Citation:
LIN Shun-Jia, SUN Hong-Juan, PENG Tong-Jiang, LIU Bo. Structure Change of Quaternary Alkylammonium-Graphite Oxide Intercalation Composite[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(11): 2333-2338.
doi:
10.3969/j.issn.1001-4861.2013.00.383
-
The graphite oxide (GO) samples were prepared from flake graphite via modified Hummers method. Aseries of quaternary alkylammonium-graphite oxide intercalation composites (CnTAB/GO) were synthesized by changing the alkyl chain length and surfactant concentration, respectively. The structure and intercalated amount of CnTAB for intercalation composites were characterized by using XRDand elemental analysis. The results suggest that the interlayer spacing of CnTAB/GO composites increases with the increase of alkyl chain length or surfactant concentration. It is also found that the experimental data obtained from surfactants in GO spacing have been fitted well into the Modified Langmuir adsorption isotherm equations,indicating that the CnTAB molecules are adsorbed on the surface of GO within a monomolecular layer. The result of elemental analysis also suggests that surfactant is intercalated into GO spacing via electrovalent and hydrophobic interaction. Finally, the arrangement models of the surfactant in the layer of GO include lateral monolayer, lateral bilayer, paraffin-type monolayer and vertical monolayer.
-
References
-
[1]
[1] Stankovieh S, Dikin D A, Dommett H B. Nature, 2006,442 (7100):282-286
-
[2]
[2] Wei T, Luo G L, Fan Z J, et al. Carbon, 2009,47:2296-2299
-
[3]
[3] Ramanathan T, Abdala A A, Stankovich S, et al. Nat. Nan otechnol., 2008,3:327-331
-
[4]
[4] Liang J J, Xu Y F, Huang Y, et al. Phys. Chem. C, 2009, 113:9921-9927
-
[5]
[5] Matsuo Y, Watanabe K, Fukutsuka T, et al. Carbon, 2003, 41:1545-1550
-
[6]
[6] WU Ping-Xiao(吴平霄), LI Rong(李荣), DANG Zhi(党志). J. South China University of Technology(Huanan Ligong Daxue Xuebao), 2006,34(5):15-19
-
[7]
[7] Huang Y, Ma X Y, Liang G Z, et al. Polymer, 2008,49: 2085-2094
-
[8]
[8] Cao Y W, Feng J C, Wu P Y. Carbon, 2010,48(5):1683-1685
-
[9]
[9] Liang Y, Wu D, Feng X, et al. Adv. Mater., 2009,21:1679-1683
-
[10]
[10]HAN Zhi-Dong(韩志东), WANG Jian-Qi(王建祺). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,5(19):459-461
-
[11]
[11]Matsuo Y, Niwa T, Sugie Y. Carbon, 1999,37:897-901
-
[12]
[12]Hummers Jr W S, Offeman R E. J. Am. Chem. Soc., 1958,80(6):1339-1339
-
[13]
[13]YANG Yong-Hiu(杨勇辉), SUN Hong-Juan(孙红娟), PENG Tong-Jiang(彭同江). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(11): 2083-2090
-
[14]
[14]He H Y, Klinowski J, Forster M, et al. Chem. Phys. Lett., 1998,287:53-56
-
[15]
[15]Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007, 45:1558-1565
-
[16]
[16]Schniepp H C, Li J L, McAllister M J, et al. J. Phys. Chem. B, 2006,110(17):8535-8537
-
[17]
[17]LÜXian-Jun(吕宪俊), CHEN Ping(陈平). J. Chinese Ceram. Soc.(Guisuanyan Xuebao), 2011,39(10):1553-1558
-
[18]
[18]CHEN Bao-Liang(陈宝梁), MAO Jie-Fei(毛洁菲), LÜShao-Fang(吕少芳). Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2009,30(9):1830-1834
-
[19]
[19]Boyd S A, Mortland M M, Chiou C T. Soil. Sci. Soc. Am. J., 1988,52(3):652-657
-
[20]
[20]Daryn S W, Thomas R K, Castro M A, et al. J. Colloid Interf. Sci., 2003,267:265-271
-
[21]
[21]Ray F, He H P, Theo K, et al. Appl. Clay Sci., 2006,31: 262271
-
[22]
[22]Vaia R A, Teukolsky R K, Giannelis E P. Chem. Mater., 1994,6:1017-1022
-
[23]
[23]Beneke K, Lagaly G. Clays Clay Miner., 1981,16:1-21
-
[24]
[24]Brindley G W, Moll W F. Am. Miner., 1955,50:1355-1370
-
[25]
[25]Khate D, Chaudhary R. J. Mater. Sci., 2007,42(3):729-746
-
[1]
-
-
[1]
[1] Stankovieh S, Dikin D A, Dommett H B. Nature, 2006,442 (7100):282-286
-
[2]
[2] Wei T, Luo G L, Fan Z J, et al. Carbon, 2009,47:2296-2299
-
[3]
[3] Ramanathan T, Abdala A A, Stankovich S, et al. Nat. Nan otechnol., 2008,3:327-331
-
[4]
[4] Liang J J, Xu Y F, Huang Y, et al. Phys. Chem. C, 2009, 113:9921-9927
