Citation: Zheng Yuan, Luo Jing, Wei Wei, Liu Xiaoya. Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions[J]. Acta Chimica Sinica, ;2017, 75(4): 391-397. doi: 10.6023/A16110624 shu

Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122

Corresponding author: Luo Jing, jingluo19801007@126.com
Received Date: 25 November 2016

Fund Project: the Six Talents Peak Project of Jiangsu Province XNY-012the National Natural Science Foundation of China 51573072

Figures(10)

In recent years, hybrid nanomaterials of graphene and polyaniline have attracted extensive interest and have been considered as promising electrode materials for supercapacitor combining the advantages of both materials with synergistic effects. In contrast to the well-developed two-dimensional planar structure of graphene-PANI, the pursuit of hollow gra-phene-PANI hybrid structure is relatively less investigated. The hollow micro/nanostructured graphene-PANI materials with the nanoscale shell, inner cavity and pore structures, is highly expected to exhibit remarkable enhanced supercapacitor performance owing to the enhanced specific surface area and shortened diffusion length for both charge and mass transport. In this work, a novel kind of graphene-polyaniline hollow capsules (PANI-SGR HS) was prepared via Pickering emulsion polymerization using sulfonated graphene (SGR) as Pickering stabilizer. Amphiphilic sulfonated graphene is prepared by a covalent modification and used to stabilize oil phase containing aniline monomer. Aniline molecules were adsorbed to the oil-water interface owing to the electrostatic interaction between amino groups of aniline and sulfonic groups of SGR, which subsequently underwent interfacial polymerization at the oil/water interface upon the addition of initiator ammonium persulfate (APS). The effects of the sulfonation degree of graphene, the SGR concentration as well as the oil/water volume ratio on the stability and morphology of SGR stabilized emulsions were investigated in detail. The SGR with appropriate sulfonation degree can produce stable emulsions. The average diameter of the emulsion droplet decreased with the increasing concentration of SGR stabilizer. The emulsion stability can be improved with the increased water phase infraction. After polymerization of aniline and removal of the oil phase, three-dimensional hollow graphene-polyaniline sphere (PANI-SGR HS) was obtained. The morphology of PANI-SGR HS was observed by scanning electron microscopy (SEM). The special hollow sphere structure not only enlarged the liquid contact area but also improved charge carrier mobility. The hollow sphere modified electrode exhibited excellent performance with a specific capacitance of 480.59 F·g^-1 at 1 A·g^-1, which is much higher than 251 F·g^-1 of the common two-dimensional stacked graphene-polyaniline film. This novel three-dimensional PANI-SGR HS material may have potential applications in energy storage.
- graphene composite,
- polyaniline,
- Pickering stabilizer,
- hollow sphere,
- electrochemistry
1. [1]
  Zhu, Y.; Murali, S.; Cai, W.; Li, X.; Suk, J.; Potts, J.; Rouff, R. Adv. Mater. 2010, 22, 3906. doi: 10.1002/adma.201001068
2. [2]
  He, Q.; Wu, S.; Yin, Z.; Zhang, H. Chem. Sci. 2012, 3, 1764. doi: 10.1039/c2sc20205k
3. [3]
  Yang, L.; Tang, Y.; Yan, D.; Liu, T.; Liu, C.; Luo, S. ACS Appl. Mater. Interfaces 2015, 8, 169.
4. [4]
  Tong, Z.; Fang, S.; Zheng, H.; Zhang, X. Acta Chim. Sinica 2016, 74, 185.
5. [5]
  Gao, H.; Lu, Q.; Liu, N.; Wang, X.; Wang, F. J. Mater. Chem. A 2015, 3, 7215. doi: 10.1039/C5TA00379B
6. [6]
  Wang, L.; Lu, X.; Lei, S.; Song, Y. J. Mater. Chem. A 2014, 2, 4491. doi: 10.1039/C3TA13462H
7. [7]
  Luo, J.; Chen, Y.; Ma, Q.; Liu, R.; Liu, X. J. Mater. Chem. C 2014, 2, 4818. doi: 10.1039/c4tc00126e
8. [8]
  Domingues, S. H.; Salvatierra, R. V.; Oliveira, M. M.; Zarbin, A. J. Chem. Commun. 2011, 47, 2592. doi: 10.1039/C0CC04304D
9. [9]
  Sun, J.; Zhu, Z.; Lai, J.; Luo, J.; Liu, X. Chem. J. Chin. Univ. 2015, 36, 581.
10. [10]
  Fan, X.; Yang, Z.; Liu, Z. Chin. J. Chem. 2016, 34, 107. doi: 10.1002/cjoc.v34.1
11. [11]
  Du, P.; Liu, H. C.; Yi, C.; Wang, K.; Gong, X. ACS Appl. Mater. Interfaces 2015, 7, 23932. doi: 10.1021/acsami.5b06261
12. [12]
