Citation: SHI Wei-Dong, REN Ao, LIU Chun-Bo, BAI Hong-Ye, CHE Guang-Bo, SUN He-Yi, CONG Yao. Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu

Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Received Date: 14 May 2013
Available Online: 9 October 2013
Fund Project: 国家科学自然基金(No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)资助项目。 (No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)

[CoCl_0.5(H₂O)_0.5(HDPPZC)₂](PW₁₂O₄₀)_0.5·3.5H₂O (1) has been synthesized under hydrothermal conditions using HDPPZC (dipyrido[3,2-a∶2',3'-c]-phenazine-2-carboxylic acid) as a neutral organic ligand. Compound 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, UV-Vis spectrum and thermogravimetric analysis (TGA). It crystallizes in triclinic, space group P1 with a=1.036 0(2) nm, b=1.564 0(3) nm, c=1.656 0(3) nm, α=80.99(3)°, β=84.93(3)°, γ=85.44(3)°, V=2.633 9(9) nm³, Z=1. Single-crystal X-ray diffraction analysis reveals that compounds 1 consists of a discrete dinuclear, linked by hydrogen bonding and π-π stacking interactions into 2D supramolecular framework. Furthermore, we studied the Rhodamine B (RhB) photodegration process by Compound 1 as the catalyst. CCDC: 968312.
- cobalt(Ⅱ) compound;crystal structure;photocatalytic property
1. [1]
  [1] Murray L J, Dinca M, Long J R. Chem. Soc. Rev., 2009, 38: 1294-1314
2. [2]
  [2] James S L. Chem. Soc. Rev., 2003, 32:276-288
3. [3]
  [3] Ferey G. Nat. Mater., 2003, 2:136-137
4. [4]
  [4] Zeng M H, Wang Q X, Tan Y X, et al. J. Am. Chem. Soc., 2010, 132:2561-2563
5. [5]
  [5] Silva C G, Corma A, Garcia H. J. Mater. Chem., 2010, 20: 3141-3156
6. [6]
  [6] Liu W T, Ou Y C, Xie Y L, et al. Eur. J. Inorg. Chem., 2009, 28:4213-4218
7. [7]
  [7] ZHAO Nan (赵楠), DENG Hong-Ping (邓洪平), SHU Mou-Hai (舒谋海), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (7):1213-1217
8. [8]
  [8] LIU Tong-Fei (刘同飞), CUI Guang-Hua (崔广华), JIAO Cui-Huan (焦翠欢), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (7):1417-1422
9. [9]
  [9] Liao Z L, Li G D, Bi M H, et al. Inorg. Chem., 2008, 47: 4844-4853
10. [10]
  [10] Lin H S, Maggard P A. Inorg. Chem., 2008, 47:8044-8052
11. [11]
  [11] Yu Z T, Liao Z L, Jiang Y S, et al. Chem.-A Eur. J., 2005, 11:2642-2650
12. [12]
  [12] Alvaro M, Carbonell E, Ferrer B, et al. Chem. Eur. J., 2007, 13:5106-5112
13. [13]
  [13] Du J J, Yuan Y P, Sun J X, et al. J. Hazard. Mater., 2011, 190:945-951
14. [14]
  [14] Wen L L, Wang F, Feng J, et al. Cryst. Growth Des., 2009, 9:3581-3589
15. [15]
  [15] Che G B, Chen J, Wang X C, et al. Inorg. Chem. Commun., 2011, 14:1086-1088
16. [16]
  [16] Gholamkhass B, Koike K, Negishi N, et al. Inorg. Chem., 2001, 40:756-765
17. [17]
  [17] Sheldrick G M. SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen: Göttingen, Germany, 1997.
18. [18]
  [18] Sheldrick G M. SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen: Göttingen, Germany, 1997.
19. [19]
  [19] Farrugia L J. WINGX, A Windows Program for Crystal Structure Analysis, University of Glasgow: Glasgow, United Kingdom, 1988.
20. [20]
  [20] Zhang G, Choi W. Chem. Commun., 2012, 48:10621-10623
21. [21]
  [21] Aarthi T, Madras G. Ind. Eng. Chem. Res., 2007, 46 (1):7-14
22. [22]
  [22] Anna K, Marcos F G, Gerardo C. Chem. Rev., 2012, 112 (3): 1555-1614
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沈阳化工大学材料科学与工程学院沈阳 110142