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Citation: CHEN Wen-Tong. Fluorescent, Theoretical and Structural Investigations of a 2, 2’-Biimidazole Cadmium Compound[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2455-2459. doi: 10.3969/j.issn.1001-4861.2013.00.364 shu

Fluorescent, Theoretical and Structural Investigations of a 2, 2’-Biimidazole Cadmium Compound

CHEN Wen-Tong

1.
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an, Jiangxi 343009, China

Received Date: 29 November 2012
Available Online: 28 April 2013
Fund Project: 科技部科技支撑计划(No.2012BAC11B01)资助项目 (No.2012BAC11B01)

Anovel cadmium-biimidazole compound [Cd(BIm)₂](ClO₄)(OH)·2H₂O (1) (BIm=2,2'-biimidazole) has been synthesized via a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 features an isolated (0D) structure with the cadmium ions coordinating to four nitrogen atoms to give a distorted tetrahedron. Photoluminescent investigation shows that compound 1 exhibits an emission in the blue region. Theoretical study reveals that the emission is ascribed to ligand-to-metal charge transfer (LMCT). The spectral data of FT-IR are also reported. CCDC: 895386.
- biimidazole;crystal;hydrothermal;photoluminescence
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