Citation: Song Qiusheng, Zhou Wen, Wu Xinmin, Wu Fan. Dual Stimulus-responsive Fluorescence Behavior and Mechanism of P(NIPAM-co-RhBHA)-NP[J]. Acta Chimica Sinica, ;2016, 74(5): 435-440. doi: 10.6023/A16010073 shu

Dual Stimulus-responsive Fluorescence Behavior and Mechanism of P(NIPAM-co-RhBHA)-NP

1.
School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China

Corresponding author: Song Qiusheng, sqshfut@126.com
Received Date: 31 January 2016

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In the present study, based on spectral overlap between 1, 8-naphthalimide and N-acrylyl-N'-rhodamine B acylhydrazine thiourea (RhBHA), reversible "on-off" ring reaction of RhBHA at various pH values, and thermosensitive property of poly(N-isopropyl acrylamide) (PNIPAM), a novel linear polymer P(NIPAM-co-RhBHA)-NP was prepared via a series of chemical reactions. Firstly, 4-(2-aminoethyl)amino-N-aminopropane-1, 8-naphthalimide (NP-NH₂) and RhBHA were prepared respectively, and they were used as the donor and acceptor to construct a fluorescence resonance energy transfer (FRET) system. Secondly, incorporating RhBHA into PNIPAM by reversible addition-fragmentation chain transfer polymerization (RAFT), P(NIPAM-co-RhBHA) was synthesized. Finally, P(NIPAM-co-RhBHA)-NP was fabricated by amide condensation between NP-NH₂ and the as-prepared P(NIPAM-co-RhBHA). The structure of P(NIPAM-co-RhBHA)-NP was characterized via ¹H NMR, FTIR, UV-vis and GPC. The fluorescence responsive behavior of the polymer to environmental temperature and pH value was investigated by photoluminescence (PL) in buffer solutions, and the mechanism was discussed in detail. The results indicate that, in an acidic solution, energy can be transferred from NP-NH₂ moieties to RhBHA moieties via FRET mechanism, either pH values or environmental temperatures play important roles to affect the fluorescence emission of P(NIPAM-co-RhBHA)-NP.
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沈阳化工大学材料科学与工程学院沈阳 110142