Citation: Li Haofei, Qiao Fulin, Fan Yaxun, Wang Yilin. Aggregation in the Mixture of Branched Carboxylate Salts and Sulfonate Surfactants with Different Oligomeric Degrees[J]. Acta Chimica Sinica, ;2018, 76(7): 564-574. doi: 10.6023/A18030086 shu

Aggregation in the Mixture of Branched Carboxylate Salts and Sulfonate Surfactants with Different Oligomeric Degrees

Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190;University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Wang Yilin, yilinwang@iccas.ac.cn
Received Date: 3 March 2018
Available Online: 3 July 2018
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21633002)the National Natural Science Foundation of China 21633002

Figures(7)

Understanding the effects of molecules with branched structures on surface activities and micellization of star-shaped oligomeric surfactants will promote the applications of oligomeric surfactants. The present work has studied the interactions and aggregation of branched carboxylate 2-hexyldecanoic acid (HDA) and 2, 2, 4, 8, 10, 10-hexamethylundecane-5-carboxylic acid (HMLCA) with single chain sodium dodecyl sulfonate (SDoS) and star-shaped tetrameric sulfonate surfactant (EDA-(C₁₂SO₃Na)₄) in aqueous solution of pH 11 by surface tension, ζ-Potential and small angle neutron scattering (SANS). Surface tension measurements have shown that the addition of HDA or HMLCA can significantly reduce the surface tension at critical micellar concentration (CMC), meanwhile, the CMC values increase slightly as the mole fraction of HDA or HMLCA increases. The interaction parameter (β), calculated according to the non-ideal mixed solution model, indicate that different interaction degrees exist between branched carboxylate and sulfonate surfactant on surface activities and micellization. The four mixtures all exhibit synergism in surface tension reduction efficiency. The mixtures of single chain sulfonate surfactant and branched carboxylate also exhibit synergism in micelle formation, whereas the mixtures of tetrameric sulfonate surfactant and branched carboxylate do not, although the attractive interaction of HDA/EDA-(C₁₂SO₃Na)₄ and HMLCA/EDA-(C₁₂SO₃Na)₄ is stronger than that of HDA/SDoS and HMLCA/SDoS in mixed micelles. Taking HDA as a representative, SANS and ζ-Potential results reveal that the addition of HDA into these two sulfonate surfactants leads to different aggregate transitions in the solution. For HDA/SDoS, when the molar fraction of HDA (X_HDA) is constant and the total surfactant concentration increases, spherical micelles transfer into rod-like micelles. For the HDA/EDA-(C₁₂SO₃Na)₄ mixture, the rod-like micelles become shorter as X_HDA increases at a fixed total surfactant concentration, while the rod-like micelles are growing longer with increasing X_HDA at a fixed total surfactant concentration. This observation suggests that the branched structure of carboxylates can improve the aggregation ability of the mixed system. In addition these mixtures show excellent performance at emulsifying dodecane, and HDA or HMLCA can greatly reduce the dosage of sulfonate surfactants.
- star-shaped oligomeric surfactant,
- SANS,
- surface tension,
- interaction,
- aggregate
1. [1]
  Zana, R. Adv. Colloid Interface Sci. 2002, 97, 205. doi: 10.1016/S0001-8686(01)00069-0
2. [2]
  Han, Y. C.; Fan, Y. X.; Wu, C. X.; Hou, Y. B.; Wang, Y. L. Sci. Sin. Chem. 2015, 45, 327(in Chinese).
3. [3]
  Yoshimura, T.; Ohno, A.; Esumi, K. J. Colloid Interface Sci. 2004, 272, 191. doi: 10.1016/j.jcis.2003.12.021
4. [4]
  Yoshimura, T.; Yoshida, H.; Ohno, A.; Esumi, K. J. Colloid Interface Sci. 2003, 267, 167. doi: 10.1016/S0021-9797(03)00694-5
5. [5]
  In, M.; Bec, V.; Aguerre-Chariol, O.; Zana, R. Langmuir 2000, 16, 141. doi: 10.1021/la990645g
6. [6]
  In, M.; Aguerre-Chariol, O.; Zana, R. J. Phys. Chem. B 1999, 103, 7747. doi: 10.1021/jp9919922
7. [7]
  Danino, D.; Talmon, Y.; Levy, H.; Zana, R. Science 1995, 269, 1420. doi: 10.1126/science.269.5229.1420
8. [8]
  Esumi, K.; Taguma, K.; Koide, Y. Langmuir 1996, 12, 4039. doi: 10.1021/la960230k
9. [9]
  Kastner, U.; Zana, R. J. Colloid Interface Sci. 1999, 218, 468. doi: 10.1006/jcis.1999.6438
10. [10]
  Zana, R.; Levy, H.; Papoutsi, D.; Beinert, G. Langmuir 1995, 11, 3694. doi: 10.1021/la00010a018
11. [11]
  Menger, F. M.; Migulin, V. A. J. Org. Chem. 1999, 64, 8916. doi: 10.1021/jo9912350
12. [12]
