Citation: He Qian, Zhang Chong, Li Xiao, Wang Xue, Mu Pan, Jiang Jiaxing. Pyrene-Based Conjugated Microporous Polymer as High Performance Electrode for Lithium-Ion Batteries[J]. Acta Chimica Sinica, ;2018, 76(3): 202-208. doi: 10.6023/A17110477 shu

Pyrene-Based Conjugated Microporous Polymer as High Performance Electrode for Lithium-Ion Batteries

School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, China

Corresponding author: Jiang Jiaxing, jiaxing@snnu.edu.cn
Received Date: 2 November 2017
Available Online: 4 March 2017
Fund Project: the National Natural Science Foundation of China 21304055the National Natural Science Foundation of China 21574077Project supported by the National Natural Science Foundation of China (Nos. 21574077, 21304055)

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Lithium ion batteries (LIBs) have been recognized as one of the most popular and promising energy storage devices because of their high energy density and cyclability. The leading electrode materials for LIBs are mainly based on inorganic compounds materials because of their excellent electrochemical performances. Compared with inorganic compounds or metal-based electrode materials, organic electrode materials have been less explored for LIBs, but they are promising because of their synthetic diversity, flexible framework, low cost and environmental benignity. Unlike organic small molecules and linear polymers electrodes, which show low surface area and are soluble in electrolyte leading to the low electrochemical performance, conjugated microporous polymers (CMPs) feature with large specific surface area, good physicochemical stability, unique extended π-conjugation along the polymer skeleton and high crosslinked degree, which make CMPs great potential as electrodes for LIBs. In this work, a pyrene-based conjugated microporous polymer (PyDB) has been synthesized via palladium-catalyzed Suzuki cross-coupling reaction from tetrabromopyrene and 1, 4-benzenediboronic acid. PyDB is insoluble in common organic solvents tested because of its highly crosslinked polymer structure. Thermogravimetric analysis indicated that the polymer is thermally stable up to 430℃ in nitrogen atmosphere. Nitrogen adsorption-desorption measurement revealed that PyDB has a high Brunauer-Emmet-Teller specific surface area of up to 1283 m²·g^-1. PyDB based electrode for LIBs exhibited excellent electrochemical performance. The assembled LIB from PyDB as cathode material shows a discharge capacity of 163 mAh·g^-1 at a current density of 50 mA·g^-1 with a high capacitance retention of 167 mAh·g^-1 after 300 cycles at a current density of 100 mA·g^-1. When PyDB was used as anode material, the assembled LIB also exhibits a high capacity of 495 mAh·g^-1 at 50 mA·g^-1 with a high capacitance retention of 245 mAh·g^-1 after 300 cycles at 200 mA·g^-1. The excellent electrochemical performance of PyDB could be attributed to its extended π-conjugation structure and porous structure with high surface area, the extended π-conjugation is beneficial to the doping reaction and electronic conduction, while porous structure with high surface area can provide plentiful active sites and promote the transmission of ions.
- conjugated microporous polymer,
- tetrabromopyrene,
- lithium-ion battery,
- electrode material
1. [1]
  Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644
2. [2]
  Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
3. [3]
  Qiu, Z. P.; Zhang, Y. J.; Xia, S. B.; Dong, P. Acta Chim. Sinica 2015, 73, 992.
4. [4]
  Zhang, C.; Yang, X.; Ren, W. F.; Wang, Y. H.; Su, F. B.; Jiang, J.-X. J. Power Sources 2016, 317, 49. doi: 10.1016/j.jpowsour.2016.03.080
5. [5]
  Zheng, Z.; Wu, Z. G.; Xiang, W.; Guo, X. D. Acta Chim. Sinica 2017, 75, 501. doi: 10.11862/CJIC.2017.053
6. [6]
  Zhang, G. B.; Xiong, T. F.; Pan, X. L.; Yan, M. Y.; Han, C. H.; Mai, L. Q. Acta Chim. Sinica 2016, 74, 582.
7. [7]
  Zhang, C.; Kong, R.; Wang, X.; Xu, Y. F.; Wang, F.; Ren, W. F.; Wang, Y. H.; Su, F. B.; Jiang, J.-X. Carbon 2017, 114, 608. doi: 10.1016/j.carbon.2016.12.064
8. [8]
  Yu, L. T.; Liu, J.; Xu, X. J.; Zhang, L. G.; Hu, R. Z.; Liu, J. W.; Yang, L. C.; Zhu, M. ACS Appl. Mater. Interfaces 2017, 9, 2516. doi: 10.1021/acsami.6b14233
9. [9]
  Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. Chem. Rev. 2013, 113, 5364. doi: 10.1021/cr3001884
10. [10]
  McDowell, M. T.; Lee, S. W.; Nix, W. D.; Cui, Y. Adv. Mater. 2013, 25, 4966. doi: 10.1002/adma.201301795
11. [11]
  Du, J.; Lin, N.; Qian, Y. T. Acta Chim. Sinica 2017, 75, 147. doi: 10.3969/j.issn.0253-2409.2017.02.003
12. [12]
  Ye, Y.; Zhu, J. Y.; Yao, Y. N.; Wang, Y. G.; Wu, P.; Tang, Y. W.; Zhou, Y. M.; Lu, T. H. Acta Chim. Sinica 2015, 73, 151.
