Citation: FENG Xue-Jiao, YANG Jun, NULI Yan-Na, WANG Jiu-Lin. Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl₄[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2289-2296. doi: 10.3969/j.issn.1001-4861.2013.00.367 shu

Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl₄

1.
School of Chemistry &Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China

Received Date: 22 April 2013
Available Online: 17 June 2013

Porous silicon/carbon composite was prepared via a mechanochemical reaction between Li₁₃Si₄ and SiCl₄ under ball milling. Specific surface area of silicon/carbon composite can be adjusted by controlling the particle size distribution of Li₁₃Si₄. Effects of the carbon weight, specific surface area and active mass loading on the electrochemical performance were investigated. The results indicated that the composite material which combined specific surface area of 100.9 m²·g^-1 and chemical vapor deposition method (CVD) carbon coating with 25.3wt% (ca.6 nm in thickness), exhibited a considerably high reversible capacity of 1900 mAh·g^-1 and an excellent cycling stability with only 7.6% capacity decay after 50 cycles at a current density of 300 mA·g^-1.
- porous silicon;specific surface area;mechanochemical reaction;chemical vapor deposition method;lithium ion battery
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl4

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl₄