Citation: YE Xing-Pei, WU Wei-Na, LI Fei-Fei, CAI Hong-Xin, WANG Yuan. A Cadmium(Ⅱ) Complex with a Quinolinyloxy Acetamide Ligand： Synthesis, Crystal Structure and Fluorescence Spectra[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2678-2682. doi: 10.3969/j.issn.1001-4861.2013.00.394 shu

A Cadmium(Ⅱ) Complex with a Quinolinyloxy Acetamide Ligand： Synthesis, Crystal Structure and Fluorescence Spectra

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Received Date: 20 April 2013
Available Online: 28 June 2013
Fund Project: 国家自然科学基金(No.21001040)，河南省科技厅基础与前沿研究项目(No.132200410404)，河南省教育厅自然科学基金(No.12B150011) (No.21001040)，河南省科技厅基础与前沿研究项目(No.132200410404)，河南省教育厅自然科学基金(No.12B150011)河南理工大学青年骨干教师项目(No.649210)资助项目。 (No.649210)

[CdL(H₂O)(NO₃)]NO₃·CH₃COCH₃(1) (L=N-methyl-N-phenyl-2-(quinolin-8-yloxy)acetamide), was synth-esized and characterized by X-ray diffraction. In complex 1, the Cd(Ⅱ) center is coordinated with two O atoms and one N atom from one ligand L, two O atoms from two mono-dentate nitrate anions and one O atom from one water molecule, possessing a distorted octahedral coordination geometry. In the crystal, intramolecular O-H…O hydrogen bonds between the coordinated water molecules and free nitrate O atoms link the complexes into chains along the a axis. In CH₃CN solution, both ligand L and complex 1 exhibit emission band at 390 nm. However, the emission intensity of 1 is much lower than that of the ligand L. CCDC: 958121.
- 8-hydroxyquinoline;acetamide;cadmium complex;crystal structure;fluorescence
1. [1]
  [1] Wang H P, Ma Y F, Tian H, et al. Dalton Trans., 2010, 39: 7485-7492
2. [2]
  [2] Wang H P, Li H G, Lu G N, et al. Inorg. Chem. Commun., 2010, 13:882-886
3. [3]
  [3] Wu W N, Tang N, Yan L. J. Fluoresc., 2008, 18:101-107
4. [4]
  [4] Wu W N, Cheng F X, Yan L, et al. J. Coord. Chem., 2008, 61:2207-2215
5. [5]
  [5] Wu W N, Tang N, Yan L. Spectrochim. Acta A, 2008, 71: 1461-1465
6. [6]
  [6] Zhou X Y, Li P X, Shi Z H, et al. Inorg. Chem., 2012, 51: 9226-9231
7. [7]
  [7] Wang Y, Wu W N. Chinese J. Struct. Chem., 2012, 31:777-782
8. [8]
  [8] WU Wei-Na (吴伟娜), WANG Yuan (王元), TANG Ning (唐宁), Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28:425-428
9. [9]
  [9] Zhi L H, Wu W N, Li S, et al. Acta Cryst. E, 2011, 67:o1420
10. [10]
  [10] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
11. [11]
  [11] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
12. [12]
  [12] Nakamato K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. New York: John Wiley, 1978:227
13. [13]
  [13] Song X Q, Zang Z P, Liu W S, et al. J. Solid State Chem., 2009, 182:841-848
14. [14]
  [14] ZHUO Xin (卓馨), PAN Zhao-Rui (潘兆瑞), WANG Zuo-Wei (王作为), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006, 22:1847-1851
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沈阳化工大学材料科学与工程学院沈阳 110142