Citation: WANG Juan-Juan, ZHANG Li, XU Guan-Cheng, JIA Dian-Zeng. Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M₄[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2609-2614. doi: 10.3969/j.issn.1001-4861.2013.00.360 shu

Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M₄[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property

1.
Key Laboratory of Material and Technology for Clean Energy, Ministry of Education, Key Laboratory of AdvancedFunctional Materials, Autonomous Region, Institute of Applied Chemistry Xinjiang University, Urumqi 830046, China

Received Date: 16 February 2013
Available Online: 7 June 2013
Fund Project: 新疆自治区自然科学基金面上项目(No.2012211A009)资助项目。 (No.2012211A009)

A novel tetranuclear M₄[2×2] square grid complex [ZN₄(HL)₄](ClO₄)₄·2MeCN·2MeOH(H₂L=1,5-bis(1-(pyridine-2-yl)ethylidene)carbonhydrazide) was constructed via self-assembly using Schiff base ligand based on carbohydrazone derivative. The complex was characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and single crystal X-ray diffraction. Single crystal structure analysis showed that all mental atoms have N₄O₂ distorted octahedral coordination spheres and four ligands are monodeprotonated with four enolyl oxygen atoms direct bridging the Zn ions to form a tetranuclear [2×2] square grid complex. Furthermore, the fluorescent spectra analysis indicated the tetranuclear Zn(Ⅱ)₄ complex exhibits intense fluorescence emission band at around 530 nm in the solid state. CCDC: 922042.
- zinc(Ⅱ) complex;tetranuclear complex;crystal structure;fluorescence property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M4[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property

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通讯作者: 陈斌, bchen63@163.com

Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M₄[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property