13. [13]
  Luo, F.; Zheng, J. Y.; Chu, G.; Liu, B. N.; Zhang, S. L.; Li, H.; Chen, L. Q. Acta Chim. Sinica 2015, 73, 808.
14. [14]
  Wang, L.; Zhao, D. D.; Liu, X.; Yu, P.; Fu, H. G. Acta Chim. Sinica 2017, 75, 231. doi: 10.7503/cjcu20160577
15. [15]
  Lyv, Z. Y.; Feng, R.; Zhao, J.; Fan, H.; Xu, D.; Wu, Q.; Yang, L. J.; Chen, Q.; Wang, X. Z.; Hu, Z. Acta Chim. Sinica 2015, 73, 1013.
16. [16]
  Yang, Y. Q.; Zhang, Q.; Zhang, S. B.; Li, S. H. Polymer 2013, 54, 5698. doi: 10.1016/j.polymer.2013.08.039
17. [17]
  Xu, Y. H.; Jin, S. B.; Xu, H.; Nagai, A.; Jiang, D. L. Chem. Soc. Rev. 2013, 42, 8012. doi: 10.1039/c3cs60160a
18. [18]
  Dawson, R.; Cooper, A. I.; Adams, D. J. Prog. Polym. Sci. 2012, 37, 530. doi: 10.1016/j.progpolymsci.2011.09.002
19. [19]
  Xu, J. W.; Zhang, C.; Wang, X. C.; Jiang, J. X.; Wang, F. Acta Chim. Sinica 2017, 75, 473.
20. [20]
  Xu, J. W.; Zhang, C.; Qiu, Z. X.; Lei, Z. Y.; Chen, B.; Jiang, J.-X.; Wang, F. Macromol. Chem. Phys. 2017, 218, 1700275. doi: 10.1002/macp.v218.22
21. [21]
  Shu, G.; Zhang, C.; Li, Y. D.; Jiang, J. X.; Wang, X. C.; Li, H.; Wang, F. J. Appl. Polym. Sci. 2017, 10, 45907.
22. [22]
  Zhang, H. J.; Zhang, C.; Wang, X. C.; Qiu, Z. X.; Liang, X. M.; Chen, B.; Xu, J. W.; Jiang, J.-X.; Li, Y. D.; Li, H.; Wang, F. RSC Adv. 2016, 6, 113826. doi: 10.1039/C6RA20765K
23. [23]
  Sprick, R. S.; Jiang, J. X.; Bonillo, B.; Ren, S.; Ratvijitvech, T.; Guiglion, P.; Zwijnenburg, M. A.; Adams, D. J.; Cooper, A. I. J. Am. Chem. Soc. 2015, 137, 3265. doi: 10.1021/ja511552k
24. [24]
  Jiang, J. X.; Wang, C.; Laybourn, A.; Hasell, T.; Clowes, R.; Khimyak, Y. Z.; Xiao, J.; Higgins, S. J.; Adams, D. J.; Cooper, A. I. Angew. Chem. Int. Ed. 2011, 50, 1072. doi: 10.1002/anie.v50.5
25. [25]
  Jiang, J.-X.; Li, Y. Y.; Wu, X. F.; Xiao, J. L.; Adams, D. J.; Cooper, A. I. Macromolecules 2013, 46, 8779. doi: 10.1021/ma402104h
26. [26]
  Xu, Y. F.; Mao, N.; Feng, S.; Zhang, C.; Wang, F.; Chen, Y.; Zeng, J. H.; Jiang, J.-X. Macromol. Chem. Phys. 2017, 218, 1700049. doi: 10.1002/macp.v218.14
27. [27]
  Xu, Y. F.; Zhang, C.; Mu, P.; Mao, N.; Wang, X.; He, Q.; Wang, F.; Jiang, J.-X. Sci. China:Chem. 2017, 60, 1075. doi: 10.1007/s11426-017-9077-0
28. [28]
  Wang, X. Y.; Mu, P.; Zhang, C.; Chen, Y.; Zeng, J. H.; Wang, F.; Jiang, J. X. ACS Appl. Mater. Interfaces 2017, 9, 20779. doi: 10.1021/acsami.7b05345
29. [29]
  Xu, F.; Chen, X.; Tang, Z. W.; Wu, D. C.; Fu, R. W.; Jiang, D. L. Chem. Commun. 2014, 50, 4788. doi: 10.1039/C4CC01002G
30. [30]
  Kou, Y.; Xu, Y. H.; Guo, Z. Q.; Jiang, D. L. Angew. Chem. Int. Ed. 2011, 50, 8753. doi: 10.1002/anie.201103493
31. [31]
