Citation: Guo Xiaoling, Chen Xiao, Su Dangsheng, Liang Changhai. Preparation of Ni/C Core-shell Nanoparticles through MOF Pyrolysis for Phenylacetylene Hydrogenation Reaction[J]. Acta Chimica Sinica, ;2018, 76(1): 22-29. doi: 10.6023/A17070339 shu

Preparation of Ni/C Core-shell Nanoparticles through MOF Pyrolysis for Phenylacetylene Hydrogenation Reaction

a.
Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024
b.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016

Corresponding author: Liang Changhai, changhai@dlut.edu.cn
Received Date: 26 July 2017
Available Online: 23 January 2017
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21373038, 21403026), the Natural Science Foundation of Liaoning Province in China (No. 2015021014), and the Fundamental Research Funds for the Central Universities (No. DUT16RC(4)03)the Fundamental Research Funds for the Central Universities DUT16RC(4)03the National Natural Science Foundation of China 21373038the Natural Science Foundation of Liaoning Province in China 2015021014the National Natural Science Foundation of China 21403026

Figures(10)

A series of Ni/C core-shell nano catalysts with abundant mesoporous and uniform size were prepared by Ni-MOF-74 pyrolysis. The Ni-MOF-74 was synthesized via hydrothermal method with nickel acetate and 2, 5-dihydroxyterephthalic acid (DHTA) as raw materials. The pyrolysis process was carried out in a tube furnace under Argon (Ar) atmosphere with a heating rate of 2℃/min. Completed pyrolytic product Ni/C can be obtained by extending the pyrolysis time (6 h) at 400℃ or increasing the pyrolysis temperature (≥ 500℃) based on the TG result. Moreover, the particle size of Ni/C varied with pyrolysis temperature from 3 nm (500℃) to 17 nm (800℃). The TEM images and Ar ion sputtering XPS indicated a core-shell structure of the pyrolysis product. Nickel species can be stable in the form of nickel (Ni⁰) due to the electronic properties regulating and confinement effect of the carbon shell. Moreover, the carbon shell greatly weaken the interaction between particles, which is favorable for the dispersion of the catalyst in the reaction system. H₂-TPR results show that the interaction between nickel and amorphous carbon increases with the pyrolysis temperature, which is unfavorable to the interaction between Ni species and the reactant. The phenylacetylene (PA) hydrogenation reaction was carried out with 0.2 g catalyst, 10 mL of 1 mol/L ethanolic phenylacetylene solution and 1.0 MPa H₂ in a 50 mL high-pressure autoclave under 50℃. Ni/C exhibits excellent catalytic activity and recyclability in phenylacetylene (PA) hydrogenation. In addition, we compared the activity of Ni/C with several reported catalyst system and found their activity increases in the order of Ni, NiSi_x, supported Ni₂Si, Ni/C, Pd and Pt. With an activity of up to 0.833 mmol·min^-1·g_cat.^-1 at 50℃ (Ni/C-400-6, Ni/C-500-2), Ni/C is the most promising transition metal catalyst that can be comparable with noble metal.
- MOFs pyrolysis,
- Ni/C nano-material,
- core-shell structure,
- heterogeneous catalysis,
- phenylacetylene hydrogenation
1. [1]
  (a) Wu, Z. L.; Cravotto, G.; Gaudino, E. C.; Giacomino, A.; Medlock, J.; Bonrath, W. Ultrason. Sonochem. 2017, 35, 664. (b) Yang, K. X.; Chen, X.; Guan, J. C.; Liang, C. H. Catal. Today 2015, 246, 176.
