Citation: Zhang Ting, Cai Xuediao, Liu Na, Xu Chunli. Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance[J]. Acta Chimica Sinica, ;2016, 74(5): 441-449. doi: 10.6023/A16010036 shu

Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance

Zhang Ting ^a ,
Cai Xuediao ^a,*,, ,
Liu Na ^b ,
Xu Chunli ^b

a.
Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
b.
Key Laboratory of Applied Surface and Colloid Chemistry of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

Corresponding author: Cai Xuediao, xdcai@snnu.edu.cn
Received Date: 18 January 2016

Fund Project: the Fundamental Research Funds for the Central Universities GK200902008

Figures(8)

Molybdenum oxide (MoO₃)/dodecylamine (DDA) intercalated materials were synthesized via direct thermal treatment followed by calcination to give MoO₃/C-N hybrid materials. These prepared intercalated materials were characterized by powder X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy to investigate the influences of the calcination conditions, such as calcination temperature, calcination heating rate and calcination time, on the structure and composition of these materials. The results exhibited the order-disorder-order changes of the crystal structure during the calcination temperature from 400 ℃ to 800 ℃. Meanwhile, the valence of some Mo was reduced from +6 to +4 or +2. XRD patterns showed that calcination heating rate had almost no effect on the composite structure. Crystal MoO₂ was produced with the increase of calcination time at 600 ℃ in N₂atmosphere. Crystal Mo₂C was formed and the crystalline became regular with the increase of calcination temperature when the calcination temperature was higher than 600 ℃. SEM and TEM images clearly showed that molybdenum oxide layers were kept with the reducing of interlayer spacing as the calcination temperature below 600 ℃. With the calcination temperature rising up to 800 ℃, the carbonization effect of carbonaceous molecules and the enormous loss of gas molecules made the layer structure collapsed. In addition, the carbon and nitrogen elements were detected on the surface of molybdenum oxide. MoO₃/C-N hybrid materials were used as catalyst for the oxidation of benzyl alcohol. The results showed that the structure and composition of the materials have a certain effect on the catalytic yield and the selectivity. The MoO₃/C-N hybrid materials formed at calcination of 600 ℃ in 2 h was found to catalyze benzyl alcohol to benzaldehyde efficiently with high selectivity and relative stability. The yield of oxidation of benzyl alcohol to benzaldehyde in 3 h was up to 30% with a high selectivity retention, which was nearly 4 times compared with that of the pristine MoO₃. The MoO₃/C-N hybrid materials used as catalyst can be recycled several times with high selectivity.
- molybdenum trioxide,
- hybrid materials,
- calcination,
- catalytic performance,
- oxidation of benzyl alcohol
1. [1]
  Faughnan, B. W.; Crandall, R. S. Appl. Phys. Lett. 1977, 31, 834. doi: 10.1063/1.89566
2. [2]
  Yao, J. N.; Loo, B. H.; Hashimoto, K.; Fujishima, A. J. Electroanal. Chem. 1990, 290, 263. doi: 10.1016/0022-0728(90)87436-N
3. [3]
  Yao, J. N.; Yang, Y. A.; Loo, B. H. J. Phys. Chem. B 1998, 102, 1856. doi: 10.1021/jp972217u
4. [4]
  Balendhran, S.; Deng, J.; Ou, J. Z.; Walia, S.; Scott, J.; Tang, J.; Wang, K. L.; Field, M. R.; Russo, S.; Zhuiykov, S.; Strano, M. S.; Medhekar, N.; Sriram, S.; Bhaskaran, M.; Kalantar-zadeh, K. Adv. Mater. 2013, 25, 109. doi: 10.1002/adma.201203346
5. [5]
  Campanel, L.; Pistoia, G. J. Electrochem. Soc. 1971, 118, 1905. doi: 10.1149/1.2407864
6. [6]
  Zhang, Z.; Yang, R. Y.; Umar, A.; Gao, Y. S.; Wang, J. Y.; Lu, P.; Guo, Z. H.; Huang, L.; Zhou, T. T.; Wang, Q. Adv. Mater. Sci. 2014, 6(10), 2159. doi: 10.1166/sam.2014.2127
7. [7]
  Brookes, C.; Wells, P. P.; Cibin, G.; Dimitratos, N.; Jones, W.; Morgan, D. J.; Bowker, M. ACS Catal. 2014, 4(1), 243. doi: 10.1021/cs400683e
8. [8]
  Shuwa, S. M.; Al-Hajri, R. S.; Jibril, B. Y.; Al-Waheibi, Y. M. Electron. Mater. Lett. 2015, 11(2), 252.
9. [9]
  Meyer, J.; Hamwi, S.; Kroger, M.; Kowalsky, W.; Riedl, T.; Kahn, A. Adv. Mater. 2012, 24, 5408. doi: 10.1002/adma.v24.40
