Citation: XU Jing, CHEN Min-Dong. Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2666-2672. doi: 10.3969/j.issn.1001-4861.2013.00.398 shu

Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand

XU Jing ,
CHEN Min-Dong

1.
Key laboratory of atmospheric environment monitoring and pollution control, School of environment science and technology, Nanjing University of Information Science and Technology, Nanjing 210044, China

Received Date: 19 July 2013
Available Online: 27 August 2013
Fund Project: 国家自然科学基金(No.21272118)资助项目。 (No.21272118)

Reactions of ligand 4-[(1H-imidazol-4-yl)methylamino]benzoic acid (H₂L) with transition metal salts led to the formation of three complexes [M(HL)₂(H₂O)₂](M(Ⅱ)=Mn(Ⅱ)(1), Cd(Ⅱ)(2), Cu(Ⅱ)(3)) under different conditions. The single crystal X-ray diffraction analyses revealed that three complexes crystallized in the same triclinic space group P1 are isomorphous and isostructural, and the molecules are further connected by hydrogen bonds interactions resulting in formation of 3D structures. Thermal stability and electrochemistry properties of complexes were also investigated. CCDC: 945340, 1; 945338, 2; 945339, 3.
- 4-[(1H-imidazol-4-yl)methylamino]benzoic acid;complex;hydrgen bonding interaction;properties
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