Citation: Wang Kaikai, He Junhui. Fabrication and Study of Antibacterial/Antireflective Dual-functional Thin Films from Quaternary Ammonium Salt Modified Hollow Silica Nanospheres[J]. Acta Chimica Sinica, ;2018, 76(10): 807-812. doi: 10.6023/A18050201 shu

Fabrication and Study of Antibacterial/Antireflective Dual-functional Thin Films from Quaternary Ammonium Salt Modified Hollow Silica Nanospheres

Wang Kaikai ^a,b ,
He Junhui ^a,,

a.
Functional Nanomaterials Laboratory, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: He Junhui, jhhe@mail.ipc.ac.cn
Received Date: 15 May 2018
Available Online: 13 October 2018
Fund Project: the Science and Technology Commission of Beijing Municipality Z151100003315018the National Key Research and Development Program of China 2017YFA0207102the National Natural Science Foundation of China 21571182Project supported by the National Natural Science Foundation of China (No. 21571182), the National Key Research and Development Program of China (No. 2017YFA0207102) and the Science and Technology Commission of Beijing Municipality (No. Z151100003315018)

Figures(8)

Dual-functional thin films simultaneously demonstrating antireflective and antibacterial properties have important practical values in the fields of medicine and health. Unfortunately, related studies have so far been very limited. This work chose a quaternary ammonium salt with the longest carbon chain of C₁₈ as antibacterial agent, and used it to modify an acid-catalyzed silica sol via chemical bonding. The obtained quaternary ammonium salt modified acid-catalyzed silica sol (Q-ASNs) was subsequently mixed with a hollow silica nanospheres sol (HSNs) followed by stirring for 6 h to obtain a mixed sol. The volume percentage of Q-ASNs was varied as 3.1%, 4.9%, 6.7%, and 8.4%, respectively. In detail, Q-ASNs were synthesized as follows:1 mL tetraethyl orthosilicate (TEOS), 0.6 mL quaternary ammonium salt methanol solution (65 wt%), 13.6 mL ethanol, 0.45 mL water and 21 μL HCl were mixed followed by stirring at room temperature for 4 h and aging for at least one day. HSNs were prepared according to the following procedure:0.1 g poly(acrylic acid) (PAA) was dissolved in 4.5 mL ammonium hydroxide, and then it was mixed with 90 mL absolute ethanol under stirring. This was followed by the injection of 800 μL TEOS under vigorous magnetic stirring at room temperature in 40 min. After 10 h, a HSNs sol containing~30 nm hollow silica nanospheres formed. Before mixing Q-ASNs and HSNs, the HSNs were stirred in a ventilating cabinet for more than 24 h to remove ammonia. Antireflective/antibacterial dual-functional thin films were fabricated by dip-coating from the mixed sol of Q-ASNs and HSNs. The optical properties of the films were optimized by regulating the mixing ratio of the above-mentioned two sols. The optimal thin film coated glass substrate presented high transmittance (T_max=99.2%, T_ave=98.6%) in the visible wavelength range of 400~800 nm. The HSNs and the mixed sol were observed by transmission electron microscopy. The fabricated thin films were characterized by scanning electron microscopy, atomic force microscopy, transmission/reflection spectroscopy, X-ray photoelectron spectroscopy, and confocal laser scanning microscopy using a live/dead reagent. The current method is simple and easy for large-area coating without any high-temperature heat treatment, and is thus promising for practical applications.
- antireflective,
- antibacterial,
- quaternary ammonium salt,
- hollow silica nanospheres,
- thin film
1. [1]
  Yao, L.; He, J. Prog. Mater. Sci. 2014, 61, 94. doi: 10.1016/j.pmatsci.2013.12.003
2. [2]
  Xu, L.; He, J. J. Mater. Chem. C 2013, 1, 4655. doi: 10.1039/c3tc30734d
3. [3]
  Li, T.; He, J. J. Mater. Chem. C 2016, 4, 5342. doi: 10.1039/C6TC01540A
4. [4]
  Zhang, J.; Yu, J. Chin. J. Chem. 2017, 36, 51.
5. [5]
  Sun, H.; He, Q.; Yin, S.; Xu, K. Chin. J. Chem. 2017, 35, 1627. doi: 10.1002/cjoc.v35.10
6. [6]
  Raut, H. K.; Ganesh, V. A.; Nair, A. S.; Ramakrishna, S. Energy Environ. Sci. 2011, 4, 3779. doi: 10.1039/c1ee01297e
7. [7]
