Citation: Li Tao, Lu Dan. Shape Characteristics of Complex Single Chain and Aggregation by Exponential Law[J]. Acta Chimica Sinica, ;2016, 74(8): 649-656. doi: 10.6023/A16050252 shu

Shape Characteristics of Complex Single Chain and Aggregation by Exponential Law

Li Tao ,
Lu Dan ^*,,

1.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012

Corresponding author: Lu Dan, lud@jlu.edu.cn
Received Date: 20 May 2016

Fund Project: the National Natural Science Foundation of China 21174049the National Natural Science Foundation of China 91333103the National Natural Science Foundation of China 21574053

Figures(11)

Being an important part of polymer science, the single chain conformation and aggregation structure in polymer solution has been widely studied by many experiential exponential laws. In the review, several kinds of commonly used exponential laws were summarized, and the use in the study of shape characteristics of complex single chain and aggregation was introduced. The aggregation structure and morphology of films can be controlled by precursor solution, so deep understanding to the intrinsic properties of precursor solution is particularly important. Combined with the electron microscope, spectra, etc., the exponential law can be used to further study the single chain, aggregation size and morphology, structure evolution, and the law of the movement process of structure units at all levels in polymer solution, this will lay a theoretical foundation for the molecular designing, functional development and application of polymer materials.
- polymer solution,
- exponential law,
- single chain,
- aggregation structure,
- structural evolution
1. [1]
  Wu Q. Y.Polymer Condensed Matter Physics, Science Press, Beijing, 2012, pp. 32～44.
2. [2]
  de Gennes P. E.Scaling Concepts in Polymer Physics, Cornell University Press, New York, 1985.
3. [3]
  Wu Q. Y.China Plastics 2013, 27(1), 1.
4. [4]
  Robinson G., Ross-Murphy S. B., Morris, E R. Carbohydr. Res. 1982, 107, 17. doi: 10.1016/S0008-6215(00)80772-7
5. [5]
  Teraoka I.Polymer Solutions: An Introduction to Physical Properties, John Wiley & Sons, Inc., New York, 2001, pp. 209～221.
6. [6]
  Kato T., Okamoto T., Tokuya T., Takahashi A.Biopolymers, 1982, 21:1623. doi: 10.1002/(ISSN)1097-0282
7. [7]
  Picton L., Bataille G., Muller G.Carbohydr. Polym., 2000, 42:23. doi: 10.1016/S0144-8617(99)00139-3
8. [8]
  Picton L., Merle L., Muller G.Int. J. Polym. Anal. Ch., 1996, 2:103. doi: 10.1080/10236669608233900
9. [9]
  Beaucage G.Phys. Rev. E, 2004, 70:031401.
10. [10]
  Gelade E. T. F., Goderis B., de Koster C. G..; Meijerink N., van Benthem R. A.T. M. Macromolecules, 2001, 34:3552. doi: 10.1021/ma001266t
11. [11]
  Scherrenberg R., Coussens B., Van Vliet P., Edouard G., Brackman J., De Brabander E.Macromolecules, 1998, 31:456. doi: 10.1021/ma9618181
12. [12]
  Huber K., Witte T., Hollmann J., Keuker-Baumann S. J.Am. Chem. Soc., 2007, 129:1089. doi: 10.1021/ja063368q
13. [13]
  Lages S., Michels R., Huber K.Macromolecules, 2010, 43:3027. doi: 10.1021/ma9027239
14. [14]
  Carpinti M., Ferri F., Giglio M., Paganini E., Perini U.Phys. Rev. A, 1990, 42:7347. doi: 10.1103/PhysRevA.42.7347
15. [15]
  Schärtl W.Light Scattering from Polymer Solutions and Nanoparticle Dispersions, Springer Laboratory, Berlin, 2007.
16. [16]
