Citation: Zhang Changhuan, Li Nianwu, Yao Hurong, Liu Lin, Yin Yaxia, Guo Yuguo. Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage[J]. Acta Chimica Sinica, ;2017, 75(2): 206-211. doi: 10.6023/A16100542 shu

Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage

Zhang Changhuan ^a ,
Li Nianwu ^a ,
Yao Hurong ^a,b ,
Liu Lin ^a,b ,
Yin Yaxia ^a,b,*,, ,
Guo Yuguo ^a,b,*,,

a.
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences(CAS), Beijing 100190, China
b.
School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yin Yaxia, yxyin@iccas.ac.cn Guo Yuguo, ygguo@iccas.ac.cn
Received Date: 13 October 2016
Revised Date: 19 December 2016

Fund Project: "Strategic Priority Research Program" of the Chinese Academy of Sciences XDA09010100Project supported by the National Natural Science Foundation of China 51225204，21303222，21127901

Figures(10)

Rechargeable magnesium (Mg) batteries have attracted research attention as one promising alternative for energy storage because of abundant raw materials. However, the strong electrostatic interaction between bivalent Mg-ions and host lattices often cause sluggish solid state diffusion of Mg-ion within the local crystal structure and consequently prevent reversible insertion/extraction of Mg-ion. Thus much more effort has been paid to develop suitable electrode materials with Mg-ion storage capability. This paper reports the synthesis of Sn nanoparticles/reduced-graphene-oxide nanosheet hybrid nanocomposite (Sn/rGO), by simple hydrothermal method and subsequent thermal treatment. Transmission electron microscopy (TEM) clearly shows that in the as-synthesized Sn/rGO powder Sn nanoparticles are well crystallized, and X-ray diffraction (XRD) pattern was consistent well with tetragonal Sn. Thermogravimetric analysis (TG) suggested that the mass percentage of Sn is ca. 82.3 wt% in the Sn/rGO nanocomposite, very close to the design ratio of ca. 83.4 wt%. As Mg-ion battery anode, the Sn/rGO electrode material exhibit a high initial discharge specific capacity (545.4 mAh·g^-1 at 15 mA·g^-1), good reversible ability and rate performance. The impressive electrochemical property could be attributed to the unique structure of Sn/rGO, in which the three-dimensional (3D) conducting network of rGO can effectively prevent the aggregation of Sn nanoparticles and alleviate the serious volume variation of Sn during repeated discharging/charging process, as well as facilitate the fast access of electrons and Mg-ion to improve kinetics for Mg-ion insertion/extraction. Ex situ XRD and SEM characterization were performed to investigate the electrochemical evolution of Sn/rGO electrode at different discharging/charging states. It is found that upon magnesiation crystalline Mg₂Sn appears and subsequently disappears during de-magnesiation process, which indicates the good electrochemical activity of Sn nanoparticles in Sn/rGO hybrid nanocomposite for magnesium storage. Our result will open new avenue to develop high-efficient magnesium storage material for rechargeable Mg batteries.
- magnesium storage,
- rechargeable magnesium battery,
- nanocomposite,
- conducting network,
- tin,
- graphene
1. [1]
  Ye, Y.; Zhu, J.; Yao, Y.; Wang, Y.; Wu, P.; Tang, Y.; Zhou, Y.; Lu, T. Acta Chim. Sinica 2015, 73, 151. (叶亚, 朱婧怡, 姚依男, 王雨果, 吴平, 唐亚文, 周益明, 陆天虹, 化学学报, 2015, 73, 151.)
2. [2]
  Lyu, Z.; Feng, R.; Zhao, J.; Fan, H.; Xu, D.; Wu, Q.; Yang, L.; Chen, Q.; Wang, X.; Hu, Z. Acta Chim. Sinica 2015, 73, 1013. (吕之阳, 冯瑞, 赵进, 范豪, 徐丹, 吴强, 杨立军, 陈强, 王喜章, 胡征, 化学学报, 2015, 73, 1013.)
3. [3]
  Qiu, Z. P.; Zhang, Y. J.; Xia, S. B.; Dong, P. Acta Chim. Sinica 2015, 73, 992. (邱振平, 张英杰, 夏书标, 董鹏, 化学学报, 2015, 73, 992.)
4. [4]
  Luo, F.; Zheng, J. Y.; Chu, G.; Liu, B. N.; Zhang, S. L.; Li, H.; Chen, L. Q. Acta Chim. Sinica 2015, 73, 808. (罗飞, 郑杰允, 褚赓, 刘柏男, 张素林, 李泓, 陈立泉, 化学学报, 2015, 73, 808.)
5. [5]
  Yan, Y.; Yin, Y. X.; Guo, Y. G.; Wan, L. J. Sci. China-Chem. 2014, 57, 1564.
6. [6]
  Matsui, M. J. Power Sources 2011, 196, 7048.
7. [7]
  Ling, C.; Banerjee, D.; Matsui, M. Electrochim. Acta 2012, 76, 270.
8. [8]
