Citation: Zuo Fangtao, Xu Wei, Zhao Aiwu. A SERS Approach for Rapid Detection of Hg²⁺ Based on Functionalized Fe₃O₄@Ag Nanoparticles[J]. Acta Chimica Sinica, ;2019, 77(4): 379-386. doi: 10.6023/A18110475 shu

A SERS Approach for Rapid Detection of Hg²⁺ Based on Functionalized Fe₃O₄@Ag Nanoparticles

Zuo Fangtao ^a,b,c ,
Xu Wei ^a,b,c ,
Zhao Aiwu ^a,b,c,,

a.
Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031
b.
University of Science and Technology of China, Hefei, 230026 Anhui
c.
State Key Laboratory of Transducer Technology, Chinese Academy of Sciences, Hefei 230031

Corresponding author: Zhao Aiwu, awzhao@iim.ac.cn
Received Date: 26 November 2018
Available Online: 14 April 2019
Fund Project: the National Natural Science Foundation of China 61875255Project supported by the National Natural Science Foundation of China (No. 61875255) and the Direction Program of Hefei Center of Physical Science and Technology (No. 2018ZYFX005)the Direction Program of Hefei Center of Physical Science and Technology 2018ZYFX005

Figures(12)

Mercury is an important pollutant, which has attracted wide attention in recent years. Up to now, based on surface enhanced raman spectroscopy (SERS) strategy for detection of Hg²⁺ is very attractive due to its high sensitivity among various detection methods. Based on the "turn-off" mechanism, we synthesized a magnetic Fe₃O₄@Ag nanomaterial for SERS detection of Hg²⁺. The magnetic-plasma resonance nanoparticles, which combine magnetic and plasma resonance properties, can be used for SERS detection of mercury ions with high sensitivity and selectivity. Firstly, the magnetic nanoparticles were prepared by solvothermal reaction, and silver nanoparticles were coated on the surface of magnetic nanoparticles after modification of amino groups. By modifying the positively charged PDADMAC, polyDADMAC (PDDA) layer, the negatively charged methyl orange probe molecule is adsorbed on the surface of Fe₃O₄@Ag, and in the presence of Hg²⁺, a significant decrease in SERS signal can be observed. Due to the short-time reaction of Hg²⁺ and Ag nanoparticles, an amalgam is formed on the surface of the Ag particles, which affects the surface plasmon resonance (SPR) characteristics of the Ag nanoparticles, resulting in enhanced attenuation of the electromagnetic field. And the short-time reaction of Hg²⁺ and Ag nanoparticles also leads to a decrease in the surface zeta potential of the Ag nanoparticles and affects the adsorption of the Raman probe molecules on the surface, resulting in a decrease in the SERS signal. Therefore, the decrease of SERS intensity in the presence of Hg²⁺ is mainly attributed to the interaction between Hg²⁺ and Ag nanoparticles. Through our experiments, it can be proved that the detection limit of the method based on "turn-off" mechanism for detecting Hg²⁺ ions can be as low as 10^-10 mol/L. In addition, this method also shows high selectivity for divalent mercury ions. The SERS nanosensor designed in this experiment can be used to detect the specificity and ultra-sensitivity of Hg²⁺ in the environment, and it also provides great potential for the construction of SERS nanosensor for heavy metal ions.
- surface enhanced Raman spectroscopy (SERS),
- mercury(Ⅱ) ion,
- magnetic nanomaterial,
- rapid detection,
- silver nanoparticle
1. [1]
  Cai, F. D.; Zhu, Q.; Zhao, K.; Deng, A. P.; Li, J. G. Environ. Sci. Technol. 2015, 49, 5013. doi: 10.1021/acs.est.5b00690
2. [2]
