Citation: Luo Manlin, Ge Junyu, Sun Wenzheng, Zhai Huifang. Controlled Synthesis of GaSb Nanowires Based on CVD-grown and Their Optical Characterization[J]. Acta Chimica Sinica, ;2016, 74(10): 839-845. doi: 10.6023/A16060298 shu

Controlled Synthesis of GaSb Nanowires Based on CVD-grown and Their Optical Characterization

  • Corresponding author: Ge Junyu, 
  • Received Date: 17 June 2016

  • Gallium antimonide (GaSb) has a relatively narrow band gap, high electron mobility and excellent saturation velocity, in addition, p-type GaSb nanowires (NWs) can be integrated with n-type nanowire devices potentially. These pro-perties make it applicable both optically and electrically. However, it is noted that the radial dimensions and crystal quality have remarkable influence on the performance of photovoltaic devices. Based on traditional CVD technology, the influence of Au nanoparticles on Vapoure-Liquide-Solid (VLS) growth mechanisms has been studied, GaSb nanowires grown on two different substrates which undergo gold sputtering and gold solution dropping treatment have different geometries of seed particle on nanowire tip and shapes of its body, moreover, the contact angle between these two parts provides stable condition for nanowires growth which has considerable impact on growth direction. The entire growing process is divided into three phases by the temperature: the heating phase, the synthesis phase and the cooling phase. Controllable synthesis has been realized by fixing the synthesis temperature at 900℃ and keeping the other factors unchanged. In the meantime, changing the synthesis time from 60 minutes to 240 minutes in steps, it is found that the breakthrough in radial dimensions and specific surface has been realized with the increase of growing time, the GaSb nanowire of 50 μm has been achieved in this paper. Furthermore, the nanowires were systematically characterized by scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffraction (XRD), which suggest that this material has the zincblende structure with good crystal quality and high purity. Also, the Multi-mode phonon oscillation and band-edge emission of the nanowires are shown through Raman spectroscopy (Raman) and Photoluminescence Spectroscopy (PL). All these demonstrate the superior surface morphology and good crystallinity of the obtained nanowires. The study makes contribution to the extensive exploration and novel discoveries of precise controllable growth of GaSb nanowires.
  • 加载中
    1. [1]

      [1] Kujala, J.; Segercrantz, N.; Tuomisto, F.; Slotte, J. J. Appl. Phys. 2014, 116, 143508.

    2. [2]

      [2] Borg, B. M.; Dick, K. A.; Ganjipour, B.; Pistol, M.; Wernersson, L.; Thelander, C. Nano Lett. 2010, 10, 4080.

    3. [3]

      [3] Ali, A. A. Ph.D. Dissertation, Pennsylvania State University, PA, USA, 2012.

    4. [4]

      [4] Borg, B. M.; Wernersson, L. Nanotechnology 2013, 24, 202001.

    5. [5]

      [5] Zhu, H.; Huang, W.; Huang, Y.; Wang, W. Acta Chim. Sinica 2016, 74, 429. (朱昊云, 黄威, 黄宇立, 汪伟志, 化学学报, 2016, 74, 429.)

    6. [6]

      [6] Chen, X.; Zhao, A.; Gao, Q.; Gan, Z.; Tao, W. Acta Chim. Sinica 2014, 72, 1199. (陈旭成, 赵爱武, 高倩, 甘自保, 陶文玉, 化学学报, 2014, 72, 1199.)

    7. [7]

      [7] Ek, M.; Borg, B. M.; Johansson, J.; Dick, K. A. Nano Lett. 2012, 12, 1794.

    8. [8]

      [8] Lu, Z. Ph.D. Dissertation, University of Chinese Academy of Sciences, Shanghai, 2014(in Chinese). (卢振宇, 博士论文, 中国科学院大学, 上海, 2014.)

    9. [9]

      [9] Ding, Y.; Wang, Z. L. J. Phys. Chem. B 2004, 108, 12280.

    10. [10]

      [10] Li, X.; Deng, F.; Ni, C.; Chen, Z. PTCA (Part A: Phys. Test) 2015, 51, 225.

    11. [11]

      [11] Zardo, I.; Abstreiter, G.; Morral, A. F. i. In Nanowires, Ed.: Prete, P., InTech, Croatia, 2010, p. 414.

    12. [12]

      [12] Yang, Z.; Wang, F.; Han, N.; Lin, H.; Cheung, H.; Fang, M.; Yip, S.; Hung, T.; Wong, C.; Ho, J. C. ACS Appl. Mater. Interfaces 2013, 5, 10946.

