Citation: Ma Guojia, Zheng Haikun, Chang Shinan, Wang Shuoshuo. Wettability Analysis and Design of Micro-nanostructured Superhydrophobic Surface[J]. Acta Chimica Sinica, ;2019, 77(3): 269-277. doi: 10.6023/A18100430 shu

Wettability Analysis and Design of Micro-nanostructured Superhydrophobic Surface

a.
Science and Technology on Power Beam Processes Laboratory, Beijing Aeronautical Manufacturing Technology Research Institute, Beijing 100024
b.
School of Aeronautic Science and Engineering, Beihang University, Beijing 100191

Corresponding author: Chang Shinan, sn_chang@buaa.edu.cn
Received Date: 16 October 2018
Available Online: 3 March 2018
Fund Project: National Basic Research Program of China 2015CB755803the National Natural Science Foundation of China 11672024the National Natural Science Foundation of China 11372026Project supported by the National Natural Science Foundation of China (Grant Nos. 11672024, 11372026) and National Basic Research Program of China (Grants No. 2015CB755803)

Figures(8)

The special wettability of superhydrophobic surface usually has high contact angles (CA>150°) and low contact angle hysteresis (CAH < 5°), which has been exploited for many potential applications. It is well known that wettability is mainly determined by micro/nano structure and surface composition, and various types of natural superhydrophobic surface could exhibit different wetting states, showing different wetting properties, such as low adhesive lotus leaf; the anisotropic superhydrophobic rice leaf; high adhesive rose petal. Therefore, the relationship between the wetting state and the surface structure should have a deeper understanding, especially in the design preliminary stage. The "droplet-superhydrophobic surface" system is taken as the research objects, four stable wetting state expressions are analyzed based on the principle of minimum energy. Wetting state transitions are studied on superhydrophobic surface coverd with micro/nano structured pillars of different distributions. The calculation formula of intrinsic contact angle is derived and the intrinsic contact angle of common materials is investigated. Based on the four wetting state of apparent contact angle equations, wetting diagrams were drew for investigating the wetting behavior, which include "one point, three lines, six areas, four state". The influence of the relative structure spacing and relative structure height on the wetting state is analyzed. It is found that the larger relative structure height, the smaller relative structure spacing, which can reduce the critical parameters of the transition state of the infiltration state, thereby expanding the range of the superhydrophobic surface, the more design options are available. It is also beneficial to the stability of the superhydrophobic surface, but should be controlled within certain scales because of mechanical stability. The simulation results accurately reflect the wetting state with the changes of the relative structure spacing and relative structure height. Finally, the general design of the superhydrophobic surface is refined. The results can provide theoretical guidance and technical fundament for the design of superhydrophobic surfaces.
- wettability,
- superhydrophobic surface,
- critical relative structure spacing,
- critical relative structure height,
- design clue,
- wetting state transition
1. [1]
  Barthlott, W.; Neinhuis, C. Planta 1997, 202, 1. doi: 10.1007/s004250050096
2. [2]
  Marmur, A. Langmuir 2003, 19, 5956. doi: 10.1021/la034490v
3. [3]
  Zheng, H. K.; Chang, S. N.; Zhao, Y. Y. Prog. Chem. 2017, 29, 102.
4. [4]
  Kreder, M. J.; Alvarenga, J.; Kim, P.; Aizenberg, J. Nat. Rev. Mater. 2016, 1, 15003. doi: 10.1038/natrevmats.2015.3
5. [5]
  Liang, W. X.; Zhang, Y. B.; Wang, B.; Guo, Z. G.; Liu, W. M. Acta Chim. Sinica 2012, 70, 2393
6. [6]
  Zhang, J. N.; Yu, J. H. Chin. J. Chem. 2018, 36, 51. doi: 10.1002/cjoc.201700579
7. [7]
  Cui, L. Y.; Fan, S. S.; Yu, C. L.; Kuang, M. X.; Wang, J. X. Acta Chim. Sinica 2017, 75, 967.
8. [8]
  Wenzel, R. N. Ind. Eng. Chem. 1936, 28, 988. doi: 10.1021/ie50320a024
9. [9]
  Cassie, A. B. D.; Baxter, S. Trans. Faraday Soc. 1944, 40, 546. doi: 10.1039/tf9444000546
10. [10]
  Bico, J.; Tiele, U.; Quere, D. Colloid Surface A 2002, 206, 41. doi: 10.1016/S0927-7757(02)00061-4
11. [11]
  Bhushan, B.; Nosonovsky, M. Phil. Trans. R. Soc. A 2010, 368, 4713. doi: 10.1098/rsta.2010.0203
12. [12]
  Suzuki, S.; Ueno, K. Langmuir 2017, 33, 138. doi: 10.1021/acs.langmuir.6b03832
