Citation: Tang Siqun, Ma Lingling, Luo Min, Zhang Zhaohui, Qiu Ye, Feng Shuo, Xia Chuanqin, Jin Yongdong, Xu Diandou. Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles[J]. Acta Chimica Sinica, ;2019, 77(2): 160-165. doi: 10.6023/A18090401 shu

Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles

Tang Siqun ^a,b ,
Ma Lingling ^a,, ,
Luo Min ^a ,
Zhang Zhaohui ^c ,
Qiu Ye ^c ,
Feng Shuo ^c ,
Xia Chuanqin ^b ,
Jin Yongdong ^b ,
Xu Diandou ^a,,

a.
Division of Nuclear Technology and Applications, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049
b.
College of Chemistry, Sichuan University, Chengdu 610064
c.
Beijing Entry-Exit Inspection and Quarantine Bureau Technology Centre, Beijing 100026

Corresponding author: Ma Lingling, malingling@ihep.ac.cn Xu Diandou, xudd@ihep.ac.cn
Received Date: 25 September 2018
Available Online: 3 February 2018
Fund Project: the National Natural Science Foundation of China 11575210the National Natural Science Foundation of China U1832212the Key Deployment Projects of Chinese Academy of Sciences ZDRW-CN-2018-1the National Natural Science Foundation of China 91643206Project supported by the National Natural Science Foundation of China (Nos. U1832212, 11405184, 11575210, 91643206) and the Key Deployment Projects of Chinese Academy of Sciences (No. ZDRW-CN-2018-1)the National Natural Science Foundation of China 11405184

Figures(5)

The effect of NH₃ concentration, reaction time and other conditions on the heterogeneous reaction of NH₃ and Cl₂ on the surface of γ-Al₂O₃ particles was investigated at the room temperature, pressure and in the presence of oxygen by ion chromatography (IC). The formation of the surface species (Cl^-, NO₃^-, and SO₄^2-) via both individual reaction and co-existing reaction of NH₃, Cl₂, SO₂ and NO₂ on the surface of γ-Al₂O₃ was investigated as well. The results revealed that NH₃ (400 ppm) and Cl₂ (400 ppm) had synergistic effect on the surface γ-Al₂O₃, and the total yield of Cl^- was 589.65 μg after reaction of 2 h. The formation of the surface chlorides increased firstly and then decreased with the increase of ammonia concentration, and the maximum yield of Cl^- was reached at 400 ppm of NH₃. In the presence of active chlorine, NH₃ significantly promoted the generation of the adsorptive species on the surface, such as Cl^-, NO₃^- and SO₄^2-, and the most obvious synergistic effect was induced to form on the conditions of four gases co-existence. The heterogeneous reaction mechanism of NH₃ with Cl₂ and the influence on the atmospheric environment were also discussed as well. Additionally, the mixing ratios used in the study are extremely high compared with ambient levels, which could be as a simulation to explore whether the synergistic effect obtained in this paper are also present in the real ambient conditions. We have studied a relatively low mixing ratios for heterogeneous reaction experiments, but the content of nitrate and chloride on the surface of γ-Al₂O₃ were lower than the limit of detection of ion chromatography. Therefore, other researches such as Knudsen cell and smog chamber study, field monitoring, and mode study are also worth for exploring in future study. The results of this study could provide reference data for the study of the contribution of active chlorine and ammonia to the formation of secondary inorganic particles.
- heterogeneous reaction,
- secondary inorganic particles,
- NH₃,
- Cl₂
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Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles