Citation: Li Ran, Lu Yanying, Lei Kaixiang, Li Fujun, Cheng Fangyi, Chen Jun. Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries[J]. Acta Chimica Sinica, ;2017, 75(2): 199-205. doi: 10.6023/A16070329 shu

Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries

Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University;Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China

Corresponding author: Cheng Fangyi, fycheng@nankai.edu.cn.Tel
Received Date: 7 July 2016
Revised Date: 30 September 2016

Fund Project: Ministry of Education 113016AProject supported by the National Natural Science Foundation of China 21322101, 21231005111 Project B12015

Figures(9)

Recycling use is one of the energy and resource saving strategies to dispose depleted batteries, especially primary lithium batteries that employ electrode materials based on expensive and low-abundance elements. In this study, we report in detail the recycling use of discharged Li-AgVO₃ primary battery for rechargeable Li-O₂ battery. We demonstrate that the discharged Li-AgVO₃ cell, in which metallic silver nanoparticles in-situ generated in the vanadium oxide nanowires cathode efficiently catalyze the oxygen reduction/evolution reactions (ORR/OER), can be resumed as rechargeable Li-O₂ cells when they are exposed at O₂ atmosphere. By controlling the discharge depths, we obtained different cathodes that were composed of vanadium oxide nanowires and silver nanoparticles. As the electrode was discharged to a lower voltage, more silver nanoparticles with larger particle size were distributed on the surface of vanadium oxides, as a result of the sequential reduction of Ag⁺ to Ag⁰ and V⁵⁺ to V⁴⁺. Specifically, the average size of formed Ag nanoparticles was 15 nm and 70 nm at ceased discharge voltage of 2.9 V and 2.0 V, respectively, while the formation of V⁴⁺ was observed at discharge voltage lower than 2.3 V. Electrochemical tests indicated that the Li-O₂ cells assembled with the AgVO₃ cathode discharged to 2.3 V (AgVO₃-2.3) exhibited the highest specific capacity (9000 mAh·g_carbon^-1), the lowest overpotential and robust cycling performance (up to 95 cycles at the current density of 300 mA·g_carbon^-1). The remarkable electrochemical performance of the Li-O₂ battery with the AgVO₃-2.3 cathode is attributed to the optimization of amount, size and distribution of generated silver nanoparticles that contribute to high electronic conductivity and abundant active sites for the ORR/OER. A combined analysis of electrochemical impedance spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy confirmed that the AgVO₃-2.3 cathode enables the reversible formation and decomposition of Li₂O₂ with lower charge transfer resistance on discharge and charge. The results presented here would provide new insight into the promising recycling application of depleted primary Li-AgVO₃ batteries in rechargeable high-capacity Li-O₂ batteries.
- silver vanadium oxide,
- silver nanoparticles,
- lithium primary battery,
- Li-oxygen battery,
- recycling use,
- oxygen reduction/evolution
1. [1]
  Takeuchi, K. J.; Marschilok, A. C.; Davis, S. M.; Leising, R. A.; Takeuchi, E. S. Coord. Chem. Rev. 2001, 219, 283.
2. [2]
  Cheng, F.; Chen, J. J. Mater. Chem. 2011, 21, 9841.
3. [3]
  Han, C.; Pi, Y.; An, Q.; Mai, L.; Xie, J.; Xu, X.; Xu, L.; Zhao, Y. Nano Lett. 2012, 12, 4668.
4. [4]
  Liang, S.; Zhou, J.; Pan, A.; Li, Y.; Chen, T.; Tian, Z.; Ding, H. Mater. Lett. 2012, 74, 176.
5. [5]
  Zeng, H.; Wang, Q.; Rao, Y. RSC Adv. 2015, 5, 3011.
6. [6]
  Kang, D. H.; Chen, M.; Ogunseitan, O. A. Environ. Sci. Technol. 2013, 47, 5495.
7. [7]
  Liu, Q.; Xu, J.; Xu, D.; Zhang, X. Nat. Commun. 2015, 6, 7892.
