Citation: Zhang Ting, Cai Xuediao, Liu Na, Xu Chunli. Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance[J]. Acta Chimica Sinica, ;2016, 74(5): 441-449. doi: 10.6023/A16010036 shu

Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance

Zhang Ting ^a ,
Cai Xuediao ^a,*,, ,
Liu Na ^b ,
Xu Chunli ^b

a.
Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
b.
Key Laboratory of Applied Surface and Colloid Chemistry of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

Corresponding author: Cai Xuediao, xdcai@snnu.edu.cn
Received Date: 18 January 2016

Fund Project: the Fundamental Research Funds for the Central Universities GK200902008

Figures(8)

Molybdenum oxide (MoO₃)/dodecylamine (DDA) intercalated materials were synthesized via direct thermal treatment followed by calcination to give MoO₃/C-N hybrid materials. These prepared intercalated materials were characterized by powder X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy to investigate the influences of the calcination conditions, such as calcination temperature, calcination heating rate and calcination time, on the structure and composition of these materials. The results exhibited the order-disorder-order changes of the crystal structure during the calcination temperature from 400 ℃ to 800 ℃. Meanwhile, the valence of some Mo was reduced from +6 to +4 or +2. XRD patterns showed that calcination heating rate had almost no effect on the composite structure. Crystal MoO₂ was produced with the increase of calcination time at 600 ℃ in N₂atmosphere. Crystal Mo₂C was formed and the crystalline became regular with the increase of calcination temperature when the calcination temperature was higher than 600 ℃. SEM and TEM images clearly showed that molybdenum oxide layers were kept with the reducing of interlayer spacing as the calcination temperature below 600 ℃. With the calcination temperature rising up to 800 ℃, the carbonization effect of carbonaceous molecules and the enormous loss of gas molecules made the layer structure collapsed. In addition, the carbon and nitrogen elements were detected on the surface of molybdenum oxide. MoO₃/C-N hybrid materials were used as catalyst for the oxidation of benzyl alcohol. The results showed that the structure and composition of the materials have a certain effect on the catalytic yield and the selectivity. The MoO₃/C-N hybrid materials formed at calcination of 600 ℃ in 2 h was found to catalyze benzyl alcohol to benzaldehyde efficiently with high selectivity and relative stability. The yield of oxidation of benzyl alcohol to benzaldehyde in 3 h was up to 30% with a high selectivity retention, which was nearly 4 times compared with that of the pristine MoO₃. The MoO₃/C-N hybrid materials used as catalyst can be recycled several times with high selectivity.
- molybdenum trioxide,
- hybrid materials,
- calcination,
- catalytic performance,
- oxidation of benzyl alcohol
1. [1]
  Faughnan, B. W.; Crandall, R. S. Appl. Phys. Lett. 1977, 31, 834. doi: 10.1063/1.89566
2. [2]
  Yao, J. N.; Loo, B. H.; Hashimoto, K.; Fujishima, A. J. Electroanal. Chem. 1990, 290, 263. doi: 10.1016/0022-0728(90)87436-N
3. [3]
  Yao, J. N.; Yang, Y. A.; Loo, B. H. J. Phys. Chem. B 1998, 102, 1856. doi: 10.1021/jp972217u
4. [4]
  Balendhran, S.; Deng, J.; Ou, J. Z.; Walia, S.; Scott, J.; Tang, J.; Wang, K. L.; Field, M. R.; Russo, S.; Zhuiykov, S.; Strano, M. S.; Medhekar, N.; Sriram, S.; Bhaskaran, M.; Kalantar-zadeh, K. Adv. Mater. 2013, 25, 109. doi: 10.1002/adma.201203346
5. [5]
  Campanel, L.; Pistoia, G. J. Electrochem. Soc. 1971, 118, 1905. doi: 10.1149/1.2407864
6. [6]
  Zhang, Z.; Yang, R. Y.; Umar, A.; Gao, Y. S.; Wang, J. Y.; Lu, P.; Guo, Z. H.; Huang, L.; Zhou, T. T.; Wang, Q. Adv. Mater. Sci. 2014, 6(10), 2159. doi: 10.1166/sam.2014.2127
7. [7]
  Brookes, C.; Wells, P. P.; Cibin, G.; Dimitratos, N.; Jones, W.; Morgan, D. J.; Bowker, M. ACS Catal. 2014, 4(1), 243. doi: 10.1021/cs400683e
8. [8]
  Shuwa, S. M.; Al-Hajri, R. S.; Jibril, B. Y.; Al-Waheibi, Y. M. Electron. Mater. Lett. 2015, 11(2), 252.
9. [9]
  Meyer, J.; Hamwi, S.; Kroger, M.; Kowalsky, W.; Riedl, T.; Kahn, A. Adv. Mater. 2012, 24, 5408. doi: 10.1002/adma.v24.40
