Synthesis and Properties of an All-Conjugated Polythio-phene-Polyselenophene Diblock Copolymer
- Corresponding author: Peng Juan, juanpeng@fudan.edu.cn
Citation: Cui Huina, Qiu Feng, Peng Juan. Synthesis and Properties of an All-Conjugated Polythio-phene-Polyselenophene Diblock Copolymer[J]. Acta Chimica Sinica, ;2018, 76(9): 691-700. doi: 10.6023/A18040178
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The black curve represents the GPC profile of P3HS synthesized in the first step, and the red curve shows the GPC profile of the final P3HT-b-P3THPHT
The ratio of chloroform/pyridine is (a) 0:100, (b) 20:80, (c) 40:60 and (d) 60:40, respectively. The inset in (d) is the corresponding SAED pattern.
Ratio of methanol/pyridine is (a) 20:80 and (b) 40:60.
(a) as-cast P3HT film; (b, c) P3HT film annealed at (b) 170 ℃ and (c) 200 ℃ for 1 h, respectively; (d) as-cast P3HS-b-P3HHT film and (e) P3HS-b-P3HHT film annealed at 200 ℃ for 1 h
(a, d) P3HS-b-P3HHT (5%)/P3HT; (b, e) P3HS-b-P3HHT (10%)/P3HT; (c, f) P3HS-b-P3HHT (15%)/P3HT blending films