10. [10]
  Alsaif, M. M. Y. A.; Balendhran, S.; Field, M. R.; Latham, K.; Wlodarski, W.; Ou, J. Z.; Kalantar-zadeh, K. Sens. Actuators, B: Chem. 2014, 192, 196. doi: 10.1016/j.snb.2013.10.107
11. [11]
  Suzuki, T.; Yamazaki, T.; Koukitu, A.; Maeda, M.; Seki, H.; Takahashi, K. J. Mater. Sci. Lett. 1988, 7, 926. doi: 10.1007/BF00720732
12. [12]
  Kamiya, S.; Tsuda, D.; Miura, K.; Sasaki, N. Wear 2004, 257, 1133. doi: 10.1016/j.wear.2004.07.012
13. [13]
  Sha, X. W.; Chen, L.; Cooper, A. C.; Pez, G. P.; Cheng, H. S. J. Phys. Chem. C 2009, 113, 11399. doi: 10.1021/jp9017212
14. [14]
  Dong, Y. F.; Xua, X. M.; Li, S.; Han, C. H.; Zhao, K. N.; Zhang, L.; Niu, C. J.; Huang, Z.; Mai, L. Q. Nano Energy 2015, 15, 145. doi: 10.1016/j.nanoen.2015.04.015
15. [15]
  Itoh, T.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M. Sens. Actuators, B 2008, 128, 512. doi: 10.1016/j.snb.2007.07.059
16. [16]
  Yao, D. D.; Ou, J. Z.; Latham, K.; Zhuiykov, S.; O'Mullane, A. P.; Kalantar-zadeh, K. Cryst. Growth Des. 2012, 12, 1865. doi: 10.1021/cg201500b
17. [17]
  Gesheva, K. A.; Ivanova, T. M.; Bodurov, G. Prog. Org. Coat. 2012, 74, 635. doi: 10.1016/j.porgcoat.2011.07.016
18. [18]
  Mai, L. Q.; Hu, B.; Chen, W.; Qi, Y. Y.; Lao, C. S.; Yang, R. S.; Dai, Y.; Wang, Z. L. Adv. Mater. 2007, 19, 3712. doi: 10.1002/(ISSN)1521-4095
19. [19]
  Itoh, T.; Wang, J. Z.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M.; Murayama, N. Mater. Lett. 2008, 62, 3021. doi: 10.1016/j.matlet.2008.01.099
20. [20]
  Itoh, T.; Matsubara, I.; Shin, W.; Izu, N.; Nishibori, M. Mater. Chem. Phys. 2008, 110, 115. doi: 10.1016/j.matchemphys.2008.01.024
21. [21]
  Murugana, A. V.; Viswanath, A. K. J. Appl. Phys. 2006, 100, 074319. doi: 10.1063/1.2356788
22. [22]
  Afsharpour, M.; Mahjoub, A. R.; Amini, M. M. J. Inorg. Organomet. Polym. 2009, 19, 298. doi: 10.1007/s10904-009-9285-5
23. [23]
  Afsharpour, M.; Mahjoub, A. R.; Amini, M. M.; Khodadadi, A. A. Curr. Nanosci. 2010, 6, 82. doi: 10.2174/157341310790226261
24. [24]
  Ji, H. M.; Liu, X. L.; Liu, Z. J.; Yan, B.; Chen, L.; Xie, Y. F.; Liu, C.; Hou, W. H.; Yang, G. Adv. Funct. Mater. 2015, 25, 1886. doi: 10.1002/adfm.201404378
25. [25]
  Qiu, J. Y. C.; Yang, Z. X.; Li, Y. J. Mater. Chem. A 2015, 3, 24245. doi: 10.1039/C5TA05924K
26. [26]
  Jing, Y.; Pan, Q. Y.; Cheng, Z. X.; Dong, X. W.; Xiang, Y. X. Mater. Sci. Eng. B 2007, 138, 55. doi: 10.1016/j.mseb.2007.01.015
27. [27]
  Saghafi, M.; Ataie, A.; Heshmati-Manesh, S. Int. J. Refract. Met. Hard Mater. 2011, 29, 419. doi: 10.1016/j.ijrmhm.2010.12.012
28. [28]
  Ferrari, A. C.; Basko, D. M. Nature Nanotech. 2013, 46, 236.
29. [29]
  Graf, D.; Molitor, F.; Ensslin, K.; Stampfer, C.; Jungen, A.; Hierold, C.; Wirtz, L. Nano Lett. 2007, 7, 238. doi: 10.1021/nl061702a
30. [30]
  Ferrari, A. C. Solid State Commun. 2007, 143, 47. doi: 10.1016/j.ssc.2007.03.052
31. [31]
  Casiraghi, C.; Hartschuh, A.; Qian, H.; Piscanec, S.; Georgi, C.; Fasoli, A.; Novoselov, K. S.; Basko, D. M.; Ferrari, A. C. Nano Lett. 2009, 9, 1433. doi: 10.1021/nl8032697
32. [32]
  Kudin, N. K.; Ozbas, B.; Schniepp, H. C.; Prud'homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 1, 36.
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
6. [6]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
7. [7]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
13. [13]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
14. [14]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
15. [15]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
16. [16]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
17. [17]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
18. [18]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
19. [19]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
20. [20]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(948)
HTML views(198)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Preparation Conditions of MoO3/C-N Hybrid Materials on Its Structure and Catalytic Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Preparation Conditions of MoO₃/C-N Hybrid Materials on Its Structure and Catalytic Performance