Citation: WANG Peng-Fei, FANG Qin, WU Guo-Zhi, WANG Xin. Synthesis, Crystal Structure and Luminescent Property of a Three-Dimensional Framework Zinc Coordination Polymer Constructed from the Benzenemulticarboxylic Acid and N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2521-2527. doi: 10.3969/j.issn.1001-4861.2013.00.387 shu

Synthesis, Crystal Structure and Luminescent Property of a Three-Dimensional Framework Zinc Coordination Polymer Constructed from the Benzenemulticarboxylic Acid and N-donor Ligands

1.
1 Center of Chemical Materials and Engineering Experiment, Department of Materials and Chemical Engineering, Chizhou College, Chizhou, Anhui 247000, China;

Received Date: 7 April 2013
Available Online: 31 May 2013
Fund Project: 国家自然科学基金(No.21101019) (No.21101019)池州学院材料学重点学科(No.2011XK04)资助项目。 (No.2011XK04)

A novel coordination polymer, [Zn₃(BTCA)₂(4,4'-bipy)₂](1) (BTCAH₃=5-bromobenzene-1,2,4-tricarboxylic acid, 4,4'-bipy=4,4'-bipyridine) has been synthesized utilizing Zn(OAc)₂·2H₂O, the rigid 5-bromobenzene-1,2,4-tricarboxylic acid and 4,4'-bipy under the hydrothermal reaction. Compound 1 was characterized by infrared spectroscopy, elemental analysis, thermogravimetric analysis and single crystal X-ray diffraction analysis. In 1, the Zn(Ⅱ) ions are linked through the carboxylate oxygen atoms of the BTCA^3- anions, forming a three-dimensional framework structure with 3-nodal and 4-connected net with Schläfli symbol of (4·7·8⁴)₂(4·7⁴·8)₂(7⁴·8²). The 4,4'-bipy ligand coordinates the Zn(Ⅱ) ions in the framework. In addition, the thermal stability and luminescent properties of Compound 1 were also investigated in this paper. CCDC: 811925.
- metal-organic frameworks;crystal structure;multicarboxylate ligand;luminescent property
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