Citation: ZHAO Li, DING Wei-Ping, PENG Lu-Ming. ¹⁷O Solid-State NMR Studies of Ce³⁺ Doped La₂O₃[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2509-2513. doi: 10.3969/j.issn.1001-4861.2013.00.399 shu

¹⁷O Solid-State NMR Studies of Ce³⁺ Doped La₂O₃

1.
Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 4 May 2013
Available Online: 4 July 2013
Fund Project: 973计划青年科学专题(No．2013CB934800)资助项目。 (No．2013CB934800)

In this paper, La₂O₃ doped with varied Ce³⁺ concentrations were synthesized via hydrothermal co-precipitation followed by high temperature calcined process in H₂/N₂ atmosphere. Three new peaks show up at 698, 650 and 558 in ¹⁷O solid state NMR spectra due to Ce³⁺ doping. The intensies of these peaks increase with Ce³⁺ concentration. According to the resonant frequencies and the intensities, the peaks at around 698 and 650, and 558 are assigned to four-coordinated OCeLa₃ and six-coordinated OCeLa₅ species, respectively. The results show that ¹⁷O solid-state NMR spectroscopy can be used to study rare earth doped oxides for applicable functional materials.
- lanthanum oxide;NMR;Ce³⁺;density functional theory;¹⁷O
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

17O Solid-State NMR Studies of Ce3+ Doped La2O3

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通讯作者: 陈斌, bchen63@163.com

¹⁷O Solid-State NMR Studies of Ce³⁺ Doped La₂O₃