13. [13]
  Hejazi, V.; Nosonovsky, M. Colloid Polym. Sci. 2013, 291, 329. doi: 10.1007/s00396-012-2838-0
14. [14]
  Tuvshindorj, U.; Yildirim, A.; Ozturk, F. E.; Bayindir, M. ACS Appl. Mater. Inter. 2014, 6, 9680. doi: 10.1021/am502117a
15. [15]
  Wang, S.; Jiang, L. Adv. Mater. 2007, 19, 3423. doi: 10.1002/(ISSN)1521-4095
16. [16]
  Rahmawan, Y.; Moon, M. W.; Kim, K. S. Langmuir 2009, 26, 484.
17. [17]
  Wu, B. B.; Wu, H. P.; Zhang, Z.; Dong, C. C.; Chai, G. Z. Acta Phys. Sin. 2015, 64, 176801.
18. [18]
  Lv, P. Y.; Xue, Y. H.; Duan, H. L. Adv. Mech. 2016, 46, 179.
19. [19]
  Moosmann, M.; Schimmel, T.; Barthlott, W.; Mail, M. Beilstein J. Nanotech. 2017, 8, 1671. doi: 10.3762/bjnano.8.167
20. [20]
  Seo, J.; García-Mayoral, R.; Mani, A. J. Fluid Mech. 2018, 8, 35.
21. [21]
  Lafuma, A.; Queré, D. Nat. Mater. 2003, 2, 457. doi: 10.1038/nmat924
22. [22]
  Ye, X. M.; Zhang, X. S.; Li, M. L.; Li, C. X. Acta Phys. Sin. 2018, 67, 114702. doi: 10.7498/aps.67.20180159
23. [23]
  Kwon, H. M.; Paxson, A. T.; Varanasi, K. K.; Patankar, N. A. Phys. Rev. Lett. 2011, 106, 036102. doi: 10.1103/PhysRevLett.106.036102
24. [24]
  Bartolo, D.; Bouamrirene, F.; Verneuil, É.; Buguin, A.; Silberzan, P.; Moulinet, S. EPL 2006, 74, 299. doi: 10.1209/epl/i2005-10522-3
25. [25]
  Bormashenko, E.; Pogreb, R.; Whyman, G.; Erlich, G. Langmuir 2007, 23, 12217. doi: 10.1021/la7016374
26. [26]
  Girifalco, L. A.; Good, R. J. J. Phys. Chem. 1957, 61, 904. doi: 10.1021/j150553a013
27. [27]
  Zisman, W. A. Adv. Chem. 1964, 43, 1. doi: 10.1021/advances
28. [28]
  Barthlott, W.; Neinhuis, C.; Cutler, D.; Ditsch, F.; Meusel, I.; Theisen, I. Bot. J. Linn. Soc. 1998, 126, 237. doi: 10.1111/boj.1998.126.issue-3
29. [29]
  Nishino, T.; Meguro, M.; Nakamae, K. Langmuir 1999, 15, 4321. doi: 10.1021/la981727s
30. [30]
  Han, J. T.; Sun, Y. K.; Woo, J. S.; Lee, G. W. Adv. Mater. 2010, 20, 3724.
31. [31]
  Raza, M. A.; Kooij, E. S.; Silfhout, A. Langmuir 2010, 26, 12962. doi: 10.1021/la101867z
32. [32]
  Liu, X.; Dai, B.; Zhou, L.; Sun, J. J. Mater. Chem. 2009, 19, 497. doi: 10.1039/B817467A
33. [33]
  Dong, J.; Jin, Y.; Dong, H.; Sun, L. Langmuir 2017, 33, 1041.
34. [34]
  Guan, Z. S.; Zhang, Q. Acta Chim. Sinica 2005, 63, 880.
35. [35]
  Kulinich, S. A.; Farhadi, S.; Nose, K. Langmuir 2011, 27, 25. doi: 10.1021/la104277q
1. [1]
  Guoxian Zhu , Jing Chen , Rongkai Pan . Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies. University Chemistry, 2024, 39(3): 376-383. doi: 10.3866/PKU.DXHX202305027
2. [2]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
5. [5]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
6. [6]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
7. [7]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
8. [8]
  Ling Zhang , Jing Kang . Turn Waste into Valuable: Preparation of High-Strength Water-Based Adhesives from Polymethylmethacrylate Wastes: a Comprehensive Chemical Experiments. University Chemistry, 2024, 39(2): 221-226. doi: 10.3866/PKU.DXHX202306075
9. [9]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
10. [10]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
11. [11]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
12. [12]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
13. [13]
  Nana Wang , Gaosheng Zhang , Huosheng Li , Tangfu Xiao . Discussion on the Teaching Reform of Environmental Functional Materials within the Context of “Double First-Class” Initiative: Emphasizing the Integration of Industry, Academia, Research, and Application. University Chemistry, 2024, 39(6): 137-144. doi: 10.3866/PKU.DXHX202312010
14. [14]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
15. [15]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
16. [16]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
17. [17]
  Wanqun Hu , Pingping Zhu , Yuan Zheng , Wanqun Zhang , Wei Shao , Hong Wu , Qiang Zhou , Kaiping Yang , Xiang Sheng . Design and Practice of Ideological and Political Case Study in Instrumental Analysis Experiment Course: the Extraction and Structural Identification of Artemisinin. University Chemistry, 2024, 39(2): 203-207. doi: 10.3866/PKU.DXHX202310062
18. [18]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
19. [19]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
20. [20]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064

Get Citation

PDF

XML

Metrics

PDF Downloads(118)
Abstract views(3748)
HTML views(1176)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142