10. [10]
  Alsaif, M. M. Y. A.; Balendhran, S.; Field, M. R.; Latham, K.; Wlodarski, W.; Ou, J. Z.; Kalantar-zadeh, K. Sens. Actuators, B: Chem. 2014, 192, 196. doi: 10.1016/j.snb.2013.10.107
11. [11]
  Suzuki, T.; Yamazaki, T.; Koukitu, A.; Maeda, M.; Seki, H.; Takahashi, K. J. Mater. Sci. Lett. 1988, 7, 926. doi: 10.1007/BF00720732
12. [12]
  Kamiya, S.; Tsuda, D.; Miura, K.; Sasaki, N. Wear 2004, 257, 1133. doi: 10.1016/j.wear.2004.07.012
13. [13]
  Sha, X. W.; Chen, L.; Cooper, A. C.; Pez, G. P.; Cheng, H. S. J. Phys. Chem. C 2009, 113, 11399. doi: 10.1021/jp9017212
14. [14]
  Dong, Y. F.; Xua, X. M.; Li, S.; Han, C. H.; Zhao, K. N.; Zhang, L.; Niu, C. J.; Huang, Z.; Mai, L. Q. Nano Energy 2015, 15, 145. doi: 10.1016/j.nanoen.2015.04.015
15. [15]
  Itoh, T.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M. Sens. Actuators, B 2008, 128, 512. doi: 10.1016/j.snb.2007.07.059
16. [16]
  Yao, D. D.; Ou, J. Z.; Latham, K.; Zhuiykov, S.; O'Mullane, A. P.; Kalantar-zadeh, K. Cryst. Growth Des. 2012, 12, 1865. doi: 10.1021/cg201500b
17. [17]
  Gesheva, K. A.; Ivanova, T. M.; Bodurov, G. Prog. Org. Coat. 2012, 74, 635. doi: 10.1016/j.porgcoat.2011.07.016
18. [18]
  Mai, L. Q.; Hu, B.; Chen, W.; Qi, Y. Y.; Lao, C. S.; Yang, R. S.; Dai, Y.; Wang, Z. L. Adv. Mater. 2007, 19, 3712. doi: 10.1002/(ISSN)1521-4095
19. [19]
  Itoh, T.; Wang, J. Z.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M.; Murayama, N. Mater. Lett. 2008, 62, 3021. doi: 10.1016/j.matlet.2008.01.099
20. [20]
  Itoh, T.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M. Mater. Chem. Phys. 2008, 110, 115. doi: 10.1016/j.matchemphys.2008.01.024
21. [21]
  Murugana, A. V.; Viswanath, A. K. J. Appl. Phys. 2006, 100, 074319. doi: 10.1063/1.2356788
22. [22]
  Afsharpour, M.; Mahjoub, A. R.; Amini, M. M. J. Inorg. Organomet. Polym. 2009, 19, 298. doi: 10.1007/s10904-009-9285-5
23. [23]
  Afsharpour, M.; Mahjoub, A. R.; Amini, M. M.; Khodadadi, A. A. Curr. Nanosci. 2010, 6, 82. doi: 10.2174/157341310790226261
24. [24]
  Ji, H. M.; Liu, X. L.; Liu, Z. J.; Yan, B.; Chen, L.; Xie, Y. F.; Liu, C.; Hou, W. H.; Yang, G. Adv. Funct. Mater. 2015, 25, 1886. doi: 10.1002/adfm.201404378
25. [25]
  Qiu, J. Y. C.; Yang, Z. X.; Li, Y. J. Mater. Chem. A 2015, 3, 24245. doi: 10.1039/C5TA05924K
26. [26]
  Jing, Y.; Pan, Q. Y.; Cheng, Z. X.; Dong, X. W.; Xiang, Y. X. Mater. Sci. Eng. B 2007, 138, 55. doi: 10.1016/j.mseb.2007.01.015
27. [27]
  Saghafi, M.; Ataie, A.; Heshmati-Manesh, S. Int. J. Refract. Met. Hard Mater. 2011, 29, 419. doi: 10.1016/j.ijrmhm.2010.12.012
28. [28]
  Ferrari, A. C.; Basko, D. M. Nature Nanotech. 2013, 46, 236.
29. [29]
  Graf, D.; Molitor, F.; Ensslin, K.; Stampfer, C.; Jungen, A.; Hierold, C.; Wirtz, L. Nano Lett. 2007, 7, 238. doi: 10.1021/nl061702a
30. [30]
  Ferrari, A. C. Solid State Commun. 2007, 143, 47. doi: 10.1016/j.ssc.2007.03.052
31. [31]
  Casiraghi, C.; Hartschuh, A.; Qian, H.; Piscanec, S.; Georgi, C.; Fasoli, A.; Novoselov, K. S.; Basko, D. M.; Ferrari, A. C. Nano Lett. 2009, 9, 1433. doi: 10.1021/nl8032697
32. [32]
  Kudin, N. K.; Ozbas, B.; Schniepp, H. C.; Prud'homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 1, 36.
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
6. [6]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
9. [9]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
10. [10]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
11. [11]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
12. [12]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
13. [13]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
14. [14]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
15. [15]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
16. [16]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
17. [17]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
20. [20]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(918)
HTML views(195)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Preparation Conditions of MoO3/C-N Hybrid Materials on Its Structure and Catalytic Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance