Citation: Wang Chaoqiang, Qiu Feilong, Deng Han, Zhang Xiaoyu, He Ping, Zhou Haoshen. Study on the Aqueous Hybrid Supercapacitor Based on Carbon-coated NaTi₂(PO₄)₃ and Activated Carbon Electrode Materials[J]. Acta Chimica Sinica, ;2017, 75(2): 241-246. doi: 10.6023/A16100523 shu

Study on the Aqueous Hybrid Supercapacitor Based on Carbon-coated NaTi₂(PO₄)₃ and Activated Carbon Electrode Materials

Wang Chaoqiang ^a ,
Qiu Feilong ^a ,
Deng Han ^a ,
Zhang Xiaoyu ^a ,
He Ping ^a ,
Zhou Haoshen ^a,b,*,,

a.
Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
b.
Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology(AIST), Tsukuba 3058568, Japan

Corresponding author: Zhou Haoshen, pinghe@nju.edu.cn;hszhou@nju.edu.cn
Received Date: 4 October 2016
Revised Date: 22 February 2017

Fund Project: PAPD of Jiangsu Higher Education Institutions, and the Project on Union of Industry-Study-Research of Jiangsu Province BY2015069-01Project supported by the National Basic Research Program of China 2014CB932302 National Natural Science Foundation of China BK20160068, BK20140055National Natural Science Foundation of China 21673116, 21403107,21373111

Figures(4)

Supercapacitors have been regarded as one of the next-generation energy storage devices because of the high power density, excellent cycling performance, long lifespan and easy maintenance. However, its relatively low specific energy hinders its application in the future. Recently, Na-ion based aqueous hybrid supercapacitors have attracted worldwide attention due to its high energy density, environment friendly and low cost. In our work, the Na-ion aqueous hybrid supercapacitor is constructed with NaTi₂(PO₄)₃/C and commercial activated carbon as electrode materials. NaTi₂(PO₄)₃/C nanoparticles with the size of about 40 nm were synthesized by high-temperature solid state reaction method using the NaTi₂(PO₄)₃/C precursor that was prepared through the solution method with Ti(C₄H₉O)₄, NH₄H₂PO₄, Na₂CO₃ as the raw materials, and citric acid as the carbon source. The electrochemical tests were performed using 1 mol·L^-1 Na₂SO₄ solution as the electrolyte. The carbon-coated NaTi₂(PO₄)₃ electrode delivers the discharge capacity of 122 mAh·g^-1 and shows an excellent cycling stability with the retention of 60% of the initial capacity after 1000 cycles at a 10C rate. The supercapacitor was consisted of NaTi₂(PO₄)₃/C anode, AC cathode and 1 mol·L^-1 Na₂SO₄ electrolyte. And the weight ratio of active materials in cathode and anode was 2.2. Cyclic voltammetry, galvanostatic test were employed to study the electrochemical properties of the supercapacitor. The as-fabricated device was then cycled between 0.15~1.4 V with different current density. Our results show the power density of 121.15 W·kg^-1 with specific energy of 18.71 Wh·kg^-1 at the current density of 0.5 A·g^-1. Moreover, the specific energy and power density goes to 14.13 Wh·kg^-1 and 2.42 kW·kg^-1 at a higher current density of 10 A·g^-1. More importantly, the device showed an excellent cycling stability with the retention of 76% after 1000 cycles at a current density of 1 A·g^-1. This research shows the designed hybrid supercapacitor has the potential to be used as auxiliary high-power energy storage device for the practical applications.
- aqueous electrolyte,
- sodium-ion,
- hybrid supercapacitor,
- NaTi₂(PO₄)₃,
- activated carbon
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Study on the Aqueous Hybrid Supercapacitor Based on Carbon-coated NaTi₂(PO₄)₃ and Activated Carbon Electrode Materials