  Zhang, C. Y.; Meng, Y. Z.; Kuang, J. Z.; Xu, L. Acta Chim. Sinica 2015, 73, 409.
3. [3]
  Wang, X. W.; Chen, S. Acta Chim. Sinica 2014, 72, 1147.
4. [4]
  Wan, J.; Yin, G.; Ma, X. J.; Xing, L.; Luo, X. L. Electroanalysis 2014, 26, 823. doi: 10.1002/elan.201300628
5. [5]
  Taylor, V. F.; Bugge, D.; Jackson, B. P.; Chen, C. Y. Environ. Sci. Technol. 2014, 48, 5058. doi: 10.1021/es404159k
6. [6]
  Srivastava, R. K.; Sedman, C. B.; Kilgroe, J. D.; Smith, D.; Renninger, S. J. Air Waste Manage. Assoc. 2001, 51, 1460. doi: 10.1080/10473289.2001.10464367
7. [7]
  Lee, C.; Choo, J. Bull. Korean Chem. Soc. 2011, 32, 2003. doi: 10.5012/bkcs.2011.32.6.2003
8. [8]
  Wu, Y. G.; Zhan, S. S.; Xu, L. R.; Shi, W. W.; Xi, T.; Zhan, X. J.; Zhou, P. Chem. Commun. 2011, 47, 6029.
9. [9]
  Shah, A. Q.; Kazi, T. G.; Baig, J. A.; Afridi, H. I.; Arain, M. B. Food Chem. 2012, 134, 2345. doi: 10.1016/j.foodchem.2012.03.109
10. [10]
  Ye, B. C.; Yin, B. C. Angew. Chem., Int. Ed. 2008, 47, 8386. doi: 10.1002/anie.v47:44
11. [11]
  Lou, T. T.; Chen, L.; Zhang, C. R.; Kang, Q.; You, H. Y.; Shen, D. Z.; Chen, L. X. Anal. Methods 2012, 4, 488. doi: 10.1039/c2ay05764f
12. [12]
  Wu, X. F.; Ma, Q. J.; Wei, X. J.; Hou, Y. M.; Zhu, X. Sens. Actuators, B 2013, 183, 565. doi: 10.1016/j.snb.2013.04.024
13. [13]
  Rakkesh, R. A.; Durgalakshmi, D.; Balakumar, S. RSC Adv. 2016, 6, 34342. doi: 10.1039/C6RA01784C
14. [14]
  Qu, H.; Lai, Y.; Niu, D.; Sun, S. Anal. Chim. Acta 2013, 763, 38. doi: 10.1016/j.aca.2012.12.016
15. [15]
  Du, Y. X.; Liu, R. Y.; Liu, B. H.; Wang, S. H.; Han, M. Y.; Zhang, Z. P. Anal. Chem. 2013, 85, 3160. doi: 10.1021/ac303358w
16. [16]
  Li, D.-W.; Zhai, W.-L.; Li, Y.-T.; Long, Y.-T. Microchim. Acta 2014, 181, 23. doi: 10.1007/s00604-013-1115-3
17. [17]
  Alvarez-Puebla, R. A.; Liz-Marzan, L. M. Angew. Chem., Int. Ed. 2012, 51, 11214. doi: 10.1002/anie.201204438
18. [18]
  Kang, T.; Yoo, S. M.; Yoon, I.; Lee, S.; Choo, J.; Lee, S. Y.; Kim, B. Chem.-Eur. J. 2011, 17, 2211. doi: 10.1002/chem.201001663
19. [19]
  Duan, J. L.; Yang, M.; Lai, Y. C.; Yuan, J. P.; Zhan, J. H. Anal. Chim. Acta 2012, 723, 88. doi: 10.1016/j.aca.2012.02.031
20. [20]
  Li, F.; Wang, J.; Lai, Y. M.; Wu, C.; Sun, S. Q.; He, Y. H.; Ma, H. Biosens. Bioelectron. 2013, 39, 82. doi: 10.1016/j.bios.2012.06.050
21. [21]
  Kang, Y.; Wu, T.; Liu, B. X.; Wang, X.; Du, Y. P. Microchim. Acta 2014, 181, 1333. doi: 10.1007/s00604-014-1259-9
22. [22]
  Ojea-Jimenez, I.; Lopez, X.; Arbiol, J.; Puntes, V. ACS Nano 2012, 6, 2253. doi: 10.1021/nn204313a
23. [23]
  Ding, X.; Kong, L.; Wang, J.; Fang, F.; Li, D.; Liu, J. ACS Appl. Mater. Interfaces 2013, 5, 7072. doi: 10.1021/am401373e
24. [24]
  Zhang, L.; Chang, H. X.; Hirata, A.; Wu, H. K.; Xue, Q. K.; Chen, M. W. ACS Nano. 2013, 7, 4595. doi: 10.1021/nn4013737
25. [25]
  Chung, E.; Gao, R.; Ko, J.; Choi, N.; Lim, D. W.; Lee, E. K.; Chang, S.-I.; Choo, J. Lab. Chip. 2013, 13, 260. doi: 10.1039/C2LC41079F
26. [26]
  Esmaielzadeh Kandjani, A.; Sabri, Y. M.; Mohammad-Taheri, M.; Bansal, V.; Bhargava, S. K. Environ. Sci. Technol. 2015, 49, 1578. doi: 10.1021/es503527e
27. [27]
  Sun, B.; Jiang, X. X.; Wang, H. Y.; Song, B.; Zhu, Y.; Wang, H.; Su, Y. Y.; He, Y. Anal. Chem. 2015, 87, 1250. doi: 10.1021/ac503939d
28. [28]
  Deng, H.; Li, X. L.; Peng, Q.; Wang, X.; Chen, J. P.; Li, Y. D. Angew. Chem., Int. Ed. 2005, 44, 2782. doi: 10.1002/(ISSN)1521-3773
29. [29]
