Citation: YU Jiang-Xi, KUANG Dai-Zhi, FENG Yong-Lan, ZHANG Fu-Xing, WANG Jian-Qiu, JIANG Wu-Jiu, ZHU Xiao-Ming, PENG Yan, YANG Yi. Synthesis, Characterization, Fluorescence, Thermal Property and Quantum Chemistry of Triphenyltin 9-Anthroicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2688-2694. doi: 10.3969/j.issn.1001-4861.2013.00.373 shu

Synthesis, Characterization, Fluorescence, Thermal Property and Quantum Chemistry of Triphenyltin 9-Anthroicarboxylate

1.
1 Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;

Received Date: 13 February 2013
Available Online: 3 July 2013
Fund Project: 湖南省自然科学基金(No.11JJ3021)，湖南省科技计划(No.2013TZ2025)湖南省教育厅创新平台开放基金(No.10K010) (No.11JJ3021)，湖南省科技计划(No.2013TZ2025)湖南省教育厅创新平台开放基金(No.10K010)一般项目(No.12C0537)，湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)，衡阳市科技计划(No.2011KG56，2012KJ30)，衡阳师范学院青年骨干教师培养计划(2012) (No.12C0537)，湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)，衡阳市科技计划(No.2011KG56，2012KJ30)，衡阳师范学院青年骨干教师培养计划(2012)南岳学院大学生研究性学习与创新性实验(No.NYD201205)资助项目。 (No.NYD201205)

A new organotin complex [PH₃Sn(O₂CC₁₄H₉)(CH₃OH)]₂·CH₃OH has been synthesized by the reaction of triphenyltin hydroxide with 9-anthroic acid in methanol. It was characterized by IR, ¹H and ¹³C NMR, elemental analysis and X-ray crystal diffraction. Crystal structure shows a distorted trigonal bipyramidal configuration with five-coordination for the central tin atom. In the crystal, O-H…O hydrogen-bond interactions exist between the methanol O atom and the carbonyl O atom in an adjacent complex molecule, and between the neighboring methanol O atoms, resulting in the formation of a 1D S-shaped chain. Due to the C-H…π interactions between anthryl-H and anthracene ring, the obtained chain is further linked to form 1D ladderlike structure. Finally, a 2D network has been generated by the C-H…π interactions between methyl-H and benzene ring in the neighbouring 1D ladderlike chains. Fluorescence spectra of the complex reveals a strong emission band at 460 nm when excited with 360 nm radiation at room temperature. Thermogravimetric analysis shows that the complex is stable up to 240 ℃. The stability of the complex, the orbital energies and composition characteristics of some frontier molecular orbitals have been investigated at LANL2DZ level with G03W software. CCDC: 899826.
- organotin complex;crystal structure;fluorescence;thermal stability;quantum chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142