Citation: HAO Hong-Qing, CHEN Mu-Hua, LI Xin, PENG Meng-Xia. Structure and Fluorescence of Two Ag(Ⅰ) Complexes Based on 4-Biphenylacetate and 1, 3-Bis(4-pyridyl)propane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2480-2484. doi: 10.3969/j.issn.1001-4861.2013.00.370 shu

Structure and Fluorescence of Two Ag(Ⅰ) Complexes Based on 4-Biphenylacetate and 1, 3-Bis(4-pyridyl)propane

1.
School of Chemistry and Environment, Jiaying University, Meizhou, Guangdong 514015, China

Received Date: 16 April 2013
Available Online: 7 August 2013
Fund Project: 国家自然科学基金(No.21101077) (No.21101077)广东自然科学基金(No.S2011040001705)资助项目。 (No.S2011040001705)

Two sandwich-like coordination polymers based on Ag(Ⅰ) and mixed flexible ligands, {[Ag₂(bpa)₂(bpp)₂]·2H₂O}_n (1) and {[Ag(bpa)(bpp)]·2H₂O}_n (2) (bpa^-=4-biphenylacetate, bpp=1,3-bis(4-pyridyl)propane), have been synthesized by solution reactions of Hbpa, bpp and [Ag(NH₃)](OH) with the same ratio under different experimental conditions. They were characterized by single-crystal X-ray diffraction, EA, IRand XRD. Complex 1 is a two-dimensional network based on T-shaped coordination Ag(Ⅰ) ions and Ag…Ag interactions. In 2, the distorted tetrahedral coordination Ag(Ⅰ) ions are further organized by π…π stacking interactions into another two-dimensional network. 1 and 2 exhibit different and intense emissions in the visible region. CCDC: 922168,1;922167, 2.
- flexible ligand;sandwich-like;supramolecular interaction;luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142