  Menger, F. M.; Keiper, J. S. Angew. Chem. Int. Ed. 2000, 39, 1906. doi: 10.1002/(ISSN)1521-3773
13. [13]
  Laschewsky, A.; Wattebled, L.; Arotcarena, M.; Habib-Jiwan, J.; Rakotoaly, R. H. Langmuir 2005, 21, 7170. doi: 10.1021/la050952o
14. [14]
  Wattebled, L.; Laschewsky, A.; Moussa, A.; Habib-Jiwan, J. Langmuir 2006, 22, 2551. doi: 10.1021/la052414h
15. [15]
  Yoshimura, T.; Esumi, K. Langmuir 2003, 19, 3535. doi: 10.1021/la026762k
16. [16]
  Sumida, Y.; Oki, T.; Masuyama, A.; Maekawa, H.; Nishiura, M.; Kida, T.; Nakatsuji, Y.; Ikeda, I.; Nojima, M. Langmuir 1998, 14, 7450. doi: 10.1021/la980814h
17. [17]
  Hou, Y. B.; Han, Y. C.; Deng, M. L.; Xiang, J. F.; Wang, Y. L. Langmuir 2010, 26, 28. doi: 10.1021/la903672r
18. [18]
  Wu, C. X.; Hou, Y. B.; Deng, M. L.; Huang, X.; Xiang, J. F.; Liu, Y.; Li, Z. B.; Wang, Y. L. Langmuir 2010, 26, 7922. doi: 10.1021/la9048067
19. [19]
  Fan, Y. X.; Hou, Y. B.; Xiang, J. F.; Yu, D. F.; Wu, C. X.; Tian, M. Z.; Wang, Y. L. Langmuir 2011, 27, 10570. doi: 10.1021/la202453c
20. [20]
  Murguia, M. C.; Cabrera, M. I.; Guastavino, J. E.; Grau, R. J. Colloids Surf., A 2005, 262, 1. doi: 10.1016/j.colsurfa.2005.03.018
21. [21]
  Zhou, C. C.; Wang, F. Y.; Chen, H.; Li, M.; Qiao, F. L.; Liu, Z.; Hou, Y. B.; Wu, C. X.; Fan, Y. X.; Liu, L. B.; Wang, S.; Wang, Y. L. ACS Appl. Mater. Interfaces 2016, 8, 4242. doi: 10.1021/acsami.5b12688
22. [22]
  Zhou, C. C.; Wang, D.; Cao, M. W.; Chen, Y.; Liu, Z.; Wu, C. X.; Xu, H.; Wang, S.; Wang, Y. L. ACS Appl Mater Interfaces 2016, 8, 30811. doi: 10.1021/acsami.6b11667
23. [23]
  Jurasin, D.; Habus, I.; Filipovic-Vincekovic, N. Colloids Surf., A 2010, 368, 119. doi: 10.1016/j.colsurfa.2010.07.025
24. [24]
  Qiao, F. L.; Wang, M. N.; Liu, Z.; Fan, Y. X.; Wang, Y. L. Chem. Asian J. 2016, 11, 2763. doi: 10.1002/asia.201600432
25. [25]
  Tian, M. Z.; Fan, Y. X.; Ji, G.; Wang, Y. L. Langmuir 2012, 28, 12005. doi: 10.1021/la301762g
26. [26]
  Wang, T. F.; Shang, Y. Z.; Peng, C. J.; Liu, H. L. Acta Chim. Sinica 2009, 67, 1159(in Chinese).
27. [27]
  Sadeghi, R.; Shahabi, S. J. Chem. Thermodynamics 2011, 43, 1361. doi: 10.1016/j.jct.2011.04.012
28. [28]
  Xu, G. Y.; Gu, Y. H.; Zeng, L. R.; Zhu, H. P.; Mao, H. Z. Acta Phys. Chim. Sin. 1992, 8, 352(in Chinese). doi: 10.3866/PKU.WHXB19920313
29. [29]
  Zhu, B. Y.; Zhao, G. X. Fine Chemicals 1985, 2, 1(in Chinese).
30. [30]
  Vora, S.; George, A.; Desai, H.; Bahadur, P. J. Surfactants Deterg. 1999, 2, 213. doi: 10.1007/s11743-999-0076-5
31. [31]
  Singh, O. G.; Ismail, K. J. Surfactants Deterg. 2008, 11, 89. doi: 10.1007/s11743-007-1058-y
32. [32]
  Azum, N.; Naqvi, A. Z.; Akram, M.; Kabir-ud-Din J. Colloid Interface Sci. 2008, 328, 429. doi: 10.1016/j.jcis.2008.09.034
33. [33]
  Xue, J. Y.; Liu, T. S.; Liu, Y. C. J. Dispersion Sci. Technol. 2012, 33, 599. doi: 10.1080/01932691.2010.548279
34. [34]
  Hayter, J. B.; Penfold, J. Colloid Polym. Sci. 1983, 261, 1022. doi: 10.1007/BF01421709
35. [35]
  Tanford, C. J. Phys. Chem. 1972, 76, 3020. doi: 10.1021/j100665a018
36. [36]
  Chen, Z. D.; Penfold, J.; Li, P. X.; Doutch, J.; Fan, Y. X.; Wang, Y. L. Soft Matter 2017, 13, 8980. doi: 10.1039/C7SM02058A
37. [37]
  Holland, P. M.; Rubingh, D. N. J. Phys. Chem. 1983, 87, 1984. doi: 10.1021/j100234a030
38. [38]
  Rosen, M. J.; Gao, T.; Nakatsuji, Y.; Masuyama, A. Colloids Surf., A 1994, 88, 1. doi: 10.1016/0927-7757(94)80080-4
39. [39]
  Liu, L.; Rosen, M. J. J. Colloid Interface Sci. 1996, 179, 454. doi: 10.1006/jcis.1996.0237
1. [1]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
2. [2]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
5. [5]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
6. [6]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
7. [7]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
8. [8]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
9. [9]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
10. [10]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
11. [11]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
14. [14]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
15. [15]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
16. [16]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
17. [17]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
18. [18]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1482)
HTML views(158)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142