Citation: YE Xing-Pei, WU Wei-Na, LI Fei-Fei, CAI Hong-Xin, WANG Yuan. A Cadmium(Ⅱ) Complex with a Quinolinyloxy Acetamide Ligand： Synthesis, Crystal Structure and Fluorescence Spectra[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2678-2682. doi: 10.3969/j.issn.1001-4861.2013.00.394 shu

A Cadmium(Ⅱ) Complex with a Quinolinyloxy Acetamide Ligand： Synthesis, Crystal Structure and Fluorescence Spectra

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Received Date: 20 April 2013
Available Online: 28 June 2013
Fund Project: 国家自然科学基金(No.21001040)，河南省科技厅基础与前沿研究项目(No.132200410404)，河南省教育厅自然科学基金(No.12B150011) (No.21001040)，河南省科技厅基础与前沿研究项目(No.132200410404)，河南省教育厅自然科学基金(No.12B150011)河南理工大学青年骨干教师项目(No.649210)资助项目。 (No.649210)

[CdL(H₂O)(NO₃)]NO₃·CH₃COCH₃(1) (L=N-methyl-N-phenyl-2-(quinolin-8-yloxy)acetamide), was synth-esized and characterized by X-ray diffraction. In complex 1, the Cd(Ⅱ) center is coordinated with two O atoms and one N atom from one ligand L, two O atoms from two mono-dentate nitrate anions and one O atom from one water molecule, possessing a distorted octahedral coordination geometry. In the crystal, intramolecular O-H…O hydrogen bonds between the coordinated water molecules and free nitrate O atoms link the complexes into chains along the a axis. In CH₃CN solution, both ligand L and complex 1 exhibit emission band at 390 nm. However, the emission intensity of 1 is much lower than that of the ligand L. CCDC: 958121.
- 8-hydroxyquinoline;acetamide;cadmium complex;crystal structure;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142