Citation: ZHANG Hua, XU Xiao-Wu, WU Fang-Ying. Synthesis of s-Triazine Derivatives and Application of Heavy Metal Ions Recognition[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2394-2398. doi: 10.3969/j.issn.1001-4861.2013.00.375 shu

Synthesis of s-Triazine Derivatives and Application of Heavy Metal Ions Recognition

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China

Received Date: 29 March 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.21365014) (No.21365014)江西省自然科学基金(No.20132BAB203011)资助项目。 (No.20132BAB203011)

Anew compound, namely 2,4-di(2-thiazole)-6-[2-(4-N,N-dimethylamino)phenylethenyl]-1,3,5-s-triazine (2), was synthesized and fully characterized. Compound 2 displayed double absorption peaks at 355 and 416 nm in the acetonitrile-water mixed medium. In the presence of various metal ions, a new absorption band peaking at 520 nm was appeared for Cu²⁺, Hg²⁺ and Fe³⁺ ions. The binding stoichiometry of compound 2 with Cu²⁺, Hg²⁺ and Fe³⁺ ions was 1:1 and the association constants were 1.9×10⁵, 6.6×10³ and 2.7×10³ L·mol^-1, respectively. Compound 4 exhibited similar spectral response to metal ions with compound 2. The binding mode for compounds 2 with these heavy metal ions was investigated using₁H NMR spectral titration as well. The results suggested that Cu²⁺, Hg²⁺ and Fe³⁺ ions coordinated with the Natom of the triazine and the Satom of thiophene cooperatively.
- s-triazine derivatives;colorimetric assay;Cu²⁺;Hg²⁺;Fe³⁺
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沈阳化工大学材料科学与工程学院沈阳 110142