Citation:
ZHOU Chao, WANG Dan, GAO Yan-Min. Fabrication and Characterization of Cu2ZnSnS4 (CZTS) Microparticles[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(11): 2382-2386.
doi:
10.3969/j.issn.1001-4861.2013.00.376
-
Quaternary kesterite Cu2ZnSnS4(CZTS) micro-particles were successfully synthesized by a facile solvothermal method in ethylene glycol with the presence of Polyvinylpyrrolidone (PVP) as surfactant, using CuCl2·2H2O、Zn(Ac)2·2H2O and SnCl4·5H2O as metal precursor and thiourea as sulfur source. Different dispersion CZTS particles were obtained by different contents of PVP. The structure, morphology and absorption spectra of the as-obtained CZTS particles were characterized by means of X-ray diffraction(XRD), Raman spectroscopy, scanning electron microscopy(SEM), transmission electron microscopy(TEM), UV-V is spectroscopy. The results revealed that the structure of as-synthesized CZTS microparticles is kesterite;the morphology of CZTS has occurred a certain change with different contents of PVP. When 0.2 g of PVP was added to the reaction system, uniform and monodisperse CZTS MCs containing nanosheets were obtained. The nanosheets was more compact than the reaction system with 0.1 g of PVP. The band gap of the CZTS is about 1.47 eV, which approaches the optimum value for solar photoelectric conversion. Finally, a possible fabrication mechanisms of uniform and monodisperse CZTS MCs containing nanosheets was also inferred.
-
-
-
[1]
[1] Philip J, Dimitrios H, Erwin L, et al. Prog. Photovolt: Res. Appl., 2011,19:894-897
-
[2]
[2] Teodor K T, Tang J, Santanu B, et al. Adv. Energy Mater., 2013,1:34-38
-
[3]
[3] Shockley W, Queisser H J. J. Appl. Phys, 1961,32:510-519
-
[4]
[4] Michelle D R, Chen Y, Suo H L, et al. Chem. Eur. J., 2012,18:3127-3131
-
[5]
[5] Lu X T, Zhuang Z B, Peng Q, et al. Chem. Commun., 2011, 47:3141-3143
-
[6]
[6] Li M, Zhou W H, Guo J, et al. J. Phys. Chem. C, 2012,116: 26507-26516
-
[7]
[7] Anthony S R C, Neol W D, Steve P, et al. RSC Adv., 2013,3:1017-1020
-
[8]
[8] Su Z H, Yan C, Tang D, et al. Crystengcomm, 2012,14:782-785
-
[9]
[9] Wang L, Wang W Z, Sun S M. J. Mater. Chem., 2012,22: 6553-6555
-
[10]
[10] Li Z Q, Shi J H, Liu Q Q, et al. Nanotechnology, 2011,22: 265615
-
[11]
[11]Ahmed S, Reuter K B, Gunawan O, et al. Adv. Energy Mater., 2012,2:253-259
-
[12]
[12]Woo K, Kim Y, Moon J. Energy Environ. Sci., 2012,5:5340-5345
-
[13]
[13]Xu J, Yang X, Yang Q D, et al. J. Phys. Chem. C, 2012, 116,19718-19723
-
[14]
[14]CAI Qian(蔡倩), XIANG Wei-Dong(向卫东), LIANG Xiao-Juan(梁晓娟),et al. Bull. Chin. Ceram. Soc.(Guisuanyan Tongbao), 2011,30(6):1333-1342
-
[15]
[15]Chet S, Matthew G P, Vahid A, et al. J. Am. Chem. Soc., 2009,131,12554-12555
-
[16]
[16]NIE Qiu-Lin(聂秋林), ZHEN Yi-Fan(郑遗凡), YUE Lin-Hai (岳林海), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(4):445-448
-
[17]
[17]Zhou Y L, Zhou W H, Li M, et al. J. Phys. Chem. C, 2011,115:19632-19639
-
[1]
-
-
-
[1]
Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu2(Salen)2 Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
-
[2]
Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
-
[3]
Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO2 batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
-
[4]
Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
-
[5]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[6]
Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
-
[7]
Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
-
[8]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[9]
Haiming Wu , Gaya N. Andrew , Rajini Anumula , Zhixun Luo . Corrigendum to 'How ligand coordination and superatomic-states accommodate the structure and property of a metal cluster: Cu4 (dppy)4 Cl2 vs. Cu21 (dppy)10 with altered photoluminescence' [Chin. Chem. Lett. 35 (2024) 108340]. Chinese Chemical Letters, 2024, 35(12): 109912-. doi: 10.1016/j.cclet.2024.109912
-
[10]
Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
-
[11]
Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
-
[12]
Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
-
[13]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[14]
Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
-
[15]
Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu2Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu2+ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
-
[16]
Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
-
[17]
Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
-
[18]
Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
-
[19]
Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
-
[20]
Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO2/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(224)
- HTML views(17)