Citation: YU Jiang-Xi, KUANG Dai-Zhi, FENG Yong-Lan, ZHANG Fu-Xing, WANG Jian-Qiu, JIANG Wu-Jiu, ZHU Xiao-Ming, PENG Yan, YANG Yi. Synthesis, Characterization, Fluorescence, Thermal Property and Quantum Chemistry of Triphenyltin 9-Anthroicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2688-2694. doi: 10.3969/j.issn.1001-4861.2013.00.373 shu

Synthesis, Characterization, Fluorescence, Thermal Property and Quantum Chemistry of Triphenyltin 9-Anthroicarboxylate

1.
1 Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;

Received Date: 13 February 2013
Available Online: 3 July 2013
Fund Project: 湖南省自然科学基金(No.11JJ3021)，湖南省科技计划(No.2013TZ2025)湖南省教育厅创新平台开放基金(No.10K010) (No.11JJ3021)，湖南省科技计划(No.2013TZ2025)湖南省教育厅创新平台开放基金(No.10K010)一般项目(No.12C0537)，湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)，衡阳市科技计划(No.2011KG56，2012KJ30)，衡阳师范学院青年骨干教师培养计划(2012) (No.12C0537)，湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)，衡阳市科技计划(No.2011KG56，2012KJ30)，衡阳师范学院青年骨干教师培养计划(2012)南岳学院大学生研究性学习与创新性实验(No.NYD201205)资助项目。 (No.NYD201205)

A new organotin complex [PH₃Sn(O₂CC₁₄H₉)(CH₃OH)]₂·CH₃OH has been synthesized by the reaction of triphenyltin hydroxide with 9-anthroic acid in methanol. It was characterized by IR, ¹H and ¹³C NMR, elemental analysis and X-ray crystal diffraction. Crystal structure shows a distorted trigonal bipyramidal configuration with five-coordination for the central tin atom. In the crystal, O-H…O hydrogen-bond interactions exist between the methanol O atom and the carbonyl O atom in an adjacent complex molecule, and between the neighboring methanol O atoms, resulting in the formation of a 1D S-shaped chain. Due to the C-H…π interactions between anthryl-H and anthracene ring, the obtained chain is further linked to form 1D ladderlike structure. Finally, a 2D network has been generated by the C-H…π interactions between methyl-H and benzene ring in the neighbouring 1D ladderlike chains. Fluorescence spectra of the complex reveals a strong emission band at 460 nm when excited with 360 nm radiation at room temperature. Thermogravimetric analysis shows that the complex is stable up to 240 ℃. The stability of the complex, the orbital energies and composition characteristics of some frontier molecular orbitals have been investigated at LANL2DZ level with G03W software. CCDC: 899826.
- organotin complex;crystal structure;fluorescence;thermal stability;quantum chemistry
1. [1]
  [1] Chandrasekhar V, Gopal K, Thilagar P. Acc. Chem. Res., 2007, 40 (6):420-434
2. [2]
  [2] TIAN Lai-Jin (田来进), YANG Hong-Jun (杨红军), ZHENG Xiao-Liang (郑晓亮), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009, 25 (7):1205-1211
3. [3]
  [3] Davies A G, Gielen M, Pannell K H, et al. Tin Chemistry. Chichester: John Wiley & Sons, 2008:431, 667
4. [4]
  [4] CAO Zuo-Ying (曹佐英), XU Hai-Feng (许海峰), TANG Rui-Ren (唐瑞仁), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2008, 24 (3):474-478
5. [5]
  [5] DU Zhi-Ping (杜治平), LIU Liang (刘亮), WANG Gong-Ying (王公应), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009, 25 (12):2225-2228
6. [6]
  [6] Suzuki T, Takakura I, Yoda M. Eur. Polym. J., 1971, 7 (8): 1105-1110
7. [7]
  [7] Davies A G. Organotin Chemistry. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA, 2004:383
8. [8]
  [8] TIAN Lai-Jin (田来进), SUN Yu-Xi (孙玉希), ZHENG Xiao-Liang (郑晓亮), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006, 22 (4):629-632
9. [9]
  [9] Kovala-Demertzi D, Dokorou V, Primikiri A, et al. J. Inorg. Biochem., 2009, 103 (5):738-744
10. [10]
  [10] Lecat J L, Devaud M. J. Organomet. Chem., 1983, 244 (3): 217-224
11. [11]
  [11] Kovala-Demertzi D. J. Organomet. Chem., 2006, 691 (8):1767-1774
12. [12]
  [12] WANG Zhi-Hong (王志宏), WANG He (王贺), GUO Yan-Zhao (郭彦召), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (9):1926-1934
13. [13]
  [13] YU Jiang-Xi (庾江喜), KUANG Dai-Zhi (邝代治), YIN Du-Lin (尹笃林), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (8):1507-1510
14. [14]
  [14] KUANG Dai-Zhi (邝代治), YU Jiang-Xi (庾江喜), YIN Du-Lin (尹笃林), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (12):2303-2306
15. [15]
  [15] Chandrasekhar V, Thilagar P, Steiner A, et al. Chem.-Eur. J., 2006, 12 (34):8847-8861
16. [16]
  [16] George M S. SHELXTL-97: Program for Crystal Structure Analysis. Göttingen: University of Göttingen, 1997.
17. [17]
  [17] KUANG Dai-Zhi (邝代治), CHEN Zhi-Min (陈志敏), ZHANG Fu-Xing (张复兴), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006, 22 (11):1947-1951
18. [18]
  [18] KE Yi-Kan (柯以侃), DONG Hui-Ru (董慧茹). Analysis Chemistry handbook, Vol.3 (分析化学手册:第三分册). Beijing: Chemical Industry Press, 1998:932, 935
19. [19]
  [19] XIE Qing-Lan (谢庆兰), XU Xiao-Hua (徐效华), ZHANG Dian-Kun (张殿坤), et al. Acta Chimica Sinica (Huaxue Xuebao), 1992, 50 (5):508-514
20. [20]
  [20] Geng W Q, Zhou H P, Cheng L H, et al. Polyhedron, 2012, 31 (1):738-747
21. [21]
  [21] Alcock N W, Timms R E. J. Chem. Soc. A, 1968:1873-1876
22. [22]
  [22] Bondi A. J. Phys. Chem., 1964, 68 (3):441-451 Table 1 Crystal data and structure refinement parameters of the complex Hydrogen atoms are omitted for clarity
1. [1]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Jia Zhou . Constructing Potential Energy Surface of Water Molecule by Quantum Chemistry and Machine Learning: Introduction to a Comprehensive Computational Chemistry Experiment. University Chemistry, 2024, 39(3): 351-358. doi: 10.3866/PKU.DXHX202309060
7. [7]
  Dongju Zhang , Rongxiu Zhu . Construction of Ideological and Political Education in Quantum Chemistry Course: Several Teaching Cases to Reveal the Universal Connection of Things. University Chemistry, 2024, 39(7): 272-277. doi: 10.3866/PKU.DXHX202311032
8. [8]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
12. [12]
  Guoxian Zhu , Jing Chen , Rongkai Pan . Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies. University Chemistry, 2024, 39(3): 376-383. doi: 10.3866/PKU.DXHX202305027
13. [13]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
14. [14]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
15. [15]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
18. [18]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
19. [19]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
20. [20]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(198)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142