Citation: Zhu Xuewei, Cui Xiaoyu, Cai Wensheng, Shao Xueguang. Temperature Dependent Near Infrared Spectroscopy for Understanding the Hydrogen Bonding of Amines[J]. Acta Chimica Sinica, ;2018, 76(4): 298-302. doi: 10.6023/A18010003 shu

Temperature Dependent Near Infrared Spectroscopy for Understanding the Hydrogen Bonding of Amines

Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin Key Laboratory of Biosensing and Molecular Recognition, State Key Laboratory of Medicinal Chemical Biology, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300071

Corresponding author: Shao Xueguang, xshao@nankai.edu.cn
Received Date: 3 January 2018
Available Online: 5 April 2018
Fund Project: the National Natural Science Foundation of China 21775046Project supported by the National Natural Science Foundation of China (Nos. 21475068 and 21775046)the National Natural Science Foundation of China 21475068

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Temperature dependent near-infrared (NIR) spectroscopy has been developed for structural analyses, especially for the study of hydrogen bonding, due to the distinct influence of temperature on both intra-and inter-molecular interactions. In this work, the hydrogen bonding of primary aliphatic amines (amylamine, hexylamine and heptylamine) were studied using the NIR spectra measured from 25 to 80℃ with a step of 5℃. Continuous wavelet transform (CWT) was applied to enhance the resolution of the NIR spectra, and independent component analysis (ICA) was adopted for analyzing the temperature effect. High resolution spectra were obtained by CWT, from which the peaks of free and hydrogen-bonded NH groups can be identified. The results obtained by ICA show that three independent components (ICs) can be obtained, corresponding to the spectral information of the free, linearly and cyclically hydrogen-bonded NH groups, respectively. Therefore, with the reconstructed spectra from the three ICs, the variation of the three forms of NH groups with temperature can be analyzed. When temperature increases, the hydrogen-bonded NH groups transform into the free form, and the cyclic form dissociates through the linear form. Furthermore, NIR spectra of the amines in carbon tetrachloride (CCl₄) solution were measured at 25℃ in the concentration range of 0.1~1.0 mol/L. The three ICs can also be obtained by ICA from the spectra after CWT. From the variation of the ICs with concentration, it was shown that NH groups in the amines prefer to be linearly aggregated at low concentration, but the cyclic aggregation increases with the increase of concentration. In addition, a comparison was performed on the results obtained by ICA from the spectra of the three amines measured at different temperatures. The result shows that there is no obvious difference for the temperature effect of the three amines, the variation of the three forms of NH groups with temperature, however, is different. With the increase of the carbon chain length, the variation of free and cyclically hydrogen-bonded NH group slows down, but there is a slight increase for the change rate of linearly hydrogen-bonded NH group. Therefore, temperature dependent near-infrared (NIR) spectroscopy may provide a new tool for studying the hydrogen bonding in liquid and solution samples with the help of chemometric calculations. The method may be promising for analyzing the complicated interactions in bio-systems, particularly the hydrogen bonding or inter-and intra-molecular interactions.
- near-infrared spectroscopy,
- temperature effect,
- primary aliphatic amine,
- independent component analysis,
- hydrogen bonding
1. [1]
  Wang, Y.; Murayama, K.; Myojo, Y.; Tsenkova, R.; Hayashi, N.; Ozaki, Y. J. Phys. Chem. B 1998, 102, 6655. doi: 10.1021/jp9816115
2. [2]
  Wu, Y. Q.; Czarnik-Matusewicz, B.; Murayama, K.; Ozaki, Y. J. Phys. Chem. B 2000, 104, 5840. doi: 10.1021/jp000537z
3. [3]
  Yuan, B.; Murayama, K.; Wu, Y. Q.; Tsenkova, R.; Dou, X. M.; Era, S.; Ozaki, Y. Appl. Spectrosc. 2003, 57, 1223. doi: 10.1366/000370203769699072
