Citation: Zhu Mingjing, Peng Juan, Tang Ping, Qiu Feng. Preparation and Characterization of Highly Stable and Aqueous Dispersion of Conjugated Polyelectrolyte/Single-Walled Carbon Nanotube Nanocomposites[J]. Acta Chimica Sinica, ;2018, 76(6): 453-459. doi: 10.6023/A18030090 shu

Preparation and Characterization of Highly Stable and Aqueous Dispersion of Conjugated Polyelectrolyte/Single-Walled Carbon Nanotube Nanocomposites

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China

Corresponding author: Peng Juan, juanpeng@fudan.edu.cn
Received Date: 6 March 2018
Available Online: 20 June 2018
Fund Project: the National Natural Science Foundation of China 21674024Ministry of Science and Technology of China 2016YFA0203301the National Natural Science Foundation of China 21320102005the National Natural Science Foundation of China 21274029Project supported by the National Natural Science Foundation of China (Nos. 21674024, 21274029, 21320102005) and Ministry of Science and Technology of China (No. 2016YFA0203301)

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The dispersion of single-walled carbon nanotubes (SWNTs) is a key point to develop their extensive applications. Especially, to meet the requirements of future green chemistry, the preparation of environmentally-friendly, highly stable and well-distributed SWNTs in aqueous solution becomes particularly important. Based on it, a water-soluble conjugated polyelectrolyte, namely poly[3-[6-(N-methylimidazolium)hexyl]thiophene] (P3MHT) was designed and used to disperse SWNTs through non-covalent strategy. P3MHT was synthesized by a modified Grignard metathesis (GRIM) polymerization followed by quaternization of the bromohexyl side groups of the poly[3-(6-bromohexyl)thiophene] with N-methylimidazole. The P3MHT/SWNTs nanocomposites were prepared by mixing P3MHT and SWNTs in water during ultrasonication followed by centrifugation. UV-vis absorption spectroscopy, photoluminescence (PL) spectroscopy, transmission electron microscope (TEM), Zeta-nano electric potential analyzer, thermogravimetric (TGA) analysis were applied to characterize P3MHT/SWNTs nanocomposites. Compared to the commercial sodium dodecyl sulfate (SDS) surfactant to disperse SWNTs in aqueous solution, P3MHT exhibited a much better ability to disperse SWNTs under the same condition, i.e., the concentration of SWNTs dispersed by P3MHT was about two times than that of SWNTs dispersed by SDS. In P3MHT/SWNTs nanocomposite solution, SWNTs were exfoliated to form individuals or small bundles with an average size of 298 nm. However, in SDS/SWNTs solution, SWNTs preferred to form small aggregates with an average size of more than 500 nm. The P3MHT backbones were wrapped around individual SWNTs via π-π interactions to form the charge-transfer complexes. The ionic side chains of P3MHT not only made the nanocomposites dispersed in water, but also prevented the aggregation of SWNTs by electrostatic repulsion, resulting in aqueous dispersion of P3MHT/SWNTs nanocomposites. While SDS molecules were adsorbed on the surface of SWNTs via hydrophobic alkyl chains, which was much weaker than the π-π interactions between P3MHT and SWNTs. Such P3MHT/SWNTs nanocomposite solution exhibited high stability which remained almost unchanged after 6 months while SDS/SWNTs nanocomposite had already precipitated then. Overall, it provides a promising and simple method to develop highly stable and water processed SWNTs.
- conjugated polyelectrolytes,
- single-walled carbon nanotubes (SWNTs),
- aqueous dispersion,
- stability
1. [1]
  Jariwala, D.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C. Chem. Soc. Rev. 2013, 42, 2824. doi: 10.1039/C2CS35335K
2. [2]
  Qiu, C.; Zhang, Z.; Xiao, M.; Yang, Y.; Zhong, D.; Peng, L. M. Science 2017, 355, 271. doi: 10.1126/science.aaj1628
3. [3]
  Liu, S.; Guo, X. F. Acta Chim. Sinica 2013, 71, 478(in Chinese).