  Muench, S.; Wild, A.; Friebe, C.; Haupler, B.; Janoschka, T.; Schubert, U. S. Chem. Rev. 2016, 116, 9438. doi: 10.1021/acs.chemrev.6b00070
32. [32]
  Yang, H.; Zhang, S. L.; Han, L. H.; Zhang, Z.; Xue, Z.; Gao, J.; Li, Y. J.; Huang, C. S.; Yi, Y. P.; Liu, H. B.; Li, Y. L. ACS Appl. Mater. Interfaces 2016, 8, 5366. doi: 10.1021/acsami.5b12370
33. [33]
  Zhang, S. L.; Huang, W.; Hu, P.; Huang, C. S.; Shang, C. Q.; Zhang, C. J.; Yang, R. Q.; Cui, G. L. J. Mater. Chem. A 2015, 3, 1896. doi: 10.1039/C4TA06058J
34. [34]
  Bai, L. Y.; Gao, Q.; Zhao, Y. L. J. Mater. Chem. A 2016, 4, 14106. doi: 10.1039/C6TA06449C
35. [35]
  Haupler, B.; Burges, R.; Friebe, C.; Janoschka, T.; Schmidt, D.; Wild, A.; Schubert, U. S. Macromol. Rapid Commun. 2014, 35, 1367. doi: 10.1002/marc.v35.15
36. [36]
  Yao, M.; Senoh, H.; Sakai, T.; Kiyobayashi, T. J. Power Sources 2012, 202, 364. doi: 10.1016/j.jpowsour.2011.11.035
37. [37]
  Su, C.; He, H. H.; Xu, L. H.; Zhao, K.; Zheng, C. C.; Zhang, C. J. Mater. Chem. A 2017, 5, 2701. doi: 10.1039/C6TA10127E
38. [38]
  Zhang, C.; He, Y. W.; Mu, P.; Wang, X.; He, Q.; Chen, Y.; Zeng, J. H.; Wang, F.; Xu, Y. H.; Jiang, J.-X. Adv. Funct. Mater. 2017, 27, 1705432.
39. [39]
  Jiang, J. X.; Su, F.; Trewin, A.; Wood, C. D.; Campbell, N. L.; Niu, H.; Dickinson, C.; Ganin, A. Y.; Rosseinsky, M. J.; Khimyak, Y. Z.; Cooper, A. I. Angew. Chem. Int. Ed. 2007, 46, 8574. doi: 10.1002/anie.v46:45
40. [40]
  Weber, J.; Antonietti, M.; Thomas, A. Macromolecules 2008, 41, 2880. doi: 10.1021/ma702495r
41. [41]
  Su, Y. Z.; Liu, Y. X.; Liu, P.; Wu, D. Q.; Zhuang, X. D.; Zhang, F.; Feng, X. L. Angew. Chem. Int. Ed. 2015, 54, 1812. doi: 10.1002/anie.201410154
42. [42]
  Zhu, L. M.; Cao, X. Y. Mater. Lett. 2015, 150, 16. doi: 10.1016/j.matlet.2015.02.129
43. [43]
  Xiang, J.; Burges, R.; Häupler, B.; Wild, A.; Schubert, U. S.; Ho, C.-L.; Wong, W.-Y. Polymer 2015, 68, 328. doi: 10.1016/j.polymer.2015.01.054
44. [44]
  Xiong, J. Q.; Wei, Z.; Xu, T.; Zhang, Y.; Xiong, C. X.; Dong, L. J. Polymer 2017, 130, 135. doi: 10.1016/j.polymer.2017.10.004
45. [45]
  Wang, S.; Wang, Q. Y.; Shao, P. P.; Han, Y. Z.; Gao, X.; Ma, L.; Yuan, S.; Ma, X. J.; Zhou, J. W.; Feng, X.; Wang, B. J. Am. Chem. Soc. 2017, 139, 4258. doi: 10.1021/jacs.7b02648
46. [46]
  Wang, Y.; Qu, Q. T.; Liu, G.; Battaglia, V. S.; Zheng, H. H. Nano. Energy 2017, 39, 200.
47. [47]
  Nauroozi, D.; Pejic, M.; Schwartz, P.-O.; Wachtler, M.; Bäuerle, P. RSC Adv. 2016, 6, 111350. doi: 10.1039/C6RA24064J
48. [48]
  Zhao, R. R.; Cao, Y. L.; Ai, X. P.; Yang, H. X. J. Electroanal. Chem. 2013, 688, 93. doi: 10.1016/j.jelechem.2012.07.019
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