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Citation: WANG Juan-Juan, ZHANG Li, XU Guan-Cheng, JIA Dian-Zeng. Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M4[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2609-2614. doi: 10.3969/j.issn.1001-4861.2013.00.360 shu

Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M4[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property

  • 1.

    Key Laboratory of Material and Technology for Clean Energy, Ministry of Education, Key Laboratory of AdvancedFunctional Materials, Autonomous Region, Institute of Applied Chemistry Xinjiang University, Urumqi 830046, China

  • Received Date: 16 February 2013
    Available Online: 7 June 2013

    Fund Project: 新疆自治区自然科学基金面上项目(No.2012211A009)资助项目。 (No.2012211A009)

  • A novel tetranuclear M4[2×2] square grid complex [ZN4(HL)4](ClO4)4·2MeCN·2MeOH(H2L=1,5-bis(1-(pyridine-2-yl)ethylidene)carbonhydrazide) was constructed via self-assembly using Schiff base ligand based on carbohydrazone derivative. The complex was characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and single crystal X-ray diffraction. Single crystal structure analysis showed that all mental atoms have N4O2 distorted octahedral coordination spheres and four ligands are monodeprotonated with four enolyl oxygen atoms direct bridging the Zn ions to form a tetranuclear [2×2] square grid complex. Furthermore, the fluorescent spectra analysis indicated the tetranuclear Zn(Ⅱ)4 complex exhibits intense fluorescence emission band at around 530 nm in the solid state. CCDC: 922042.
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