Citation: XU Fu-Qiu, CHEN Hua-Jun, DING Wu-Xiu. Preparation and Antibacterial Property of Ag-Doped Hydroxyapatite Antibacterial Powders and Antibacterial Ceramic[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2582-2586. doi: 10.3969/j.issn.1001-4861.2013.00.362 shu

Preparation and Antibacterial Property of Ag-Doped Hydroxyapatite Antibacterial Powders and Antibacterial Ceramic

1.
Department of Environment and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China

Received Date: 4 January 2013
Available Online: 26 May 2013
Fund Project: 国家自然科学基金(No.51279073) (No.51279073)河南省科技攻关课题(No.132102310367)资助项目。 (No.132102310367)

Silver doped hydroxyapatite antimicrobial powders were synthesized by one-step reaction, then it was used for preparing antibacterial ceramic. The experimental results show that there was a significant linear correlation between silver content of HA and quantity of silver nitrate at hydrothermal condition. The XRD patterns and TEM photos indicate that HA and Ag-HA have the same crystal structure, and Ca²⁺ in HA crystals is displaced by Ag⁺ and Ag_xCa_1-x(PO₄)₆(OH)₂ was produced at hydrothermal condition. The length of Ag-HA antimicrobial powders increases with the increase of content of Ag⁺ in Ag-HA. Ag-HA antimicrobial powders went from sticks to whisker when the contents of Ag⁺ in Ag-HA exceeds 1.5%. 4.50% Ag-HA was selected as antimicrobial powders, an antibacterial rate of antibacterial ceramic is above 99.9%. and at this point, the mass fraction of Ag₃PO₄ in antimicrobial tglazes is 0.56%, which was far below 2wt%~4wt% of Ag₃PO₄ in antimicrobial tglazes of ongoing research. This technology can not only reduce the cost of producing antibacterial ceramic, but also meet JC/T 897-2002 demands for antibacterial properties of antibacterial ceramic.
- Ag;hydroxyapatite(HA);hydro-thermal method;antibacterial property;ceramic
1. [1]
  [1] Steens W, Schneeberger A G, Skripitz R, et al. Arch Orthop. Trauma Surg., 2010, 130:921-926
2. [2]
  [2] Iwai T, Harada Y, Imura K, et al. J. Bone Miner Metab., 2007, 25:392-399
3. [3]
  [3] Nath S, Kalmodia S, Basu B. J. Mater. Sci: Mater. Med., 2010, 21:1273-1287
4. [4]
  [4] Zhang Y, Yin Q S, Zhang Y, et al. J. Materi. Sci.: Mater. Med., 2010, 21 (8):2453-2462
5. [5]
  [5] WANG Hong (王虹), WANG Peng (王鹏). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009, 25 (11):1928-1934
6. [6]
  [6] LIAO Ma-Hua (廖马花), YAN Wen-Yan (颜文艳), CAI Xiang (蔡祥), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (5):977-983
7. [7]
  [7] Silver S, Phung L T, Silver G. J. Ind. Microbiol. Biotechnol., 2006, 33:627-634
8. [8]
  [8] Kim T N, Feng Q L, Kim J O, et al. J. Mater. Sci.: Mater. Med., 1998, 9:129-134
9. [9]
  [9] ÜlkÜ seven B, Tavman A, ÖtÜ k G, et al. Folia. Microbiol., 2002, 47 (5):481-487
10. [10]
  [10] Matsumoto N, Sato K, Yoshida K, et al. Acta Biomater., 2009, 5 (8):3157-3164
11. [11]
  [11] Hwang K S, Hwangbo S, Kim J T. J. Nanopart. Res., 2008, 10:1337-1341
12. [12]
  [12] Tuan W H, Chen W R. J. Mater. Sci. Lett., 1994, 13:658-659
13. [13]
  [13] XIAO Xiu-Feng (肖秀峰), LIU Rong-Fang (刘榕芳), ZHENG Yang-Zeng (郑炀曾). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2005, 21 (7):965-970
14. [14]
  [14] ZHOU Song (周松), LI Yu-Bao (李玉宝), WANG Yan-Ying (王妍媖), et al. Acta Materiae Compositae Sinica (Fuhe Cailiao Xuebao), 2011, 28 (6):86-91
15. [15]
  [15] GUO Jin-Wu (郭进武), ZHANG Jun (张军), PENG Wei-Tao (彭伟涛,), et al. Acta Materiae Compositae Sinica (), 2011, 28 (2):170-173
16. [16]
  [16] XIAO Yong (肖勇), GAO Chuang (高闯), SHI Ya-Yun (施亚运), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (6):1222-1228
17. [17]
  [17] HUANG Zai-Yin (黄在银), QU Song-Sheng (屈松生), ZHAO Qun-Jin (赵群金), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 1998, 14 (4):490-492
18. [18]
  [18] CHEN Yu (陈于), XU Can (徐灿), SU Jia-Can (苏佳灿), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (4): 625-630
19. [19]
  [19] LU Guo-Yu (吕国玉), LI Yu-Bao (李玉宝), WEI Jie (魏杰), et al. J. Funct. Mater. (Gongneng Cailao Xuebao), 2005, 36: 888-891
20. [20]
  [20] CHEN Hua-Jun (陈华军), XU Fu-Qiu (徐伏秋), XUE Dong (薛冬), et al. Acta Chim. Sin. (Huaxue Xuebao), 2012, 70 (12):1362-1366
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沈阳化工大学材料科学与工程学院沈阳 110142