Ruthenium Nanoparticles Supported on Hierarchical Nitrogen-Doped Carbon Nanocages for Selective Hydrogenation of Acetophenone in Mild Conditions
- Corresponding author: Wu Qiang, wqchem@nju.edu.cn Wang Xizhang, wangxzh@nju.edu.cn
Citation: Cai Yuejin, Liu Chenxia, Zhuo Ou, Wu Qiang, Yang Lijun, Chen Qiang, Wang Xizhang, Hu Zheng. Ruthenium Nanoparticles Supported on Hierarchical Nitrogen-Doped Carbon Nanocages for Selective Hydrogenation of Acetophenone in Mild Conditions[J]. Acta Chimica Sinica, ;2017, 75(7): 686-691. doi: 10.6023/A17030134
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(a) SEM image of hNCNC. Inset is HRTEM image. (b) N2 adsorption/desorption isotherms of hNCNC, hCNC and AC. The inset is the corresponding plot of pore size distributions. (c~e) TEM images of Ru/hNCNC, Ru/hCNC and Ru/AC. The insets are HRTEM images and histograms of particle size distribution from ca. 300 Ru nanoparticles. (f) Corresponding XRD patterns
(a) XPS survey spectrum of Ru/hNCNC, hNCNC and hCNC. (b) The deconvolution plot of N1s of hNCNC and Ru/hNCNC. N1, N2, N3, and N4 denote pyridinic, pyrrolic, graphitic nitrogen, and pyridinic N-oxide species, respectively. (c) The deconvolution plot of Ru 3p XPS spectrum of Ru/hCNC and Ru/hNCNC. (d) Raman scatter of hNCNC and hCNC
(a) Plot of conversion of acetophenone versus cycle number. (b, c) TEM images of post-reacted Ru/hNCNC and Ru/hCNC catalysts. The insert is the histogram of particle size distribution from ca. 300 Ru nanoparticles. Reaction conditions: 0.10 mL acetophenone, 5.0 mL isopropanol, 2.0 mg catalysts, 2.0 MPa H2, 50 ℃, and 2.0 h
Reaction conditions: 0.10 mL acetophenone, 5.0 mL isopropanol, 2.0 mg catalyst. Ru/hNCNC in (a~c). 2.0 h and 50.0 ℃ in (a). 2.0 MPa H2 in (b, c). Ru/hNCNC or Ru/hNCNC, 2.0 h, and 2.0 MPa H2 in (d)