  Saha, P.; Datta, M. K.; Velikokhatnyi, O. I.; Manivannan, A.; Alman, D.; Kumta, P. N. Prog. Mater. Sci. 2014, 66, 1.
9. [9]
  Yoo, H. D.; Shterenberg, I.; Gofer, Y.; Gershinsky, G.; Pour, N.; Aurbach, D. Energ. Environ. Sci. 2013, 6, 2265.
10. [10]
  Shterenberg, I.; Salama, M.; Gofer, Y.; Levi, E.; Aurbach, D. Mrs. Bull. 2014, 39, 453.
11. [11]
  Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.; Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature 2000, 407, 724.
12. [12]
  Aurbach, D.; Weissman, I.; Gofer, Y.; Levi, E. Chem. Rec. 2003, 3, 61.
13. [13]
  Chusid, O.; Gofer, Y.; Gizbar, H.; Vestfrid, Y.; Levi, E.; Aurbach, D.; Riech, I. Adv. Mater. 2003, 15, 627.
14. [14]
  Levi, E.; Gofer, Y.; Aurbach, D. Chem. Mater. 2010, 22, 860.
15. [15]
  Imamura, D.; Miyayama, M.; Hibino, M.; Kudo, T. J. Electrochem. Soc. 2003, 150, A753.
16. [16]
  Tao, Z. L.; Xu, L. N.; Gou, X. L.; Chen, J.; Yuan, H. T. Chem. Commun. 2004, 18, 2080.
17. [17]
  Singh, N.; Arthur, T. S.; Ling, C.; Matsui, M.; Mizuno, F. Chem. Commun. 2013, 49, 149.
18. [18]
  Shao, Y.; Gu, M.; Li, X.; Nie, Z.; Zuo, P.; Li, G.; Liu, T.; Xiao, J.; Cheng, Y.; Wang, C.; Zhang, J. G.; Liu, J. Nano Lett. 2014, 14, 255.
19. [19]
  Wu, N.; Lyu, Y. C.; Xiao, R. J.; Yu, X.; Yin, Y. X.; Yang, X. Q.; Li, H.; Gu, L.; Guo, Y. G. Npg Asia Mater. 2014, 6, e120.
20. [20]
  Wu, N.; Yang, Z. Z.; Yao, H. R.; Yin, Y. X.; Gu, L.; Guo, Y. G. Angew. Chem. Int. Ed. 2015, 54, 5757.
21. [21]
  He, D.; Wu, D.; Gao, J.; Wu, X.; Zeng, X.; Ding, W. J. Power Sources 2015, 294, 643.
22. [22]
  Kim, C.; Phillips, P. J.; Key, B.; Yi, T.; Nordlund, D.; Yu, Y.-S.; Bayliss, R. D.; Han, S.-D.; He, M.; Zhang, Z.; Burrell, A. K.; Klie, R. F.; Cabana, J. Adv. Mater. 2015, 27, 3377.
23. [23]
  Liang, Y.; Yoo, H. D.; Li, Y.; Shuai, J.; Calderon, H. A.; Hernandez, F. C. R.; Grabow, L. C.; Yao, Y. Nano Lett. 2015, 15, 2194.
24. [24]
  Murgia, F.; Stievano, L.; Monconduit, L.; Berthelot, R. J. Mater. Chem. A 2015, 3, 16478.
25. [25]
  Su, S.; Huang, Z.; Nuli, Y.; Tuerxun, F.; Yang, J.; Wang, J. Chem. Commun. 2015, 51, 2641.
26. [26]
  Huang, J.; Poyraz, A. S.; Takeuchi, K. J.; Takeuchi, E. S.; Marschilok, A. C. Chem. Commun. 2016, 52, 4088.
27. [27]
  Malyi, O. I.; Tan, T. L.; Manzhos, S. J. Power Sources 2013, 233, 341.
28. [28]
  Xin, S.; Guo, Y. G.; Wan, L. J. Acc. Chem. Res. 2012, 45, 1759.
29. [29]
  Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339.
30. [30]
  Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.; Gottlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D. J. Electrochem. Soc. 2008, 155, A103.
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
3. [3]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
4. [4]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
5. [5]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
6. [6]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
7. [7]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
8. [8]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
9. [9]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
10. [10]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
11. [11]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
12. [12]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
13. [13]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
14. [14]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
15. [15]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
16. [16]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
17. [17]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
18. [18]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
19. [19]
  Wei-Yu Zhou , Zi-Han Xi , Ning-Ning Du , Li Ye , Ming-Hao Jiang , Jin-Le Hao , Bin Lin , Guo-Dong Yao , Xiao-Xiao Huang , Shao-Jiang Song . Rapid discovery of two unprecedented meroterpenoids from Daphne altaica Pall. using molecular networking integrated with MolNetEnhancer and Network Annotation Propagation. Chinese Chemical Letters, 2024, 35(8): 109030-. doi: 10.1016/j.cclet.2023.109030
20. [20]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(937)
HTML views(89)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142