8. [8]
  Armand, M.; Tarascon, J. M. Nature 2008, 451, 652.
9. [9]
  Sen, X.; Guo, Y.; Wan, L. Scientia Sinica Chimica 2011, 41, 1229.
10. [10]
  Zhang, Z.; Li, L.; Ren, Q.; Xu, Q.; Cao, B. Chin. J. Chem. 2016, 34, 631.
11. [11]
  Zhang, Y.; Li, Y.; Xia, X.; Wang, X.; Gu, C.; Tu, J. Sci. China Tech. Sci. 2015, 58, 1809.
12. [12]
  Chen, J.; Cheng, F. Acc. Chem. Res. 2009, 42, 713.
13. [13]
  Wang, Y.; Yi, J.; Xia, Y. Adv. Energy Mater. 2012, 2, 830.
14. [14]
15. [15]
  Cao, Y.; Wei, Z.; He, J.; Zang, J.; Zhang, Q.; Zheng, M.; Dong, Q. F. Energy Environ. Sci. 2012, 5, 9765.
16. [16]
  Cheng, F.; Chen, J. Chem. Soc. Rev. 2012, 41, 2172.
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
  Hu, Y.; Zhang, T.; Cheng, F.; Zhao, Q.; Han, X.; Chen, J. Angew. Chem. Int. Ed. 2015, 54, 4338.
22. [22]
  Zhang, S.; Li, W.; Li, C.; Chen, J. J. Phys. Chem. B 2006, 110, 24855.
23. [23]
  Bao, Q.; Bao, S.; Li, C. M.; Qi, X.; Pan, C.; Zang, J.; Wang, W.; Tang, D. Y. Chem. Mater. 2007, 19, 5965.
24. [24]
  Xu, Y.; Han, X.; Zheng, L.; Wei, S.; Xie, Y. Dalton Trans. 2011, 40, 10751.
25. [25]
  Kirshenbaum, K.; Bock, D. C.; Lee, C. Y.; Zhong, Z.; Takeuchi, K. J.; Marschilok, A. C.; Takeuchi, E. S. Science 2015, 347, 149.
26. [26]
  Wittmaier, D.; Cañas, N. A.; Biswas, I.; Friedrich, K. A. Adv. Energy Mater. 2015, 5, 1500763.
27. [27]
28. [28]
  Kumar, S.; Selvaraj, C.; Scanlon, L. G.; Munichandraiah, N. Phys. Chem. Chem. Phys. 2014, 16, 22830.
29. [29]
  Cui, Q.; Zhang, Y.; Peng, Z. Chem. Res. Chin. Univ. 2016, 32, 106.
30. [30]
  Lu, J.; Cheng, L.; Lau, K. C.; Tyo, E.; Luo, X.; Wen, J.; Miller, D.; Assary, R. S. Nat. Commun. 2014, 5, 4895.
31. [31]
  Park, J. B.; Luo, X.; Lu, J.; Shin, C. D.; Yoon, C. S.; Amine, K.; Sun, Y. K. J. Phys. Chem. C 2015, 119, 15036.
32. [32]
  Rozier, P.; Savariault, J. M.; Galy, J. J. Solid State Chem. 1996, 122, 303.
33. [33]
  Song, J.; Lin, Y.; Yao, H.; Fan, F.; Li, X.; Yu, S. ACS Nano 2009, 3, 653.
34. [34]
  Lim, S. H.; Kim, B. K.; Yoon, W. Y. J. Appl. Electrochem. 2012, 42, 1045.
35. [35]
  Li, F.; Tang, D.-M.; Zhang, T.; Liao, K.; He, P.; Golberg, D.; Yamada, A.; Zhou, H. Adv. Energy Mater. 2015, 5, 1500294.
36. [36]
  Cui, Q.; Zhang, Y.; Ma, S.; Peng, Z. Sci. Bull. 2015, 60, 1227.
37. [37]
  Liu, Q.; Jiang, Y.; Xu, J.; Xu, D.; Chang, Z.; Yin, Y.; Liu, W.; Zhang, X. Nano Res. 2015, 8, 576.
38. [38]
  Shao, X.; Zhang, T.; Wen, Z. Chin. J. Chem. 2017, 35, 35.
39. [39]
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
3. [3]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
4. [4]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
7. [7]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
8. [8]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
9. [9]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
10. [10]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
11. [11]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
12. [12]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
13. [13]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
16. [16]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
17. [17]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
18. [18]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
19. [19]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
20. [20]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1370)
HTML views(178)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Resumption of the Discharged Li-AgVO3 Primary Batteries for Rechargeable Li-O2 Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Resumption of the Discharged Li-AgVO₃ Primary Batteries for Rechargeable Li-O₂ Batteries