Citation: Yang Xiaodong, Wang Xinmiao, Gao Shanbin, Wang Anjie. Hydrodesulfurization Performances of Pd Catalysts Supported on ZSM-5/MCM-41 Composite Zeolite[J]. Acta Chimica Sinica, ;2017, 75(5): 479-484. doi: 10.6023/A17010031 shu

Hydrodesulfurization Performances of Pd Catalysts Supported on ZSM-5/MCM-41 Composite Zeolite

a.
Petrochemical Research Institute, CNPC, Daqing 163714, China
b.
College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum Beijing, Beijing 102249, China
c.
State Key Laboratory of Fine Chemical, Dalian University of Technology, Dalian 116012, China

Corresponding author: Yang Xiaodong, xiaodongyang1983@126.com
Received Date: 20 January 2017

Fund Project: the China National Petroleum Corporation Fund 2013E-1502the China National Petroleum Corporation Fund 2014B-2508

Figures(6)

Siliceous MCM-41 (Si-MCM-41), two micro-mesoporous materials obtained either by physically mixing Si-MCM-41 with HZSM-5 zeolite (Z-MCM-41-M) or by coating Si-MCM-41 over HZSM-5 zeolite particles (Z-MCM-41), were prepared and characterized by means of XRD, N₂ adsorption-desorption, pyridine adsorbed FT-IR. The hydrodesulfurization (HDS) performances of the supported Pd catalysts thereof, were evaluated with dibenzothiophene (DBT) as the model sulfur-containing molecule. The close relationship between the surface area of the support and the HDS performance for the supported Pd catalysts was not observed. The result indicated that the surface area of the support or the dispersion of the catalyst might not be the key parameter affecting the HDS performance of the supported Pd catalyst. However, the HDS performances of Pd catalysts were significantly influenced by the pore structures and acid properties of the supports. Pd catalysts supported on the acidic supports showed the enhancement of HDS and hydrogenation activities that was thought to be the effect of hydrogen spillover. Among the catalysts studied, Pd/Z-MCM-41 exhibited the highest HDS activity and excellent hydrogenation activities. The results demonstrated that mesoporous materials introducing to microporous zeolite was beneficial to the improvement of HDS activities, but only physically mixing Si-MCM-41 with HZSM-5 zeolite couldn't show the combination advantage of pore of mesoporous materials and acid properties of microporous zeolite, and further generate better synergistic catalytic action. Z-MCM-41 composite material with the regular structure and uniform distribution acidity was potential carriers for precious metal catalysts.
- MCM-41,
- ZSM-5,
- composite zeolite,
- Pd,
- hydrodesulfurization
1. [1]
  Song, C. S. Catal. Today 2003, 86, 211. doi: 10.1016/S0920-5861(03)00412-7
2. [2]
  Bej, S. K.; Maity, S. K.; Turaga, U. T. Energy Fuels 2004, 18, 1227. doi: 10.1021/ef030179+
3. [3]
  Kunisada, N.; Choi, K. H.; Korai, Y.; Mochida, I.; Nakano, K. Appl. Catal. A 2004, 269(1-2), 43. doi: 10.1016/j.apcata.2004.03.051
4. [4]
  Liu, B.; Liu, L.; Wang, Z.; Chai, Y. M.; Liu, H.; Yin, C. L.; Liu, C. G. Catal. Today 2017, 282, 214. doi: 10.1016/j.cattod.2016.08.020
5. [5]