2. [2]
  Wang, B.; Sun, L. M.; Ma, H. W.; Zheng, Y. D.; Hu, X. L.; Yang, H. Q.; Liang, S. Q. Contemp. Chem. Ind. 2015, 2048. doi: 10.3969/j.issn.1671-0460.2015.08.103
3. [3]
  Berenblyum, A. S.; Al-Wadhaf, H. A.; Katsman, E. A. Petrol. Chem. 2015, 55, 118. doi: 10.1134/S0965544115020048
4. [4]
  (a) Mastalir, Á.; Király, Z. J. Catal. 2003, 220, 372; (b) Erokhin, A. V.; Lokteva, E. S.; Yermakov, A. Y.; Boukhvalov, D. W.; Maslakov, K. I.; Golubina, E. V.; Uimin, M. A. Carbon 2014, 74, 291.
5. [5]
  Su, D. S.; Perathoner, S.; Centi, G. Chem. Rev. 2013, 113, 5782. doi: 10.1021/cr300367d
6. [6]
  Li, S. Q.; Liu, J. T.; Sun, F. X.; Wang, W. M.; Cheng, Y. L. CN101475438, 2009[Chem. Abstr. 2009, 35, 840049].
7. [7]
  Beyhaghi, M.; Kiani-Rashid, A. R.; Kashefi, M.; Khaki, J. V.; Jonsson, S. Appl. Surf. Sci. 2015, 344, 1. doi: 10.1016/j.apsusc.2015.01.186
8. [8]
  (a) Cho, G. S.; Lim, J. K.; Choe, K. H.; Lee, W. Mater. Sci. Forum 2010, 658, 360; (b) Wu, C. Z.; Yao, X. D.; Zhang, H. Int. J. Hydrogen Energy 2010, 35, 247.
9. [9]
  Manukyan, A.; Mirzakhanyan, A.; Sajti, L.; Khachaturyan, R.; Kaniukov, E.; Lobanovsky, L.; Sharoyan, E. Nano 2015, 10, 7.
10. [10]
  Meng, Z. Q.; Li, X. B.; Xiong, Y. J.; Zhan, J. T. Nonferr. Metal. Soc. 2012, 22, 2719. doi: 10.1016/S1003-6326(11)61523-9
11. [11]
  Li, X.; Cheng, H.; Fan, J. Powder Metall. Technol. 2009, 27, 142.
12. [12]
  Shen, K.; Chen, X.; Chen, J.; Li, Y. ACS Catal. 2016, 6, 5887. doi: 10.1021/acscatal.6b01222
13. [13]
  Meek, S. T.; Greathouse, J. A.; Allendorf, M. D. Adv. Mater. 2011, 23, 249. doi: 10.1002/adma.201002854
14. [14]
  Dietzel, P. D.; Panella, B.; Hirscher, M.; Blom, R.; Fjellvag, H. Chem. Commun. 2006, 959.
15. [15]
  Dietzel, P. D.; Morita, Y.; Blom, R.; Fjellvag, H. Angew. Chem., Int. Ed. 2005, 44, 6354. doi: 10.1002/(ISSN)1521-3773
16. [16]
  Grant Glover, T.; Peterson, G. W.; Schindler, B. J.; Britt, D.; Yaghi, O. Chem. Eng. Sci. 2011, 66, 163. doi: 10.1016/j.ces.2010.10.002
17. [17]
  An, C.; Liu, G.; Li, L.; Wang, Y.; Chen, C.; Wang, Y.; Jiao, L.; Yuan, H. Nanoscale 2014, 6, 3223. doi: 10.1039/c3nr05607d
18. [18]
  Zhou, L.; Zhang, T.; Tao, Z.; Chen, J. Nano Res. 2014, 7, 774. doi: 10.1007/s12274-014-0438-7
19. [19]
  (a) Paul, R.; Sharma, M. K.; Chatterjee, R.; Hussain, S.; Bhar, R.; Pal, A. K. Appl. Surf. Sci. 2012, 258, 5850; (b) Wang, H.; Cao, Y.; Zou, G.; Yi, Q.; Guo, J.; Gao, L. ACS Appl. Mater. Interfaces 2017, 9, 60; (c) Kovacs, G. J.; Bertoti, I.; Radnoczi, G. Thin Solid Films 2008, 516, 7942.
20. [20]
  (a) Leng, Y. G.; Shao, H. Y.; Wang, Y. T.; Suzuki, M.; Li, X. G. J. Nanosci. Nanotechnol. 2006, 6, 221; (b) Hasegawa, M.; Sugawara, K.; Suto, R.; Sambonsuge, S.; Teraoka, Y.; Yoshigoe, A.; Filimonov, S.; Fukidome, H.; Suemitsu, M. Nanoscale Res. Lett. 2015, 10, 421.
21. [21]
  Golubina, E. V.; Lokteva, E. S.; Erokhin, A. V.; Veligzhanin, A. A.; Zubavichus, Y. V.; Likholobov, V. A.; Lunin, V. V. J. Catal. 2016, 344, 90. doi: 10.1016/j.jcat.2016.08.017
22. [22]
  Guo, J. X.; Liang, J.; Chu, Y. H.; Sun, M. C.; Yin, H. Q.; Li, J. J. Appl. Catal. A: Gen. 2012, 421, 142.
23. [23]
  Park, S. J.; Jung, W. Y. J. Colloid Interface Sci. 2002, 250, 93. doi: 10.1006/jcis.2002.8309
24. [24]
