Citation: Wang Ling, Yang Guorui, Wang Jianan, Wang Silan, Peng Shengjie, Yan Wei. Research Progress on Electrospun Materials for Sodium-Ion Batteries[J]. Acta Chimica Sinica, ;2018, 76(9): 666-680. doi: 10.6023/A18040129 shu

Research Progress on Electrospun Materials for Sodium-Ion Batteries

Wang Ling ^a ,
Yang Guorui ^a,b ,
Wang Jianan ^a,c ,
Wang Silan ^a ,
Peng Shengjie ^d ,
Yan Wei ^a,,

a.
Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049
b.
Xi'an Jiaotong University Suzhou Institute, Suzhou 215123
c.
Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an 710049
d.
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016

Corresponding author: Yan Wei, yanwei@xjtu.edu.cn
Received Date: 3 April 2018
Available Online: 6 September 2018
Fund Project: Natural Science Basic Research Plan in Shaanxi Province of China 2017JM2022Natural Science Fund of Jiangsu Province BK20170416China Postdoctoral Science Foundation Funded Project 2014M560225the Fundamental Research Funds for the Central Universities xjj2016052Project supported by the Fundamental Research Funds for the Central Universities (No. xjj2016052), Natural Science Basic Research Plan in Shaanxi Province of China (No. 2017JM2022), Natural Science Fund of Jiangsu Province (No. BK20170416) and China Postdoctoral Science Foundation Funded Project (No. 2014M560225)

Figures(10)

The scarce lithium resources would ultimately fail to satisfy the ever-growing industrial demand, especially for the large-scale stationary energy storage. Sodium-ion batteries (SIBs) are considered as promising next-generation power sources because sodium is widely available and exhibits similar chemistry to that of lithium-ion batteries (LIBs). Although sodium share similar physical and chemical properties to lithium, the lager ionic radius, heavier molar mass and less negative redox potential of Na⁺/Na of the sodium jointly lead to some issues beset the SIBs, such as sluggish sodiation kinetics, larger volume expansion and lower energy density, which need to be tackled to promote the practical applications of the SIBs. Therefore, developing appropriate electrode materials is crucial to achieve SIBs with long lifespan and high energy density. One-dimensional nanostructures can provide orientated electronic (ionic) transport and strong tolerance to volume change, thus enhancing the electrochemical performance of electrode materials. Electrospinning technique is a low cost and versatile method to fabricate continuous one-dimensional functional materials with various morphology and targeted components that has been widely applied in SIBs. The volume change could be buffered efficiently by facilely modifying the morphology of electrospun materials or in-situ compositing with carbon materials. Benefiting from the ultra-high aspect ratio, electrospun one-dimensional electrodes can reduce the ionic transport distance, while provide continuous transport way for electron along the longitudinal direction, which is helpful to improve the sluggish sodiation kinetics. It is also worth noting that free-standing or flexible fibers could be easily obtained via the electrospinning technique, which can be used as binder-free electrode to enhance the energy density of the batteries. The research progress on electrospun materials for sodium-ion batteries is summarized in this review, including cathode materials and anode materials. Their electrochemical performance in sodium storage is discussed in detail. The advantages and challenges of these materials were pointed out, and the future development of electrospun materials for sodium ion batteries was also prospected.
- sodium-ion batteries,
- electrospinning,
- cathode materials,
- anode materials,
- nanofiber,
- binder-free
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