4. [4]
  Xu, Y.; Wu, P. Y. Acta Chim. Sinica 2008, 66, 1903(in Chinese). doi: 10.3321/j.issn:0567-7351.2008.16.010
5. [5]
  Shao, X. G.; Kang, J.; Cai, W. S. Talanta 2010, 82, 1017. doi: 10.1016/j.talanta.2010.06.009
6. [6]
  Kang, J.; Cai, W. S.; Shao, X. G. Talanta 2011, 85, 420. doi: 10.1016/j.talanta.2011.03.089
7. [7]
  Shan, R. F.; Zhao, Y.; Fan, M. L.; Liu, X. W.; Cai, W. S.; Shao, X. G. Talanta 2015, 131, 170. doi: 10.1016/j.talanta.2014.07.081
8. [8]
  Cui, X. Y.; Cai, W. S.; Shao, X. G. RSC Adv. 2016, 6, 105729. doi: 10.1039/C6RA18912A
9. [9]
  Cui, X. Y.; Liu, X. W.; Yu, X. M.; Cai, W. S.; Shao, X. G. Anal. Chim. Acta 2017, 957, 47. doi: 10.1016/j.aca.2017.01.004
10. [10]
  Liu, X. W.; Cui, X. Y.; Yu, X. M.; Cai, W. S.; Shao, X. G. Chin. Chem. Lett. 2017, 28, 1447. doi: 10.1016/j.cclet.2017.03.021
11. [11]
  Qi, L. H.; Cai, W. S.; Shao, X. G. Acta Chim. Sinica 2016, 74, 172. (in Chinese).
12. [12]
  Wei, Y. R.; Yang, X. D.; Ma, Y. R.; Wang, S. F.; Yuan, Q. Chin. J. Chem. 2016, 34, 558. doi: 10.1002/cjoc.v34.6
13. [13]
  Czarnecki, M. A.; Morisawa, Y.; Futami, Y.; Ozaki, Y. Chem. Rev. 2015, 115, 9707. doi: 10.1021/cr500013u
14. [14]
  Segtnan, V. H.; Šašić, Š.; Isaksson, T.; Ozaki, Y. Anal. Chem. 2001, 73, 3153. doi: 10.1021/ac010102n
15. [15]
16. [16]
  Czarnik-Matusewicz, B.; Pilorz, S. Vib. Spectrosc. 2006, 40, 235. doi: 10.1016/j.vibspec.2005.10.002
17. [17]
  Czarnecki, M. A. J. Phys. Chem. A 2000, 104, 6356. doi: 10.1021/jp000407q
18. [18]
  Pauling, L.; Corry, R. B.; Branson, H. R. Proc. Natl. Acad. Sci. U. S. A. 1951, 37, 205. doi: 10.1073/pnas.37.4.205
19. [19]
  Watson, J. D.; Crick, F. H. Nature 1953, 171, 737. doi: 10.1038/171737a0
20. [20]
  Conley, R. T. Infrared Spectroscopy, Allyn and Bacon, Boston, MA, 1996, Chapter 7.
21. [21]
  Sinsheimer, J. E.; Keuhnelian, A. M. Anal. Chem. 1974, 46, 89. doi: 10.1021/ac60337a011
22. [22]
  Kang, J.; Cai, W. S.; Shao, X. G. Talanta 2011, 85, 420. doi: 10.1016/j.talanta.2011.03.089
23. [23]
  Shao, X. G.; Leung, A. K. M.; Chau, F. T. Acc. Chem. Res. 2003, 36, 276. doi: 10.1021/ar990163w
24. [24]
  Shan, R. F.; Cai, W. S.; Shao, X. G. Chemon. Intell. Lab. Syst. 2014, 131, 31. doi: 10.1016/j.chemolab.2013.12.002
25. [25]
  Ni, Y. N.; Wang, Y.; Kokot, S. Talanta 2009, 78, 432. doi: 10.1016/j.talanta.2008.11.035
26. [26]
  Peng, D.; Xu, K. X.; Li, C. X. Spectrosc. Spect. Anal. 2008, 28, 825(in Chinese). doi: 10.3964/j.issn.1000-0593.2008.04.026
27. [27]
  Ma, C. X.; Shao, X. G. J. Chem. Inf. Comput. Sci. 2004, 44, 907. doi: 10.1021/ci034211+
28. [28]
  Shao, X. G.; Wang, F.; Chen, D.; Su, Q. D. Anal. Bioanal. Chem. 2004, 378, 1382. doi: 10.1007/s00216-003-2397-9
29. [29]
  Shao, X. G.; Ma, C. X. Chemom. Intell. Lab. Syst. 2003, 69, 157. doi: 10.1016/j.chemolab.2003.08.001
30. [30]
  Stordrange, L.; Christy, A. A.; Kvalheim, O. M.; Shen, H. L.; Liang, Y. Z. J. Phys Chem. A 2002, 106, 8543. doi: 10.1021/jp013670f
31. [31]
  Comon, P. Signal Process. 1994, 36, 287. doi: 10.1016/0165-1684(94)90029-9
32. [32]
  Chen, J.; Wang, X. Z. J. Chem. Inf. Comput. Sci. 2001, 41, 992. doi: 10.1021/ci0004053
33. [33]
  Shao, X. G.; Wang, W.; Hou, Z. Y.; Cai, W. S. Talanta 2006, 69, 676. doi: 10.1016/j.talanta.2005.10.039
34. [34]
  Fang, L. M.; Lin, M. Acta Chim. Sinica 2008, 66, 1791(in Chinese).
35. [35]
  Pasadakis, N.; Kardamakis, A. A. Anal. Chim. Acta 2006, 578, 250. doi: 10.1016/j.aca.2006.06.072
36. [36]
  Bi, X.; Li, T. H.; Wu, L. Chem. J. Chin. Univ. 2004, 25, 1023(in Chinese). doi: 10.3321/j.issn:0251-0790.2004.06.006
37. [37]
  Shao, X. G.; Wang, G. Q.; Wang, S. F.; Su, Q. D. Anal. Chem. 2014, 76, 5143.
38. [38]
  Wang, G.; Cai, W. S.; Shao, X. G. Chemom. Intell. Lab. Syst. 2006, 82, 137. doi: 10.1016/j.chemolab.2005.05.009
39. [39]
  Zhang, M. J.; Tong, P. J.; Wang, W. M.; Geng, J. P.; Du, Y. P. Chemom. Intell. Lab. Syst. 2011, 105, 207. doi: 10.1016/j.chemolab.2011.01.007
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