  Zhao, Y. L.; Tao, C. R.; Xiao, G.; Wei, G. P.; Li, L. H.; Liu, C. X.; Su, H. J. Nanoscale 2016, 8, 5313. doi: 10.1039/C5NR08624H
30. [30]
  Li, Z. X.; Zhao, A. W.; Gao, Q.; Guo, H. Y.; Wang, D. P.; Li, L. Acta Chim. Sinica 2015, 73, 847.
31. [31]
  Ren, W.; Zhu, C. Z.; Wang, E. Nanoscale 2012, 4, 5902. doi: 10.1039/c2nr31410j
32. [32]
  Alvarez-Puebla, R. A.; Arceo, E.; Goulet, P. J. G.; Garrido, J. J.; Aroca, R. F. J. Phys. Chem. B 2005, 109, 3787. doi: 10.1021/jp045015o
33. [33]
  He, S. T.; Yao, J. N.; Jiang, P.; Shi, D. X.; Zhang, H. X.; Xie, S. S.; Pang, S. J.; Gao, H. J. Langmuir 2001, 17, 1571. doi: 10.1021/la001239w
34. [34]
  Katsikas, L.; Gutierrez, M.; Henglein, A. J. Phys. Chem. 1996, 100, 11203. doi: 10.1021/jp960357i
35. [35]
  Ding, S.-Y.; Wu, D.-Y.; Yang, Z.-L.; Ren, B.; Xu, X.; Tian, Z.-Q. Chem. J. Chin. Univ. Chin. 2008, 29, 2569. doi: 10.3321/j.issn:0251-0790.2008.12.048
36. [36]
  Zhao, L. B.; Huang, Y. F.; Wu, D. Y.; Ren, B. Acta Chim. Sinica 2014, 72, 1125.
37. [37]
  Mclellan, J. M.; Xiong, Y. J.; Hu, M.; Xia, Y. N. Chem. Phys. Lett. 2006, 417, 230. doi: 10.1016/j.cplett.2005.10.028
38. [38]
  Wang, G. Q.; Lim, C.; Chen, L. X.; Chon, H.; Choo, J.; Hong, J.; Demello, A. J. Anal. Bioanal. Chem. 2009, 394, 1827. doi: 10.1007/s00216-009-2832-7
39. [39]
  Ganbold, E.-O.; Park, J.-H.; Ock, K.-S.; Joo, S.-W. Bull. Korean Chem. Soc. 2011, 32, 519. doi: 10.5012/bkcs.2011.32.2.519
40. [40]
  Sun, Z. L.; Du, J. J.; Lv, B.; Jing, C. Y. RSC Adv. 2016, 6, 73040. doi: 10.1039/C6RA15044F
41. [41]
  Hou, M. J.; Huang, Y.; Ma, L. W.; Zhang, Z. J. Nanoscale Res. Lett. 2015, 10, 437. doi: 10.1186/s11671-015-1142-6
42. [42]
  Mou, Y.; Lu, H.; Li, M.; Chen, C. Chin. J. Chem. 2017, 35, 435. doi: 10.1002/cjoc.v35.4
1. [1]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
2. [2]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
3. [3]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
4. [4]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
5. [5]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
6. [6]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Di Yang , Jiayi Wei , Hong Zhai , Xin Wang , Taiming Sun , Haole Song , Haiyan Wang . Rapid Detection of SARS-CoV-2 Using an Innovative “Magic Strip”. University Chemistry, 2024, 39(4): 373-381. doi: 10.3866/PKU.DXHX202312023
10. [10]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
11. [11]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
12. [12]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
13. [13]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
14. [14]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
15. [15]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
16. [16]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
17. [17]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
18. [18]
  Liwei Wang , Guangran Ma , Li Wang , Fugang Xu . A Comprehensive Analytical Chemistry Experiment: Colorimetric Detection of Vitamin C Using Nanozyme and Smartphone. University Chemistry, 2024, 39(8): 255-262. doi: 10.3866/PKU.DXHX202312094
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025

Get Citation

PDF

XML

Metrics

PDF Downloads(16)
Abstract views(1674)
HTML views(296)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A SERS Approach for Rapid Detection of Hg2+ Based on Functionalized Fe3O4@Ag Nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

A SERS Approach for Rapid Detection of Hg²⁺ Based on Functionalized Fe₃O₄@Ag Nanoparticles