  Raspaud E., Lairez D., Adam M., Carton J. P.Macromolecules, 1994, 27:2956. doi: 10.1021/ma00089a011
17. [17]
  Peng S. F., Wu C.Macromolecules, , 2001, 34:6795. doi: 10.1021/ma010376c
18. [18]
  Roe R. J.Methods of X-ray and Neutron Scattering in Polymer Science, Oxford, New York, 2000.
19. [19]
  Higgins J. S., Benoit H. C.Polymers and Neutron Scattering, Oxford, New York, 1994.
20. [20]
  Perahia D., Traiphol R., Bunz U. H.F. J. Chem. Phys., 2002, 117:1827. doi: 10.1063/1.1486215
21. [21]
  Wang H., Zhou W., Ho D. L., Winey K. I., Fischer J. E., Glinka C. J., Hobbie E. K.Nano Lett., 2004, 4:1789. doi: 10.1021/nl048969z
22. [22]
  Knaapila M., Garamus V. M., Almásy L., Pang J. S., Forster M., Gutacker A., Scherf U., Monkman A. P.J. Phys. Chem. B, 2008, 112:16415. doi: 10.1021/jp806763d
23. [23]
  Rong L. X., Wei L. H., Dong B. Z., Hong X. G., Li F. M., Li Z. C.Chin. Phys., 2003, 12:771. doi: 10.1088/1009-1963/12/7/313
24. [24]
  Auguin, D.;Gostan, T.;Delsuc, M.-A.; Roumestand, C.C.R.Chimie 2004, 7, 265. doi: 10.1016/j.crci.2003.10.017
25. [25]
  Crutchfield, C.A.; Harris, D.J.J.Magn.Reson.2007, 185, 179. doi: 10.1016/j.jmr.2006.12.004
26. [26]
  Auge S., Schmit P.-O., Crutchfield C. A., Islam M. T., Harris D. J., Durand E., Clemancey M., Quoineaud A. A., Lancelin J. M., Prigent Y., Taulelle F., Delsuc M. A.J. Phys. Chem. B, 2009, 113:1914. doi: 10.1021/jp8094424
27. [27]
  Chari K., Antalek B., Minter J.Phys. Rev. Lett., 1995, 74:3624. doi: 10.1103/PhysRevLett.74.3624
28. [28]
  Wu Q. Y.Polymer Physics, Higher Education Press, Beijing, 2011, pp. 17～24.
29. [29]
  Roubroeks J. P., Mastromauro D. I., Andersson R., Christensen B. E., Åman P.Biomacromolecules, 2000, 1:584. doi: 10.1021/bm000017+
30. [30]
  Sato T., Norisuye T., Fujita H.Macromolecules, 1984, 7:6.
31. [31]
  Li W., Cui S. W., Wang Q.Biomacromolecules, 2006, 7:446. doi: 10.1021/bm050625v
32. [32]
  Tao Y. Z., Zhang L. N., Yan F., Wu X. J.Biomacromolecules, 2007, 8:2321. doi: 10.1021/bm070335+
33. [33]
  Huang Z. P., Huang Y. N., Li X. B., Zhang L. N.Carbohydr. Polym., 2009, 78:596. doi: 10.1016/j.carbpol.2009.05.027
34. [34]
  Li S., Huang Y., Wang S., Xu X. J., Zhang L. N.J. Phys. Chem. B, 2014, 118:668. doi: 10.1021/jp4087199
35. [35]
  Voit B. I., Albena L.Chem. Rev., 2009, 109:5924. doi: 10.1021/cr900068q
36. [36]
  Mori H., Müller A. H. E., Simon P. F.W. In Macromolecular Engineering: Precise Synthesis, Materials Properties, Applications, Vol. 2, Eds.: Matyjaszewski K., Gnanou Y., Leibler L., Wiley-VCH, Weinheim, Germany, 2007 p.973.
37. [37]
  Turner S. R., Voit B. I., Mourey T. H.Macromolecules, 1993, 26:4617. doi: 10.1021/ma00069a031
38. [38]
  Mourey T. H., Turner S. R., Rubinstein M., Fréchet J. M. J., Hawker C. J., Wooley K. L.Macromolecules, 1992, 25:2401. doi: 10.1021/ma00035a017
39. [39]
  Tomalia D. A., Hedstrand D. M., Wilson L. R.In Encyclopedia of Polymers Science, 2nd ed., Wiley, New York, 1990.
40. [40]
  Isaacson J., Lubensky T. C.J. Phys. Lett., 1980, 41:469. doi: 10.1051/jphyslet:019800041019046900
41. [41]
  Daoud M., Joanny J. F.J. Phys. (Les Ulis, Fr.), , 1981, 42:1359. doi: 10.1051/jphys:0198100420100135900
42. [42]
  Flory P. J.Principles of Polymer Chemistry, Cornell University, Press, Ithaca, New York, 1953.
43. [43]
  Luca E. D., Richards R. W., Grillo I., King S. M.J. Polym. Sci. Polom. Phys., 2003, 41:1352. doi: 10.1002/(ISSN)1099-0488