  Wang, Z. M.; Yamashita, N.; Wang, Z. X.; Hoshinoo, K.; Kanoh, H. J. Colloid Interface Sci. 2004, 276, 143. doi: 10.1016/j.jcis.2004.03.017
25. [25]
  Ortega, K. F.; Arrigo, R.; Frank, B.; Schlogl, R.; Trunschke, A. Chem. Mater. 2016, 28, 6826. doi: 10.1021/acs.chemmater.6b01594
26. [26]
  Oswald, S.; Bruckner, W. Surf. Interface Anal. 2004, 36, 17. doi: 10.1002/(ISSN)1096-9918
27. [27]
  Carraro, P. M.; Blanco, A. A. G.; Soria, F. A.; Lener, G.; Sapag, K.; Eimer, G. A.; Oliva, M. I. Microporous Mesoporous Mater. 2016, 231, 31. doi: 10.1016/j.micromeso.2016.05.017
28. [28]
  Cheng, C. B.; Shen, D. K.; Xiao, R.; Wu, C. F. Fuel 2017, 189, 419. doi: 10.1016/j.fuel.2016.10.122
29. [29]
  Rodriguez-Gomez, A.; Caballero, A. ChemNanoMat 2017, 3, 94. doi: 10.1002/cnma.201600297
30. [30]
  Liu, L. J.; Lou, H.; Chen, M. Int. J. Hydrogen Energy 2016, 41, 14721. doi: 10.1016/j.ijhydene.2016.05.188
31. [31]
  Hu, D.; Gao, J.; Ping, Y.; Jia, L.; Gunawan, P.; Zhong, Z.; Xu, G.; Gu, F.; Su, F. Ind. Eng. Chem. Res. 2012, 51, 4875. doi: 10.1021/ie300049f
32. [32]
  Yang, K. X.; Chen, X.; Wang, L.; Zhang, L. L.; Jin, S. H.; Liang, C. H. ChemCatChem 2017, 9, 1337. doi: 10.1002/cctc.201601653
33. [33]
  (a) Carturan, G.; Facchin, G.; Gottardi, V.; Guglielmi, M.; Navazio, G. J. Non-Cryst. Solids 1982, 48, 219; (b) Costa, M.; Pelagatti, P.; Pelizzi, C.; Rogolino, D. J. Mol. Catal. A: Chem. 2002, 178, 21.
34. [34]
  Chen, X.; Li, M.; Guan, J.; Wang, X.; Williams, C. T.; Liang, C. Ind. Eng. Chem. Res 2012, 51, 3604. doi: 10.1021/ie202227j
35. [35]
  Kulikov, L. A.; Terenina, M. V.; Kryazheva, I. Y.; Karakhanov, E. A. Petro. Chem. 2017, 57, 222. doi: 10.1134/S0965544117020177
36. [36]
  Zhang, W.; Wang, F. S.; Li, X. L.; Liu, Y. S.; Liu, Y.; Ma, J. T. Appl. Surf. Sci. 2017, 404, 398. doi: 10.1016/j.apsusc.2017.01.298
37. [37]
  Boronoev, M. P.; Subbotina, E. S.; Kurmaeva, A. A.; Kardasheva, Y. S.; Maksimov, A. L.; Karakhanov, E. A. Petrol. Chem. 2016, 56, 109. doi: 10.1134/S0965544116020055
38. [38]
  (a) Chen, W.; Pan, X. L.; Bao, X. H. J. Am. Chem. Soc. 2007, 129, 7421; (b) Chen, W.; Pan, X. L.; Willinger, M. G.; Su, D. S.; Bao, X. H. J. Am. Chem. Soc. 2006, 128, 3136.
39. [39]
  Fu, Q.; Bao, X. H. Chin. J. Catal. 2015, 36, 517. doi: 10.1016/S1872-2067(15)60828-2
40. [40]
  Deng, J.; Ren, P. J.; Deng, D. H.; Bao, X. H. Angew. Chem. Int. Ed. 2015, 54, 2100. doi: 10.1002/anie.201409524
41. [41]
  Chen, X.; Li, M.; Guan, J.; Wang, X.; Williams, C. T.; Liang, C. Ind. Eng. Chem. Res. 2012, 51, 3604. doi: 10.1021/ie202227j
1. [1]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
2. [2]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
3. [3]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
4. [4]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
7. [7]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
8. [8]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
9. [9]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
12. [12]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
13. [13]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
17. [17]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
18. [18]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

Get Citation

PDF

XML

Metrics

PDF Downloads(50)
Abstract views(3614)
HTML views(870)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142