. doi: 10.1021/es051236b
3. [3]
  Dell'Arciprete, M. L.; Soler, J. M.; Santos-Juanes, L.; Arques, A.; Mártire, D. O.; Furlong, J. P.; Gonzalez, M. C. Water Res. 2012, 46, 3479. doi: 10.1016/j.watres.2012.03.051
4. [4]
  Medinas, D. B.; Cerchiaro, G.; Trindade, D. F.; Augusto, O. Iubmb. Life. 2007, 59, 255. doi: 10.1080/15216540701230511
5. [5]
  Lu, C.; Lin, J. M. Catal. Today. 2004, 89, 343. doi: 10.1016/j.cattod.2003.12.013
6. [6]
  Ghalei, M.; Ma, J.; Schmidhammer, U.; Vandenborre, J.; Fattahi, M.; Mostafavi, M. J. Phys. Chem. B 2016, 120, 2434. doi: 10.1021/acs.jpcb.5b12405
7. [7]
  Wu, C.; Linden, K. G. Water Res. 2010, 44, 3585. doi: 10.1016/j.watres.2010.04.011
8. [8]
  Liu, Y.; He, X.; Duan, X.; Fatta-Kassinos, D.; Dionysiou, D. D. Water Res. 2016, 95, 195. doi: 10.1016/j.watres.2016.03.011
9. [9]
  Carena, L.; Vione, D. Environ. Chem. Lett. 2016, 14, 183. doi: 10.1007/s10311-016-0549-3
10. [10]
  Busset, C.; Mazellier, P.; Sarakha, M.; Laat, J. D. J. Photoch. Photobio. A 2007, 185, 127. doi: 10.1016/j.jphotochem.2006.04.045
11. [11]
  Zhao, T. Q.; Li, P.; Tai, C.; She, J. P.; Yin, Y. G.; Qi, Y. A.; Zhang, G. C. J. Hazard. Mater. 2018, 346, 42. doi: 10.1016/j.jhazmat.2017.12.009
12. [12]
  Bonini, M. G.; Radi, R.; Ferrersueta, G.; Ferreira, A. M.; Augusto, O. J. Biol. Chem. 1999, 274, 10802. doi: 10.1074/jbc.274.16.10802
13. [13]
  Chen, J. W.; Hu, B.; Qin, H. Y.; Ao, J. P.; Zhang, J.; Zhu, Z. Q. J. Radiat. Res. Radiat. 2006, 24, 137(in Chinese).
14. [14]
  Larson, R. A.; Zepp, R. G. Environ. Toxicol. Chem. 2010, 7, 265.
15. [15]
  Huang, J. P.; Mabury, S. A. Chemosphere 2000, 41, 1775. doi: 10.1016/S0045-6535(00)00042-4
16. [16]
  Karmakar, S.; Datta, A. J. Phys. Chem. B 2017, 121, 7621. doi: 10.1021/acs.jpcb.7b05186
17. [17]
  Zhang, R.; Sun, P.; Boyer, T. H.; Zhao, L.; Huang, C. Environ. Sci. Technol. 2015, 49, 3056. doi: 10.1021/es504799n
18. [18]
  Huang, J.; Mabury, S. A. Environ. Toxicol. Chem. 2000, 19, 1501. doi: 10.1002/etc.v19:6
19. [19]
  Mabury, S. A.; Crosby, D. G. J. Agr. Food. Chem. 1996, 44, 1920. doi: 10.1021/jf950423y
20. [20]
  Mazellier, P.; Leroy, É.; De Laat, J.; Legube, B. New J. Chem. 2002, 26, 1784. doi: 10.1039/b204332g
21. [21]
  Liu, T.; Yin, K.; Liu, C.; Luo, J.; Crittenden, J.; Zhang, W.; Luo, S.; He, Q.; Deng, Y.; Liu, H.; Zhang, D. Water Res. 2018, 147, 204. doi: 10.1016/j.watres.2018.10.007
22. [22]
  Mazellier, P.; Busset, C.; Delmont, A.; De Laat, J. Water Res. 2007, 41, 4585. doi: 10.1016/j.watres.2007.06.066
23. [23]
  Li, Y.; Li, L.; Chen, Z. X.; Zhang, J.; Gong, L.; Wang, Y. X.; Zhao, H. Q.; Mu, Y. Chemosphere 2018, 192, 372. doi: 10.1016/j.chemosphere.2017.10.126
24. [24]
  Poskrebyshev, G. A.; Neta, P.; Huie, R. E. J. Geophys. Res-Atmos. 2001, 106, 4995. doi: 10.1029/2000JD900702
25. [25]
  Wei, B.; Sun, J.; Mei, Q.; He, M. X. Comput. Theor. Chem. 2018, 1129, 1. doi: 10.1016/j.comptc.2018.02.014