44. [44]
  Ioan C. E., Aberle T., Burchard W.Macromolecules, 2000, 33:5730. doi: 10.1021/ma000282n
45. [45]
  Hanselmann R., Burchard W., Lemmes R., Schwengers D.Macromol. Chem. Phys., 1995, 196:2259. doi: 10.1002/macp.1995.021960715
46. [46]
  Huang L., Zhang L. L., Huang X. N., Li T., Liu B., Lu D. J.Phys. Chem. B., 2014, 118:791. doi: 10.1021/jp406598x
47. [47]
  Knaapila M., Almásy L., Garamus V. M., Ramosd M. L., Justino L. L. G., Galbrecht F., Preis E., Scherf U., Burrowsd H. D., Monkmanm A. P.Polymer, 2008, 49:2033. doi: 10.1016/j.polymer.2008.02.046
48. [48]
  Papi M., Arcovito G., de, Spirito. M..; Amiconi G.., Bellelli A., Boumis G.Appl. Phys. Lett., 2005, 86:183901. doi: 10.1063/1.1915526
49. [49]
  Li Y.C, Chen K.B, Chen H. L., Hsu C. S., Tsao C. S., Chen J. H., Chen S. A.Langmuir, 2006, 22:11009. doi: 10.1021/la0612769
50. [50]
  Bauer B. J., Hobbie E. K., Becker M. L.Macromolecules, 2006, 39:2637. doi: 10.1021/ma0527303
51. [51]
  Callejas-Fernández J., Ramos J., Forcada J., Moncho-Jordá A. J.Colloid Interface Sci., 2015, 450:310. doi: 10.1016/j.jcis.2015.03.031
52. [52]
  Kanai S., Muthukumar M. J.Chem. Phys., 2007, 127:25.
53. [53]
  Dai S., Tam K. C., Jenkins R. D.Macromolecules, 2000, 33:404. doi: 10.1021/ma990887n
54. [54]
  Witten T. A., Sander L. M.Phys. Rev. Lett., 1981, 47:1400. doi: 10.1103/PhysRevLett.47.1400
55. [55]
  Witten T. A., Sander L. M.Phys. Rev. B, 1983, 27:5686. doi: 10.1103/PhysRevB.27.5686
56. [56]
  Meakin P.Phys. Rev. Lett., 1983, 51:1119. doi: 10.1103/PhysRevLett.51.1119
57. [57]
  Meakin P.Phys. Rev. A, 1990, 41:2005. doi: 10.1103/PhysRevA.41.2005
58. [58]
  Meakin P.Adv. Colloid Interface Sci., 1988, 28:249.
59. [59]
  Brown W. D., Ball R. C.J. Phys. A, 1985, 18:517. doi: 10.1088/0305-4470/18/9/006
60. [60]
  Vicsek T.Fractal Growth Phenomena, World Scientific, London, 1992.
61. [61]
  Chen W. N., Zhao Y., Jiang Y., Yan D. D., Han C. C.ChemPhysChem, 2004, 5:1745. doi: 10.1002/(ISSN)1439-7641
62. [62]
  Liu X. B., Luo S. K., Ye J., Wu C.Macromolecules, 2012, 45:4830. doi: 10.1021/ma300629d
63. [63]
  Hagiwara T., Kumagai H., Nakamura K.Biosci. Biotech. Biochem., 1996, 60:1757. doi: 10.1271/bbb.60.1757
64. [64]
  Lin W., Zhou Y. S., Zhao Y., Zhu Q. S., Wu C.Macromolecules, 2002, 35:7407. doi: 10.1021/ma020372n
65. [65]
  Liao W., Zhang Y. J., Guan Y., Zhu X. X.Langmuir, 2012, 28:10873. doi: 10.1021/la3016386
66. [66]
  Burns J. L., Yan Y. D., Jameson G. J., Biggs S.Langmuir, 1997, 13:6413. doi: 10.1021/la970303f
67. [67]
  Li, N.;Li, Y.B.; Wang, X.G.Macromolecules 2011, 44, 8598. doi: 10.1021/ma200992n
1. [1]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
10. [10]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
11. [11]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
12. [12]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
13. [13]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
14. [14]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
15. [15]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
18. [18]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
19. [19]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
20. [20]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1029)
HTML views(196)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142