  Zhang, M. H.; Fan, J. Y.; Chi, K. B.; Duan, A. J.; Zhao, Z.; Meng, X. L. Fuel Process. Technol. 2017, 156, 446. doi: 10.1016/j.fuproc.2016.10.007
6. [6]
  Olivas, A.; Luque, P. A.; Gómez-Gutiérrez, C. M.; Flores, D. L.; Valdez, R. Catal. Commun. 2017, 91, 67. doi: 10.1016/j.catcom.2016.12.012
7. [7]
  Liu, W. Q.; Zhou, H.; Lei, W. N.; Shang, T. M.; Zhang, Q.; Sun, G. D. Acta Chim. Sinica 2011, 69, 1622 (in Chinese).
8. [8]
  Guo, Y. N.; Zeng, P. H.; Ji, S. F.; Wei, N.; Liu, H.; Li, C. B. Chin. J. Catal. 2010, 31, 329.
9. [9]
  Zhang, L.; Fu, W. Q.; Yu, Q. Y.; Tang, T. D.; Zhao, Y. C.; Zhao, H. W.; Li, Y. D. J. Catal. 2016, 338, 210. doi: 10.1016/j.jcat.2016.02.029
10. [10]
  Da Costa, P.; Potvin, C.; Manoli, J. M. J. Mol. Catal. A 2002, 184(1-2), 323. doi: 10.1016/S1381-1169(02)00021-3
11. [11]
  Niquille-Röthlisberger, A.; Prins R. J. Catal. 2006, 242(1), 207. doi: 10.1016/j.jcat.2006.06.009
12. [12]
  Guo, H. L.; Sun, Y. Y.; Prins, R. Catal. Today 2008, 130(1), 249. doi: 10.1016/j.cattod.2007.07.007
13. [13]
  Sun, Y. Y.; Prins, R. Angew. Chem. Int. Ed. 2008, 47, 8478. doi: 10.1002/anie.v47:44
14. [14]
  Fujikawa, T.; Idei, K.; Ebihara, T.; Mizuguchi, H.; Usui, K. Appl. Catal. A 2000, 192, 253. doi: 10.1016/S0926-860X(99)00403-2
15. [15]
  Barrio, V. L.; Arias, P. L.; Cambra, J. F.; Güemez, M. B.; Pawelec, B.; Fierro, J. L. Catal. Commun. 2004, 5, 173. doi: 10.1016/j.catcom.2004.01.004
16. [16]
  Yoshimura, Y.; Toda, M.; Matsui, T.; Harada, M.; Ichihashi, Y.; Bando, K. K.; Yasuda, H.; Ishihara, H.; Morita, Y.; Kameoka, T. Appl. Catal. A 2007, 322, 152. doi: 10.1016/j.apcata.2007.01.009
17. [17]
  Yashnik, S. A.; Chesaloy, Y. A.; Ishchenko, A. V.; Kaichev, V. V.; Ismagilov, Z. R. Appl. Catal. B 2017, 204, 89. doi: 10.1016/j.apcatb.2016.11.018
18. [18]
  Corma, A.; Martínez, A.; Martínez-Soria, V. J. Catal. 1997, 169(2), 480. doi: 10.1006/jcat.1997.1737
19. [19]
  Bai, X. L.; Sachtler, W. M. H. J. Catal. 1991, 129(1), 121. doi: 10.1016/0021-9517(91)90016-W
20. [20]
  Yao, J.; Yao, Y. F. Int. J. Hydrogen Energy 2016, 41(33), 14747. doi: 10.1016/j.ijhydene.2016.06.121
21. [21]
  Tang, T. D.; Yin C. Y.; Wang, L. F.; Ji Y. Y.; Xiao, F. S. J. Catal. 2007, 249(1), 111. doi: 10.1016/j.jcat.2007.03.031
22. [22]
  Ji, C. C.; Zhang, L.; Li, L.; Xiao, F. K.; Zhao, N.; Wei, W.; Chen, Y. J.; Wu, F. Ind. Eng. Chem. Res. 2016, 55(29), 7853. doi: 10.1021/acs.iecr.5b04105
23. [23]
  Hartmann, M. Angew. Chem. Int. Ed. 2004, 43, 5880. doi: 10.1002/(ISSN)1521-3773
24. [24]
  Coriolano, A. C. F.; Silva, C. G. C.; Costa, M. J. F.; Pergher, S. B. C.; Calderia, V. P. S.; Araujo, A. S. Microporous Mesoporous Mater. 2013, 172, 206. doi: 10.1016/j.micromeso.2013.01.022
25. [25]
  Wang, L. Y.; Wang, A. J.; Li, X.; Zhou, F.; Hu, Y. K. Acta Petrol. Sin. (Petrol. Proc. Sec.) 2012, 28(3), 380 (in Chinese).
26. [26]
  Chakraborty, B.; Viswanathan, B. Catal. Today 1999, 49(1-3), 253. doi: 10.1016/S0920-5861(98)00431-3
27. [27]
  Long, Y. C.; Xu, T. M.; Dong, W. Y.; Sun, Y. J. Acta Chim. Sinica 1999, 57, 1014 (in Chinese). doi: 10.3321/j.issn:0567-7351.1999.09.012
28. [28]
