Citation: CHEN Man-Sheng, XU Jin-Sheng, DENG Yi-Fang, ZHANG Chun-Hua, KUANG Dai-Zhi, NIE Xue. Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of Nd(Ⅲ) Complex Constructed from 5-(Isonicotinamido)-isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2673-2677. doi: 10.3969/j.issn.1001-4861.2013.00.390 shu

Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of Nd(Ⅲ) Complex Constructed from 5-(Isonicotinamido)-isophthalic Acid

1.
Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008, China

Received Date: 8 May 2013
Available Online: 19 June 2013
Fund Project: 湖南省自然科学基金(No.13JJ6069)，湖南省教育厅创新平台开放基金(No.11K009) (No.13JJ6069)，湖南省教育厅创新平台开放基金(No.11K009)湖南省科技计划重点(No.2012FJ2002)资助项目。 (No.2012FJ2002)

The complex [Nd(HINAIP)(INAIP)(H₂O)₂]_n·nH₂O was obtained by hydrothermal assembly of Nd(Ⅲ) salt with a 5-(isonicotinamido) isophthalic acid(H₂INAIP) and its crystal structure was determined by X-ray single-crystal diffraction. It is of triclinic, P1 space group space group. Single-crystal X-ray diffraction analysis revealed that the HINAIP^- and INAIP^2- ligands connect Nd(Ⅲ)-carboxylate chains to form 2D layers in complex 1. Finally, It was extended to 3D supramolecular structures by H-bonding interactions. The complex was characterized by TG, IR, UV and near IR fluorescence spectra. CCDC: 958122.
- 5-(isonicotinamido)isophthalic acid;crystal structure;hydrothermal synthesis;photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142