-
[5]
[5] Matsuo Y, Watanabe K, Fukutsuka T, et al. Carbon, 2003, 41:1545-1550
-
[6]
[6] WU Ping-Xiao(吴平霄), LI Rong(李荣), DANG Zhi(党志). J. South China University of Technology(Huanan Ligong Daxue Xuebao), 2006,34(5):15-19
-
[7]
[7] Huang Y, Ma X Y, Liang G Z, et al. Polymer, 2008,49: 2085-2094
-
[8]
[8] Cao Y W, Feng J C, Wu P Y. Carbon, 2010,48(5):1683-1685
-
[9]
[9] Liang Y, Wu D, Feng X, et al. Adv. Mater., 2009,21:1679-1683
-
[10]
[10]HAN Zhi-Dong(韩志东), WANG Jian-Qi(王建祺). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,5(19):459-461
-
[11]
[11]Matsuo Y, Niwa T, Sugie Y. Carbon, 1999,37:897-901
-
[12]
[12]Hummers Jr W S, Offeman R E. J. Am. Chem. Soc., 1958,80(6):1339-1339
-
[13]
[13]YANG Yong-Hiu(杨勇辉), SUN Hong-Juan(孙红娟), PENG Tong-Jiang(彭同江). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(11): 2083-2090
-
[14]
[14]He H Y, Klinowski J, Forster M, et al. Chem. Phys. Lett., 1998,287:53-56
-
[15]
[15]Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007, 45:1558-1565
-
[16]
[16]Schniepp H C, Li J L, McAllister M J, et al. J. Phys. Chem. B, 2006,110(17):8535-8537
-
[17]
[17]LÜXian-Jun(吕宪俊), CHEN Ping(陈平). J. Chinese Ceram. Soc.(Guisuanyan Xuebao), 2011,39(10):1553-1558
-
[18]
[18]CHEN Bao-Liang(陈宝梁), MAO Jie-Fei(毛洁菲), LÜShao-Fang(吕少芳). Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2009,30(9):1830-1834
-
[19]
[19]Boyd S A, Mortland M M, Chiou C T. Soil. Sci. Soc. Am. J., 1988,52(3):652-657
-
[20]
[20]Daryn S W, Thomas R K, Castro M A, et al. J. Colloid Interf. Sci., 2003,267:265-271
-
[21]
[21]Ray F, He H P, Theo K, et al. Appl. Clay Sci., 2006,31: 262271
-
[22]
[22]Vaia R A, Teukolsky R K, Giannelis E P. Chem. Mater., 1994,6:1017-1022
-
[23]
[23]Beneke K, Lagaly G. Clays Clay Miner., 1981,16:1-21
-
[24]
[24]Brindley G W, Moll W F. Am. Miner., 1955,50:1355-1370
-
[25]
[25]Khate D, Chaudhary R. J. Mater. Sci., 2007,42(3):729-746
-
[1]
-
-
-
[1]
Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
-
[2]
Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
-
[3]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[4]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[5]
Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
-
[6]
Qiying Xia , Guokui Liu , Yunzhi Li , Yaoyao Wei , Xia Leng , Guangli Zhou , Aixiang Wang , Congcong Mi , Dengxue Ma . Construction and Practice of “Teaching-Learning-Assessment Integration” Model Based on Outcome Orientation: Taking “Structural Chemistry” as an Example. University Chemistry, 2024, 39(10): 361-368. doi: 10.3866/PKU.DXHX202311007
-
[7]
Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
-
[8]
Hao Ren , Wen Zhao , Fangna Dai , Wenyue Guo . Finite Difference Solution of One-Dimensional Quantum Systems: (1) Fundamental Concepts and Infinite Square Well. University Chemistry, 2025, 40(3): 124-131. doi: 10.12461/PKU.DXHX202405145
-
[9]
Xiping Luo , Xing Wang , Shengxiang Yang , Jianzhong Guo , Yuxuan Wang , Xuejuan Yang . Innovative “One Body, Dual Wings” Embedded Talent Cultivation Model: Practice in the Construction of Applied Chemistry Major at Zhejiang Agriculture and Forestry University. University Chemistry, 2024, 39(3): 205-209. doi: 10.3866/PKU.DXHX202309058
-
[10]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[11]
Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
-
[12]
Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
-
[13]
Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
-
[14]
Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO2 capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
-
[15]
Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
-
[16]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[17]
Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
-
[18]
Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
-
[19]
Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
-
[20]
Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(533)
- HTML views(93)