    13. [13]

      [13] Ren, P. Ph.D. Dissertation, Hunan University, Changsha, 2014(in Chinese). (任品云, 博士论文, 湖南大学, 长沙, 2014.)

    14. [14]

      [14] Maslar, J. E.; Hurst, W. S.; Wang, C. A. J. Appl. Phys. 2008, 103, 013502.

    15. [15]

      [15] Lugstein, A.; Schoendorfer, C.; Weil, M.; Tomastik, C.; Jauss, A.; Bertagnolli, E. Nucl. Instrum. Methods Phys. Res., Sect. B 2007, 255, 309.

    16. [16]

      [16] Zhou, W.; Liu, R.; Tang, D.; Wang, X.; Fan, H.; Pan, A.; Zhang, Q.; Wan, Q.; Zou, B. Nanotechnology 2013, 24, 055201.

    17. [17]

      [17] Yang, Z.; Han, N.; Fang, M.; Lin, H.; Cheung, H.; Yip, S.; Wang, E.; Hung, T.; Wong, C.; Ho, J. C. Nat. Commun. 2014, 5, 5249.

    18. [18]

      [18] Zhao, F.; Yang, Y. Heat Treatment 2009, 24, 7. (赵峰, 杨艳丽, 热处理, 2009, 24, 7.)

    19. [19]

      [19] Lv, Y.; Liu, R.; Wang, L.; Li, G.; Zhang, Y.; Dong, X.; Zhang, B. Superlattices Microstruct. 2015, 83, 834.

    20. [20]

      [20] Sven, B.; Francisco, H. R.; Justin, D. H.; Albert, R. R. Prog. Mater. Sci. 2010, 55, 563.

    21. [21]

      [21] Dick, K. A. Prog. Cryst. Growth Charact. Mater. 2008, 54, 138.

    22. [22]

      [22] Krogstrup, P.; Jørgensen, H. I.; Johnson, E.; Madsen, M. H.; Sørensen, C. B.; Morral, A. F. i; Aagesen, M.; Nygård, J.; Glas, F. J. Phys. D: Appl. Phys. 2013, 46, 313001.

  • 加载中
    1. [1]

      Peng ZHOUXiao CAIQingxiang MAXu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    2. [2]

      Huan LIShengyan WANGLong ZhangYue CAOXiaohan YANGZiliang WANGWenjuan ZHUWenlei ZHUYang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088

    3. [3]

      Laiying Zhang Yinghuan Wu Yazi Yu Yecheng Xu Haojie Zhang Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126

    4. [4]

      Jiahong ZHENGJingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi2S4 supported by MnO2 nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170

    5. [5]

      Xuan Zhou Yi Fan Zhuoqi Jiang Zhipeng Li Guowen Yuan Laiying Zhang Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111

    6. [6]

      Qingyang Cui Feng Yu Zirun Wang Bangkun Jin Wanqun Hu Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046

    7. [7]

      Qi Wang Yicong Gao Feng Lu Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141

    8. [8]

      Lijuan Liu Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060

    9. [9]

      Jiao CHENYi LIYi XIEDandan DIAOQiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

    10. [10]

      Jingke LIUJia CHENYingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060

    11. [11]

      Haiyu Nie Chenhui Zhang Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055

    12. [12]

      Yongming Guo Jie Li Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057

    13. [13]

      Zijian Jiang Yuang Liu Yijian Zong Yong Fan Wanchun Zhu Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

    14. [14]

      Yuyang Xu Ruying Yang Yanzhe Zhang Yandong Liu Keyi Li Zehui Wei . Research Progress of Aflatoxins Removal by Modern Optical Methods. University Chemistry, 2024, 39(11): 174-181. doi: 10.12461/PKU.DXHX202402064

    15. [15]

      Zitong Chen Zipei Su Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054

    16. [16]

      Siyu HOUWeiyao LIJiadong LIUFei WANGWensi LIUJing YANGYing ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

    17. [17]

      Guangming YINHuaiyao WANGJianhua ZHENGXinyue DONGJian LIYi'nan SUNYiming GAOBingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086

    18. [18]

      Zunyuan Xie Lijin Yang Zixiao Wan Xiaoyu Liu Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137

    19. [19]

      Xiufang Wang Donglin Zhao Kehua Zhang Xiaojie Song . “Preparation of Carbon Nanotube/SnS2 Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025

    20. [20]

      Haiyuan Wang Yiming Tang Haoran Guo Guohui Chen Yajing Sun Chao Zhao Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067

Metrics
  • PDF Downloads(2)
  • Abstract views(354)
  • HTML views(40)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return