Citation:
ZHAO Li, DING Wei-Ping, PENG Lu-Ming. 17O Solid-State NMR Studies of Ce3+ Doped La2O3[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(12): 2509-2513.
doi:
10.3969/j.issn.1001-4861.2013.00.399
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In this paper, La2O3 doped with varied Ce3+ concentrations were synthesized via hydrothermal co-precipitation followed by high temperature calcined process in H2/N2 atmosphere. Three new peaks show up at 698, 650 and 558 in 17O solid state NMR spectra due to Ce3+ doping. The intensies of these peaks increase with Ce3+ concentration. According to the resonant frequencies and the intensities, the peaks at around 698 and 650, and 558 are assigned to four-coordinated OCeLa3 and six-coordinated OCeLa5 species, respectively. The results show that 17O solid-state NMR spectroscopy can be used to study rare earth doped oxides for applicable functional materials.
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