  Xue, W.; Wang, D. D.; Wang, Y. J.; Liu, Y.; Wei, J. F. Acta Petrol. Sin. (Petrol. Proc. Sec.) 2008, B10, 73 (in Chinese). doi: 10.3969/j.issn.1001-8719.2008.z1.014
29. [29]
  Wang, J.; Huang, L. M.; Li, Q. Z. Appl. Catal. A 1998, 175, 191. doi: 10.1016/S0926-860X(98)00216-6
30. [30]
  Wang, J.; Li, Q. Z.; Yao, J. D. Appl. Catal. A 1999, 184(2), 181. doi: 10.1016/S0926-860X(98)00369-X
31. [31]
  Mendes, P. S. F.; Gregório, A. F. C.; Daudin, A.; Bouchy, C.; Silva, J. M.; Ribeiro, M. F. Catal. Commun. 2017, 89, 152. doi: 10.1016/j.catcom.2016.11.006
32. [32]
  Simon, L. J.; Ommen, V. J. G.; Jentys, A.; Lercher, J. A. Catal. Today 2002, 73(1-2), 105. doi: 10.1016/S0920-5861(01)00502-8
33. [33]
  Wang, A. J.; Kabe, T. Chem. Commun. 1999, (20), 2067. doi: 10.1039/a906275k
34. [34]
  Ren, J.; Wang, A. J.; Li, X.; Chen, Y. Y.; Liu, H. O.; Hu, Y. K. Appl. Catal. A 2008, 344(1-2), 175. doi: 10.1016/j.apcata.2008.04.017
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  An Lu , Yuhao Guo , Yi Yan , Lin Zhai , Xiangyu Wang , Weiran Cao , Zijie Li , Zhixia Zhao , Yujie Shi , Yuanjun Zhu , Xiaoyan Liu , Huining He , Zhiyu Wang , Jian-Cheng Wang . Nanomedicine integrating the lipidic derivative of 5-fluorouracil, miriplatin and PD-L1 siRNA for enhancing tumor therapy. Chinese Chemical Letters, 2024, 35(6): 108928-. doi: 10.1016/j.cclet.2023.108928
6. [6]
  Long Jin , Jian Han , Dongmei Fang , Min Wang , Jian Liao . Pd-catalyzed asymmetric carbonyl alkynylation: Synthesis of axial chiral ynones. Chinese Chemical Letters, 2024, 35(6): 109212-. doi: 10.1016/j.cclet.2023.109212
7. [7]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
8. [8]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
9. [9]
  Yue Sun , Liming Yang , Yaohang Cheng , Guanghui An , Guangming Li . Pd(I)-catalyzed ring-opening arylation of cyclopropyl-α-aminoamides: Access to α-ketoamide peptidomimetics. Chinese Chemical Letters, 2024, 35(6): 109250-. doi: 10.1016/j.cclet.2023.109250
10. [10]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
11. [11]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
12. [12]
  Xiaoxiao Huang , Zhi-Long He , Yangpeng Chen , Lei Li , Zhenyu Yang , Chunyang Zhai , Mingshan Zhu . Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation. Chinese Chemical Letters, 2024, 35(6): 109271-. doi: 10.1016/j.cclet.2023.109271
13. [13]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
14. [14]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
15. [15]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
16. [16]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
17. [17]
  Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
18. [18]
  Aimin Fu , Chunmei Chen , Qin Li , Nanjin Ding , Jiaxin Dong , Yu Chen , Mengsha Wei , Weiguang Sun , Hucheng Zhu , Yonghui Zhang . Niduenes A−F, six functionalized sesterterpenoids with a pentacyclic 5/5/5/5/6 skeleton from endophytic fungus Aspergillus nidulans. Chinese Chemical Letters, 2024, 35(9): 109100-. doi: 10.1016/j.cclet.2023.109100
19. [19]
  . . University Chemistry, 2024, 39(5): 0-0.
20. [20]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(565)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142