4. [4]
  Zhang, S.; Kang, L.; Wang, X.; Tong, L.; Yang, L.; Wang, Z.; Qi, K.; Deng, S.; Li, Q.; Bai, X.; Ding, F.; Zhang, J. Nature 2017, 543, 234. doi: 10.1038/nature21051
5. [5]
  Yang, F.; Wang, X.; Zhang, D.; Yang, J.; Luo, D.; Xu, Z.; Peng, F.; Li, X.; Li, R.; Li, Y.; Li, M.; Bai, X.; Ding, F.; Li, Y. Nature 2014, 510, 522. doi: 10.1038/nature13434
6. [6]
  Li, L.; Jia, G. X.; Wang, X. X.; Wu, T. W.; Song, X. W.; An, S. L. Acta Chim. Sinica 2017, 75, 284(in Chinese). doi: 10.7503/cjcu20160630
7. [7]
  Rösner, B.; Guldi, D. M.; Chen, J.; Minett, A. I.; Fink, R. H. Nanoscale 2014, 6, 3695. doi: 10.1039/c3nr05788g
8. [8]
  Sang, W. K.; Kim, T.; Kim, Y. S.; Hong, S. C.; Lim, H. J.; Yang, S. J.; Park, C. R. Carbon 2012, 50, 3. doi: 10.1016/j.carbon.2011.08.011
9. [9]
  Guo, L. H.; Gong, L. H.; Yuan, F. L.; Zhang, B.; Bai, X. D.; Lian, Y. F. Acta Chim. Sinica 2005, 63, 1936(in Chinese). doi: 10.3321/j.issn:0567-7351.2005.20.016
10. [10]
  Lin, G. F.; Meng, L. J.; Zhang, X. K.; Lu, Q. H. Prog. Chem. 2010, 22, 331(in Chinese).
11. [11]
  Singh, P.; Campidelli, S.; Giordani, S.; Bonifazi, D.; Bianco, A.; Prato, M. Chem. Soc. Rev. 2009, 38, 2214. doi: 10.1039/b518111a
12. [12]
  Liang, L.; Xie, W.; Fang, S.; He, F.; Yin, B.; Tlili, C.; Wang, D.; Qiu, S.; Li, Q. J. Mater. Chem. C 2017, 5, 11339. doi: 10.1039/C7TC04390B
13. [13]
  Samanta, S. K.; Fritsch, M.; Scherf, U.; Gomulya, W.; Bisri, S. Z.; Loi, M. A. Acc. Chem. Res. 2014, 47, 2446. doi: 10.1021/ar500141j
14. [14]
  Lee, H. W.; Yoon, Y.; Park, S.; Oh, J. H.; Hong, S.; Liyanage, L. S.; Wang, H.; Morishita, S.; Patil, N.; Park, Y. J.; Spakowitz, A.; Galli, G.; Gygi, F.; Wong, P. H.-S.; Tok, J. B.-H.; Kim, J. M.; Bao, Z. Nat. Commun. 2011, 2, 541. doi: 10.1038/ncomms1545
15. [15]
  Yang, H.; Bezugly, V.; Kunstmann, J.; Filoramo, A.; Cuniberti, G. ACS Nano 2015, 9, 9012. doi: 10.1021/acsnano.5b03051
16. [16]
  Liu, Z.; Li, H.; Qiu, Z.; Zhang, S. L.; Zhang, Z. B. Adv. Mater. 2012, 24, 3633. doi: 10.1002/adma.v24.27
17. [17]
  Yang, S.; Meng, D.; Sun, J.; Yan, H.; Yong, H.; Geng, J. ACS Appl. Mater. Interfaces 2014, 6, 7686. doi: 10.1021/am500973m
18. [18]
  Derenskyi, V.; Gomulya, W.; Rios, J. M.; Fritsch, M.; Fröhlich, N.; Jung, S.; Allard, S.; Bisri, S. Z.; Gordiichuk, P.; Herrmann, A.; Scherf, U.; Loi, M. A. Adv. Mater. 2014, 26, 5969. doi: 10.1002/adma.201401395
19. [19]
  Mai, C. K.; Liu, J.; Evans, C. M.; Segalman, R. A.; Chabinyc, M. L.; Cahill, D. G.; Bazan, G. C. Macromolecules 2016, 49, 4957. doi: 10.1021/acs.macromol.6b00546