26. [26]
  Liebmann, J.; Karu, E.; Sobanski, N. Atmos. Chem. Phys. 2018, 18, 1. doi: 10.5194/acp-18-1-2018
27. [27]
  Maranzana, A.; Ghigo, G.; Tonachini, G. Atmos. Environ. 2017, 167, 181. doi: 10.1016/j.atmosenv.2017.08.011
28. [28]
  Maguta, M. M.; Stenstrom, Y. H.; Nielsen, C. J. J. Phys. Chem. A 2016, 120, 6970. doi: 10.1021/acs.jpca.6b05440
29. [29]
  Musat, R.; Denisov, S. A.; Marignier, J. L.; Mostafavi, M. J. Phys. Chem. B 2018, 122, 2121. doi: 10.1021/acs.jpcb.7b12702
30. [30]
  de Sémainville, P. G.; Hoffmann, D.; George, C.; Herrmann, H. Phys. Chem. Chem. Phys. 2007, 9, 958. doi: 10.1039/B613956F
31. [31]
  Jin, S.; Bi, W.; Li, S.; Dong, W.; Chen, J. J. Phys. Chem. A 2017, 121, 3461. doi: 10.1021/acs.jpca.6b08626
32. [32]
  Exner, M.; Herrmann, H.; Zellner, R. Berichte Der Bunsengesellschaft Für Physikalische Chemie. 2010, 96, 470.
33. [33]
  Mezyk, S. P.; Cullen, T. D.; Rickman, K. A.; Mincher, B. J. Int. J. Chem. Kinet. 2017, 49, 635. doi: 10.1002/kin.2017.49.issue-9
34. [34]
  Katsumura, Y.; Jiang, P. Y.; Nagaishi, R.; Oishi, T.; Ishigure, K.; Yoshida, Y. J. Phys. Chem (United States). 1991, 95, 4435.
35. [35]
  Wine, P. H.; Iii, R. L. M.; Thorn, R. P. J. Phys. Chem. 1988, 92, 1156. doi: 10.1021/j100316a031
36. [36]
  Jarke, F. H.; Ashford, N. A. J. Chem. Phys. 1975, 62, 2923. doi: 10.1063/1.430802
37. [37]
  Wayne, R. P.; Barnes, I.; Biggs, P.; Burrows, J. P. Atmos. Environ. A 1991, 25, 1.
38. [38]
  Wan, L. K.; Peng, J.; Lin, M. Z.; Muroya, Y.; Katsumura, Y.; Fu, J. Y. Radiat. Phys. Chem. 2012, 81, 524. doi: 10.1016/j.radphyschem.2012.01.025
39. [39]
  Nguyen, T. L.; Park, J.; Lee, K.; Song, K.; Barker, J. R. J. Phys. Chem. A 2011, 115, 4894. doi: 10.1021/jp200460b
40. [40]
  Neta, P.; Huie, R. E. Meat Technology 1986, 90, 4644.
41. [41]
  Umschlag, T.; Zellner, R.; Herrmann, H. Phys. Chem. Chem. Phys. 2002, 4, 2975. doi: 10.1039/b110263j
42. [42]
  Dong, W. B.; Zhu, C. Z.; Fang, H. J.; Ouyang, B.; Zhang, R. X.; Hou, H. Q. Acta Chim. Sinica 2005, 63, 2147(in Chinese).
43. [43]
  Ito, O.; Seiji, A.; Masashi, I. J. Org. Chem. 1989, 54, 2436. doi: 10.1021/jo00271a038
44. [44]
  Alfassi, Z. B.; Padmaja, S.; Neta, P.; Huie, R. E. J. Phys. Chem. 1993, 97, 3780. doi: 10.1021/j100117a025
45. [45]
  Mártire, D. O.; Gonzalez, C. Prog. React. Kinet. Mec. 2001, 26, 201. doi: 10.3184/007967401103165253
46. [46]
  Brusa, M. A.; Grela, M. A. Phys. Chem. Chem. Phys. 2003, 5, 3294. doi: 10.1039/b302296j
47. [47]
  Criado, S.; Marioli, J. M.; Allegretti, P. E.; Furlong, J.; Nieto, F. J. R.; Mártire, D. O.; Garcia, N. A. J. Photochem. Photobiol. B 2001, 65, 74. doi: 10.1016/S1011-1344(01)00239-1
48. [48]
  Kumar, M. R.; Adinarayana, M. J. Chem. Sci. 2000, 112, 551. doi: 10.1007/BF02709288
49. [49]
  Kumar, M. R.; Rao, M. T.; Adinarayana, M. Indian J. Biochem. Bio. 2000, 37, 13.
50. [50]
  Huber, J. R.; Hayon, E. J. Phys. Chem. 1968, 71, 3820.
