Citation: LIN Shun-Jia, SUN Hong-Juan, PENG Tong-Jiang, LIU Bo. Structure Change of Quaternary Alkylammonium-Graphite Oxide Intercalation Composite[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2333-2338. doi: 10.3969/j.issn.1001-4861.2013.00.383 shu

Structure Change of Quaternary Alkylammonium-Graphite Oxide Intercalation Composite

1.
1 School of Science, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;

Received Date: 14 May 2013
Available Online: 27 June 2013
Fund Project: 国家自然科学基金(No.41272051) (No.41272051)西南科技大学博士基金(No.11ZX7135) (No.11ZX7135)西南科技大学研究生创新基金(13ycjj49)资助项目。 (13ycjj49)

The graphite oxide (GO) samples were prepared from flake graphite via modified Hummers method. Aseries of quaternary alkylammonium-graphite oxide intercalation composites (C_nTAB/GO) were synthesized by changing the alkyl chain length and surfactant concentration, respectively. The structure and intercalated amount of C_nTAB for intercalation composites were characterized by using XRDand elemental analysis. The results suggest that the interlayer spacing of C_nTAB/GO composites increases with the increase of alkyl chain length or surfactant concentration. It is also found that the experimental data obtained from surfactants in GO spacing have been fitted well into the Modified Langmuir adsorption isotherm equations,indicating that the C_nTAB molecules are adsorbed on the surface of GO within a monomolecular layer. The result of elemental analysis also suggests that surfactant is intercalated into GO spacing via electrovalent and hydrophobic interaction. Finally, the arrangement models of the surfactant in the layer of GO include lateral monolayer, lateral bilayer, paraffin-type monolayer and vertical monolayer.
- graphite oxide;quaternary alkylammonium;one-dimensional structure;arrangement model
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沈阳化工大学材料科学与工程学院沈阳 110142