Citation: Zhang Jing, Chen Yiyun. Visible-Light-Induced Carboxyl and Alkoxyl Radical Generations and Reactions[J]. Acta Chimica Sinica, ;2017, 75(1): 41-48. doi: 10.6023/A16080416 shu

Visible-Light-Induced Carboxyl and Alkoxyl Radical Generations and Reactions

Zhang Jing ,
Chen Yiyun ^*,,

State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Chen Yiyun, yiyunchen@sioc.ac.cn
Received Date: 15 August 2016

Fund Project: the National Basic Research Program of China 2014CB910304National Natural Science Foundation of China 21272260the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20020200National Natural Science Foundation of China 21472230

Figures(13)

The carboxyl and alkoxyl radicals generated from visible light photoredox reactions are important reaction intermediates in organic synthesis, which have witnessed conceivable progress recently. In this review, we focus on visible-light-induced photoredox methods to generate carboxyl radicals from carboxylate derivatives and carboxylates, as well as alkoxyl radicals from alcohol derivatives and alcohols, and briefly discuss their synthetic applications.
- visible light,
- radical reaction,
- carboxyl radical,
- alkoxyl radical
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