51. [51]
  Black, E. D.; Hayon, E. J. Phys. Chem. 1970, 74, 3199. doi: 10.1021/j100711a007
52. [52]
  Ma, J.; Schmidhammer, U.; Mostafavi, M. J. Phys. Chem. B 2015, 119, 7180.
53. [53]
  Caregnato, P.; Bertolotti, S. G.; Gonzalez, M. C.; Mártire, D. O. Photochem. Photobiol. 2005, 81, 1526. doi: 10.1562/2005-07-07-RA-603
54. [54]
  Meng, J.; Xiong, X.; Zhang, X.; Xu, Y. Appl. Surf. Sci. 2018, 437, 859.
55. [55]
  Subramanian, P. J.; Rajaram, J.; Ramakrishnan, V. Indian J. Chem. 1991, 30, 913.
56. [56]
  Maruthamuthu, P.; Taniguchi, H. J. Phys. Chem. (United States) 1977, 81, 1944.
57. [57]
  Maruthamuthu, P. J. Chem. Soc., Faraday Trans. 11985, 81, 1979. doi: 10.1039/f19858101979
58. [58]
  Villata, L. S.; Gonzalez, M. C.; Mártire, D. O. Int. J. Chem. Kinet. 2010, 42, 391. doi: 10.1002/kin.v42:7
59. [59]
  Rosso, J. A.; Allegretti, P. E.; Mártire, D. O.; Gonzalez, M. C. J. Chem. Soc., Perkin Trans. 21999, 2, 205.
60. [60]
  Neta, P.; Huie, R. E.; Ross, A. B. J. Phys. Chem. Ref. Data 1988, 17, 1027. doi: 10.1063/1.555808
61. [61]
  Khan, J. A.; He, X.; Khan, H. M.; Dionysiou, D. D. Chem. Eng. J. 2013, 218, 376. doi: 10.1016/j.cej.2012.12.055
62. [62]
  Wang, A. J.; He, J. M.; Kong, L. N.; Zhang, N. D. Res. Chem. Intermed. 2017, 43, 2175. doi: 10.1007/s11164-016-2753-y
63. [63]
  Oncu, N. B.; Mercan, N.; Balcioglu, I. A. Chem. Eng. J. 2015, 259, 972. doi: 10.1016/j.cej.2014.08.066
64. [64]
  Liang, Q.; Duan, Y. M.; Wu, B. B.; Zhang, N. D. J. Adv. Oxid. Technol. 2016, 19, 372.
65. [65]
  Anipsitakis, G. P.; Dionysiou, D. D. Environ. Sci. Technol. 2004, 38, 3705. doi: 10.1021/es035121o
66. [66]
  Lou, X. Y.; Guo, Y. G.; Xiao, D. X. Environ. Sci. Pollut. R. 2013, 20, 6317. doi: 10.1007/s11356-013-1678-x
67. [67]
  Zhang, N. D.; Zhu, Z. J.; Luan, W. L. Acta Chim. Sinica 2011, 69, 2307(in Chinese).
68. [68]
  He, J. M.; Kong, L. N.; Liang, Q.; Zhang, N. D. China Environ. Sci. 2016, 36, 2638(in Chinese).
69. [69]
  Wang, B.; Li, J.; Mo, Z. P.; Xian, B. Environ. Eng. 2012, 30, 53(in Chinese).
70. [70]
  Liu, H. X.; Zhang, N. D.; Zhu, Z. J. Chin. Sci. Bull. 2012, 57, 3493(in Chinese).
71. [71]
  Liu, C.; Wu, B.; Chen, X. E. Chem. Eng. J. 2018, 335, 865. doi: 10.1016/j.cej.2017.10.162
72. [72]
  Tang, Y.; Thorn, R. P.; Iii, R. L. M. J. Photoch. Photobio. A 1988, 44, 243. doi: 10.1016/1010-6030(88)80097-2
73. [73]
  Morimoto, S.; Ito, T.; Fujita, S. I. Chem. Phys. Lett. 2008, 461, 300. doi: 10.1016/j.cplett.2008.07.013
74. [74]
  Huang, Y. F.; Huang, Y. H. J. Hazard. Mater. 2009, 162, 1211. doi: 10.1016/j.jhazmat.2008.06.008
75. [75]
  Clément, J. L.; Gilbert, B. C.; Ho, W. F.; Jackson, N. D.; Newton, M. S.; Silvester, S.; Timmins, G. S.; Tordo, P.; Whitwood, A. C. J. Chem. Soc., Perkin Trans. 21998, 8, 1715.
76. [76]
  Chawla, O. P.; Fessenden, R. W. J. Phys. Chem. 1975, 79, 2693. doi: 10.1021/j100591a020
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