Citation: XU Jing, CHEN Min-Dong. Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2666-2672. doi: 10.3969/j.issn.1001-4861.2013.00.398 shu

Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand

XU Jing ,
CHEN Min-Dong

1.
Key laboratory of atmospheric environment monitoring and pollution control, School of environment science and technology, Nanjing University of Information Science and Technology, Nanjing 210044, China

Received Date: 19 July 2013
Available Online: 27 August 2013
Fund Project: 国家自然科学基金(No.21272118)资助项目。 (No.21272118)

Reactions of ligand 4-[(1H-imidazol-4-yl)methylamino]benzoic acid (H₂L) with transition metal salts led to the formation of three complexes [M(HL)₂(H₂O)₂](M(Ⅱ)=Mn(Ⅱ)(1), Cd(Ⅱ)(2), Cu(Ⅱ)(3)) under different conditions. The single crystal X-ray diffraction analyses revealed that three complexes crystallized in the same triclinic space group P1 are isomorphous and isostructural, and the molecules are further connected by hydrogen bonds interactions resulting in formation of 3D structures. Thermal stability and electrochemistry properties of complexes were also investigated. CCDC: 945340, 1; 945338, 2; 945339, 3.
- 4-[(1H-imidazol-4-yl)methylamino]benzoic acid;complex;hydrgen bonding interaction;properties
1. [1]
  [1] Bernstein J, Davey R J, Henck J O. Angew. Chem. Int. Ed., 1999, 38:3441-3461
2. [2]
  [2] Eckert H, Ward M. Chem. Mater., 2001, 13:3061-3083
3. [3]
  [3] Rao C N R, Natarajan S, Vaidhyanathan R. Angew. Chem. Int. Ed., 2004, 43:1466-1496
4. [4]
  [4] Helay F, Maris T, Wuest J D. Cryst. Growth Des., 2008, 8: 4517-4525
5. [5]
  [5] Manzano B R, Jaló n F A, Soriano M L, et al. Cryst. Growth Des., 2008, 8:15851594
6. [6]
  [6] Li Y P, Yang P. Chin. J. Chem., 2007, 5:1715-1724
7. [7]
  [7] Yang X G, Li D S, Fu F, et al. Chin. J. Chem., 2008, 26:655-660
8. [8]
  [8] ZHANG Li (张丽), NIU Su-Yun (牛淑云), JIN Jin (金晶), et al. Acta Chim. Sin. (Huaxue Xuebao), 2007, 65:1032-1038
9. [9]
  [9] Cote A P, Benin A I, Ockwig N W, et al. Science, 2005, 310: 1166-1170.
10. [10]
  [10] Yaghi O M, O′Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714
11. [11]
  [11] Wu C D, Hu A, Zhang L, et al. J. Am. Chem. Soc., 2005, 127:8940-8941
12. [12]
  [12] Fang Q R, Zhu G S, Xue M, et al. Cryst. Growth Des., 2008, 8:319-329
13. [13]
  [13] Koh K, Wong-Foy A G, Matzger A J. Angew. Chem. Int. Ed., 2008, 47:677-680.
14. [14]
  [14] Song Y, Zhang P, Ren X M, et al. J. Am. Chem. Soc., 2005, 127:3708-3709
15. [15]
  [15] Yigit M V, Biyikli K, Moulton B, et al. Cryst. Growth Des., 2006, 6:63-69
16. [16]
  [16] Gao H L, Ding B, Yi L, et al. Inorg. Chem. Commun., 2005, 8:151-153
17. [17]
  [17] Gao H L, Yi L, Ding B, et al. Inorg. Chem., 2006, 45:481-483
18. [18]
  [18] Ghosh S K, Bharadwaj P K. Eur. J. Inorg. Chem., 2005, 4886-4889
19. [19]
  [19] Wang H S, Zhao B, Zhai B, et al. Cryst. Growth Des., 2007, 7:1851-1857
20. [20]
  [20] Koh C K. Chem. Soc. Rev., 2002, 31:157-167
21. [21]
  [21] SAINT, Pragram for Data Extraction and Reduction, Bruker AXS, Inc.; Madison, WI, 2001.
22. [22]
  [22] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
24. [24]
  [24] Hellyer R M, Larsen D S, Brooker S. Eur. J. Inorg. Chem., 2009, 1162-1171
25. [25]
  [25] Nicola C D, Garau F, Karabach Y Y, et al. Eur. J. Inorg. Chem., 2009, 666-676
26. [26]
  [26] Wang X L, Lin H Y, Liu G C, et al. J. Organomet. Chem., 2008, 693:2767-2774
27. [27]
  [27] Wang X L, Zhao H Y, Lin H Y, et al. Electroanalysis, 2008, 20:1055-1059
28. [28]
  [28] Younathan J N, Wood K S, Meyer T J. Inorg. Chem., 1992, 31:3280-3285
1. [1]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
2. [2]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
5. [5]
  Simin Fang , Hong Wu , Sizhe Sheng , Lingling Li , Yuxi Wang , Hongchun Li , Jun Jiang . The Food Kingdom Lecture Series: The Science behind Color. University Chemistry, 2024, 39(9): 177-182. doi: 10.12461/PKU.DXHX202402012
6. [6]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029
7. [7]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
8. [8]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
9. [9]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
10. [10]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
11. [11]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
12. [12]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
13. [13]
  Qianping Li , Hua Guan , Changfeng Wan , Yonghai Song , Jianwen Jiang . 大学有机化学复习课项目式教学——以“液晶化合物4-正戊基苯甲酸-4′-正戊基苯酯的合成路线设计与产品制备”为例. University Chemistry, 2025, 40(8): 100-116. doi: 10.12461/PKU.DXHX202410070
14. [14]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
15. [15]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
16. [16]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
17. [17]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
18. [18]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
19. [19]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
20. [20]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(532)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142