  Yang, F.; Xu, M.; Bao, S. J.; Wei, H.; Chai, H. Electrochim. Acta 2014, 137, 381. doi: 10.1016/j.electacta.2014.06.017
13. [13]
  Fan, W.; Zhang, C.; Tjiu, W. W.; Pramoda, K. P.; He, C.; Liu, T. ACS Appl. Mater. Interfaces 2013, 5, 3382. doi: 10.1021/am4003827
14. [14]
  Liu, Z.; Chen, W.; Fan, X.; Yu, J.; Zhao, Y. Chin. J. Chem. 2016, 34, 839. doi: 10.1002/cjoc.v34.8
15. [15]
  Fan, W., Xia, Y. Y.; Tjiu, W. W.; Pallathadka, P. K.; He, C.; Liu, T. J. Power Sources 2013, 243, 973. doi: 10.1016/j.jpowsour.2013.05.184
16. [16]
  Luo, J.; Ma, Q.; Gu, H.; Zheng, Y.; Liu, X. Electrochim. Acta 2015, 173, 184. doi: 10.1016/j.electacta.2015.05.053
17. [17]
  Trung, N. B.; Van Tam, T.; Kim, H. R.; Hur, S. H.; Kim, E. J.; Choi, W. M. Chem. Eng. J. 2014, 255, 89. doi: 10.1016/j.cej.2014.06.028
18. [18]
  Binks, B. P. Curr. Opin. Colloid Interface Sci. 2002, 7, 21. doi: 10.1016/S1359-0294(02)00008-0
19. [19]
  Wei, W.; Wang, T.; Luo, J.; Zhu, Y.; Gu, Y.; Liu, X. Colloids Surf., A 2015, 487, 58. doi: 10.1016/j.colsurfa.2015.09.060
20. [20]
  McCoy, T. M.; Pottage, M. J.; Tabor, R. F. J. Phys. Chem. C 2014, 118, 4529. doi: 10.1021/jp500072a
21. [21]
  Hu, Z.; Marway, H. S.; Kasem, H.; Pelton, R.; Cranston, E. D. ACS Macro Lett. 2016, 5, 185. doi: 10.1021/acsmacrolett.5b00919
22. [22]
  Kim, S. D.; Zhang, W. L.; Choi, H. J. J. Mater. Chem. C 2014, 2, 7541. doi: 10.1039/C4TC01040J
23. [23]
  Yin, G.; Zheng, Z.; Wang, H.; Du, Q.; Zhang, H. J. Colloid Interface Sci. 2013, 394, 192. doi: 10.1016/j.jcis.2012.11.024
24. [24]
  Fei, X.; Xia, L.; Chen, M.; Wei, W.; Luo, J.; Liu, X. Materials 2016, 9, 731. doi: 10.3390/ma9090731
25. [25]
  Wan, W.; Zhao, Z.; Hughes, T. C.; Qian, B.; Peng, S.; Hao, X.; Qiu, J. Carbon 2015, 85, 16. doi: 10.1016/j.carbon.2014.12.058
26. [26]
  Chen, X.; Eggers, P. K.; Slattery, A. D.; Ogden, S. G.; Raston, C. L. J. Colloid Interface Sci. 2014, 430, 174. doi: 10.1016/j.jcis.2014.05.048
27. [27]
  Zhang, Y.; Zheng, X.; Wang, H.; Du, Q. J. Mater. Chem. A 2014, 2, 5304. doi: 10.1039/c3ta15242a
28. [28]
  Luo, J.; Jiang, S.; Liu, R.; Zhang, Y.; Liu, X. Electrochim. Acta 2013, 96, 103. doi: 10.1016/j.electacta.2013.02.072
29. [29]
  Yang, J.; Shi, T.; Jin, W.; Zou, Y. Acta Chim. Sinica 2008, 66, 552. doi: 10.3321/j.issn:0567-7351.2008.05.011
30. [30]
  Zhu, Y.; Sun, J.; Yi, C.; Wei, W.; Liu, X. Soft Matter 2016, 12, 7577. doi: 10.1039/C6SM01263A
31. [31]
  Binks, B. P.; Lumsdon, S. O. Langmuir 2000, 16, 8622. doi: 10.1021/la000189s
32. [32]
  Zheng, Z.; Zheng, X.; Wang, H.; Du, Q. ACS Appl. Mater. Interfaces 2013, 5, 7974. doi: 10.1021/am4020549
33. [33]
  Zheng, X.; Zhang, Y.; Wang, H.; Du, Q. Macromolecules 2014, 47, 6847. doi: 10.1021/ma501253u
34. [34]
  Aveyard, R.; Binks, B. P.; Clint, J. H. Adv. Colloid Interface Sci. 2003, 100, 503.
35. [35]
  Yi, W.; Wu, H.; Wang, H.; Du, Q. Langmuir 2016, 32, 982. doi: 10.1021/acs.langmuir.5b04477
36. [36]
  Luo, J.; Jiang, S.; Wu, Y.; Chen, M.; Liu, X. J. Polym. Sci., Part A:Polym. Chem. 2012, 50, 4888. doi: 10.1002/pola.v50.23
37. [37]
  Fan, W.; Zhang, C.; Tjiu, W. W.; Pramoda, K. P.; He, C.; Liu, T. ACS Appl. Mater. Interfaces 2013, 5, 3382. doi: 10.1021/am4003827
38. [38]
  Zhou, H.; Sun, Y.; Li, G.; Chen, S.; Lu, Y. Polymer 2014, 55, 4459. doi: 10.1016/j.polymer.2014.06.079
39. [39]
  Zang, X.; Li, X.; Zhu, M.; Li, X.; Zhen, Z.; He, Y.; Zhu, H. Na-noscale 2015, 7, 7318.
40. [40]
  Mu, B.; Zhang, W.; Wang, A. J. Nanopart. Res. 2014, 16, 1.
41. [41]
  Coşkun, E.; Zaragoza-Contreras, E. A.; Salavagione, H. J. Carbon 2012, 50, 2235. doi: 10.1016/j.carbon.2012.01.041
1. [1]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
2. [2]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
6. [6]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
9. [9]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
10. [10]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
11. [11]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
14. [14]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
15. [15]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
16. [16]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
18. [18]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
19. [19]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1644)
HTML views(296)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142