  Moghal, J.; Kobler, J.; Sauer, J.; Best, J.; Gardener, M.; Watt, A. A.; Wakefield, G. ACS Appl. Mater. Interfaces 2012, 4, 854. doi: 10.1021/am201494m
8. [8]
  Yao, L.; He, J. J. Mater. Chem. A 2014, 2, 6994. doi: 10.1039/c3ta15363k
9. [9]
  Tao, C.; Yan, H.; Yuan, X.; Yin, Q.; Zhu, J.; Ni, W.; Yan, L.; Zhang, L. Colloids Surf., A 2016, 509, 307. doi: 10.1016/j.colsurfa.2016.08.055
10. [10]
  Xu, L.; Geng, Z.; He, J.; Zhou, G. ACS Appl. Mater. Interfaces 2014, 6(12), 9029. doi: 10.1021/am5016777
11. [11]
  Zhang, J.; Lan, P.; Li, J.; Xu, H.; Wang, Q.; Zhang, X.; Zheng, L.; Lu, Y.; Dai, N.; Song, W. J. Sol-Gel Sci. Technol. 2014, 71, 267. doi: 10.1007/s10971-014-3364-y
12. [12]
  Cloutier, M.; Mantovani, D.; Rosei, F. Trends Biotechnol. 2015, 33, 637. doi: 10.1016/j.tibtech.2015.09.002
13. [13]
  Kiedrowski, L. M.; Perisetti, A.; Loock, M. H.; Khaitsa, M. L.; Guerrero, D. M. Am. J. Infect. Control 2013, 41, 1136. doi: 10.1016/j.ajic.2013.01.030
14. [14]
  Wang, X.; Shi, L.; Zhang, J.; Cheng, J.; Wang, X. RSC Adv. 2017, 7, 31502. doi: 10.1039/C7RA04353H
15. [15]
  Shao, H.; Meng, W.-D.; Qing, F.-L. J. Fluorine Chem. 2004, 125, 721. doi: 10.1016/j.jfluchem.2003.12.008
16. [16]
  Liu, C. X.; Zhang, D. R.; He, Y.; Zhao, X. S.; Bai, R. J. Membr. Sci. 2010, 346, 121. doi: 10.1016/j.memsci.2009.09.028
17. [17]
  Li, L.; Chi, X.; Yan, J.; Zhao, Z. Chin. J. Org. Chem. 2018, 38, 955.
18. [18]
  Asri, L. A. T. W.; Crismaru, M.; Roest, S.; Chen, Y.; Ivashenko, O.; Rudolf, P.; Tiller, J. C.; van der Mei, H. C.; Loontjens, T. J. A.; Busscher, H. J. Adv. Funct. Mater. 2014, 24, 346. doi: 10.1002/adfm.v24.3
19. [19]
  Gottenbosa, B.; Mei, H. C. V.; Klatterb, F.; Nieuwenhuisb, P.; Busscher, H. J. Biomaterials 2002, 23, 1417. doi: 10.1016/S0142-9612(01)00263-0
20. [20]
  Nishihara, T.; Okamoto, T.; Nishiyama, N. J. Appl. Microbiol. 2000, 88, 641. doi: 10.1046/j.1365-2672.2000.01007.x
21. [21]
  Laopaiboon, L.; Hall, S. J.; Smith, R. N. J. Appl. Microbiol. 2002, 93, 1051. doi: 10.1046/j.1365-2672.2002.01785.x
22. [22]
  Kim, S.; Jung, U. T.; Kim, S. K.; Lee, J. H.; Choi, H. S.; Kim, C. S.; Jeong, M. Y. ACS Appl. Mater. Interfaces 2015, 7, 326. doi: 10.1021/am506254r
23. [23]
  Zhou, H.; Li, J.; Bao, S.; Li, J.; Liu, X.; Jin, P. Appl. Surf. Sci. 2016, 363, 532. doi: 10.1016/j.apsusc.2015.12.045
24. [24]
  Wang, K.; He, J. ACS Appl. Mater. Interfaces 2018, 10, 11189. doi: 10.1021/acsami.8b00192
25. [25]
  Zhang, Q.; Liu, H.; Zhan, X.; Chen, F.; Yan, J.; Tang, H. RSC Adv. 2015, 5, 77508. doi: 10.1039/C5RA12945A
26. [26]
  Andreu, N.; Flahaut, D.; Dedryvère, R.; Minvielle, M.; Martinez, H.; Gonbeau, D. ACS Appl. Mater. Interfaces 2015, 7, 6629. doi: 10.1021/am5089764
27. [27]
  Zhang, X.; Lan, P.; Lu, Y.; Li, J.; Xu, H.; Zhang, J.; Lee, Y.; Rhee, J. Y.; Choy, K. L.; Song, W. ACS Appl. Mater. Interfaces 2014, 6, 1415. doi: 10.1021/am405258d
28. [28]
  Zhang, X.; He, J. Chem. Commun. (Camb) 2015, 51, 12661. doi: 10.1039/C5CC04465K
29. [29]
  Knetsch, M. L. W.; Koole, L. H. Polymer 2011, 3, 340. doi: 10.3390/polym3010340
30. [30]
  Majumdar, P.; Lee, E.; Gubbins, N.; Christianson, D. A.; Stafslien, S. J.; Daniels, J.; VanderWal, L.; Bahr, J.; Chisholm, B. J. J. Comb. Chem. 2009, 11, 1115. doi: 10.1021/cc900114e
31. [31]
  Kugler, R.; Bouloussa, O.; Rondelez, F. Microbiology 2005, 151, 1341. doi: 10.1099/mic.0.27526-0
1. [1]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
2. [2]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
3. [3]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
4. [4]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
9. [9]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
10. [10]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
14. [14]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
15. [15]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
18. [18]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
19. [19]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
20. [20]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1119)
HTML views(201)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142