20. [20]
  Li, Y.; Mai, C. K.; Phan, H.; Liu, X.; Nguyen, T. Q.; Bazan, G. C.; Chan-Park, M. B. Adv. Mater. 2014, 26, 4697. doi: 10.1002/adma.v26.27
21. [21]
  Kang, Y. K.; Lee, O. S.; Deria, P.; Sang, H. K.; Park, T. H.; Bonnell, D. A.; Saven, J. G.; Therien, M. J. Nano Lett. 2009, 9, 1414. doi: 10.1021/nl8032334
22. [22]
  Deria, P.; Olivier, J. H.; Park, J.; Therien, M. J. J. Am. Chem. Soc. 2014, 136, 14193. doi: 10.1021/ja507457z
23. [23]
  Mai, C. K.; Russ, B.; Fronk, S. L.; Hu, N.; Chan-Park, M. B.; Urban, J. J.; Segalman, R. A.; Chabinyc, M. L.; Bazan, G. C. Energy Environ. Sci. 2015, 8, 2341. doi: 10.1039/C5EE00938C
24. [24]
  Osaka, I.; Mccullough, R. D. Acc. Chem. Res. 2008, 41, 1202. doi: 10.1021/ar800130s
25. [25]
  He, M.; Zhao, L.; Wang, J.; Han, W.; Yang, Y.; Qiu, F.; Lin, Z. ACS Nano 2010, 4, 3241. doi: 10.1021/nn100543w
26. [26]
  He, M.; Ge, J.; Lin, Z.; Feng, X.; Wang, X.; Lu, H.; Yang, Y.; Qiu, F. Energy Environ. Sci. 2012, 5, 8351. doi: 10.1039/c2ee21803h
27. [27]
  Pan, S.; He, L.; Peng, J.; Qiu, F.; Lin, Z. Angew. Chem. Int. Ed. 2016, 55, 8686. doi: 10.1002/anie.201603189
28. [28]
  Yang, X.; Ge, J.; He, M.; Ye, Z.; Liu, X.; Peng, J.; Qiu, F. Macromolecules 2016, 49, 287. doi: 10.1021/acs.macromol.5b02001
29. [29]
  Zhu, M.; Kim, H.; Yu, J. J.; Park, S.; Du, Y. R.; Kim, K.; Tang, P.; Qiu, F.; Kim, D. H.; Peng, L. J. Mater. Chem. A 2016, 4, 18432. doi: 10.1039/C6TA08181A
30. [30]
  Xia, H.; Ye, Z.; Liu, X.; Peng, J.; Qiu, F. RSC Adv.2014, 4, 19646. doi: 10.1039/c4ra01127a
31. [31]
  Duarte, A.; Pu, K. Y.; Liu, B.; Bazan, G. C. Chem. Mater. 2011, 23, 501. doi: 10.1021/cm102196t
32. [32]
  Feng, L.; Zhu, C.; Yuan, H.; Liu, L.; Lv, F.; Wang, S. Chem. Soc. Rev. 2013, 42, 6620. doi: 10.1039/c3cs60036j
33. [33]
  Rochat, S.; Swager, T. M. ACS Appl. Mater. Interfaces 2013, 5, 4488. doi: 10.1021/am400939w
34. [34]
  Ghoos, T.; Malinkiewicz, O.; Conings, B.; Lutsen, L.; Vanderzande, D. J.; Bolink, H. J.; Maes, W. RSC Adv. 2013, 3, 25197. doi: 10.1039/c3ra43986k
35. [35]
  Liang, S.; Zhao, Y.; Adronov, A. J. Am. Chem. Soc. 2014, 136, 970. doi: 10.1021/ja409918n
36. [36]
  Bounioux, C.; Bar-Hen, A.; Yerushalmi-Rozen, R. Chem. Commun. 2015, 51, 6343. doi: 10.1039/C5CC00802F
37. [37]
  Chen, J.; Liu, H.; Weimer, W. A.; Halls, M. D.; Waldeck, D. H.; Walker, G. C. J. Am. Chem. Soc. 2002, 124, 9034. doi: 10.1021/ja026104m
38. [38]
  Rao, G. P.; Lu, C.; Su, F. Sep. Purif. Technol. 2007, 58, 224. doi: 10.1016/j.seppur.2006.12.006
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