Advanced Search

Citation: TANG Si-Ping, XU Zhi-Feng, FENG Yong-Lan, WANG Hai-Yang. Synthesis, Electrochemical, Magnetic and Fluorescent Properties of a Zinc(Ⅱ) Complex Zn(2-PMBBA)2(Phen)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2683-2687. doi: 10.3969/j.issn.1001-4861.2013.00.358 shu

Synthesis, Electrochemical, Magnetic and Fluorescent Properties of a Zinc(Ⅱ) Complex Zn(2-PMBBA)2(Phen)

  • 1.

    Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

  • Received Date: 5 March 2013
    Available Online: 11 June 2013

    Fund Project: 国家自然科学基金(No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)，湖南省重点学科基金资助项目。 (No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)

  • A new zinc(Ⅱ) complex Zn (2-PMBBA)2(Phen) with 2-(p-methylbenzoyl) benzoic acid (2-PMBBA) and 1, 10-phenanthroline (Phen) as ligands has been synthesized. Crystal data for this complex are as follows: orthorhombic, space group Pccn, a=1.371 6(4) nm, b=1.336 8(4) nm, c=1.928 7(5) nm, V=3.536 4(17) nm3, Dc=1.360 g·cm-3, Z=4, μ(Mo Kα)=0.746 mm-1, F(000)=1 496, final discrepancy factors R1=0.0358, wR2=0.086 1. In the title complex, it is less common that the central Zn(Ⅱ) ion is in a four-coordinated distorted tetrahedron coordination environment. The electrochemical, magnetic and fluorescent properties of the title complex were investigated. The results show that its electron transfer is irreversible in the cyclic voltammetric reaction corresponding to Zn(Ⅱ)/Zn(0), and it exhibits diamagnetic property in the temperature range of 300~7 K. In addition, it can give off fluorescent emission bands at around 450 and 472 nm, respectively, with the excitation wavelength of 224 nm. CCDC: 926215.
  • 加载中
    1. [1]

      [1] Gushwa A F, Belabassi Y, Montchamp J L, et al. J. Chem. Cryst., 2009, 39:337-347

    2. [2]

      [2] Assey G E, Yisgedu T, Gultneh Y, et al. Acta Crystallog., Sect. E, 2009, 65:1007-1008

    3. [3]

      [3] ZHANG Yan-Ping (张艳萍), WANG Li-Li (王莉丽), LIU Lian-Li (刘连利), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013, 29 (2):350-354

    4. [4]

      [4] KANG Wei (康伟), DENG Zhao-Peng (邓兆鹏), GAO Shan (高 山). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (4):655-658

    5. [5]

      [5] Zhao Y J, Liu R W, Li X H. Acta Crystallogr., Sect. E, 2005, 61:535-537

    6. [6]

      [6] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009, 362:1907-1912

    7. [7]

      [7] Chandrasekhar V, Thilagar P, Steiner A, et al. Chem.-Eur. J., 2006, 12:8847-8861

    8. [8]

      [8] Srinivasan B R, Sawant J V, Nather C, et al. J. Chem. Sci. (Bangalore, India), 2007, 119:243-252

    9. [9]

      [9] GAO Hong-Ling (高洪苓), HU Cong-Cong (胡丛丛), ZHANG Hong (张虹), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):632-636

    10. [10]

      [10] WANG Peng (王鹏), LI Ying (李莹), YANG Wen-Bin (杨文 斌), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (11):2301-2305

    11. [11]

      [11] Wang R H, Hong M C, Liang Y C, et al. Acta Crystallogr., Sect. E, 2001, 57:277-279

    12. [12]

      [12] Li X J, Cao R, Sun D F, et al. Cryst. Growth Des., 2004, 4: 775-780

    13. [13]

      [13] Yang E, Song X C, Wang L H, et al. Acta Crystallogr., Sect. C, 2007, 63:481-483

    14. [14]

      [14] WANG Qian-Qian (王倩倩), LIU Chun-Bo (刘春波), LI Xiu-Ying (李秀颖), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):619-625

    15. [15]

      [15] TAO Zhao-Lin (陶兆林), CUI Jie-Hu (崔节虎), QIN Lin (覃 玲), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (12):2633-2637

    16. [16]

      [16] Kang W L, Wu X Y, Huang J B. J. Organomet. Chem., 2009, 694:2402-2408

    17. [17]

      [17] LI Wei (李薇), LI Chang-Hong (李昶红), YANG Ying-Qun (杨 颖群), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (1):166-170

    18. [18]

      [18] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen, Germany, 2002. 19] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Gottingen, Germany, 1997.

    19. [19]

      [20] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.

    20. [20]

      [21] GU Chang-Sheng (谷长生), GAO Shan (高山), ZHAO Jing-Gui (赵经贵), et al. Chinese J. Struct. Chem. (Jiegou Huaxue), 2004, 23 (9):1073-1076

  • 加载中
    1. [1]

      Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe3+ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402

    2. [2]

      Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395

    3. [3]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    4. [4]

      Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009

    5. [5]

      Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    6. [6]

      Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278

    7. [7]

      Longfei MA , Fang SI , Congjie PAN , Xinhua WANG . Synthesis and crystal structure of extended tetrathiafulvalene derivatives and cupric bromide charge transfer complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1229-1236. doi: 10.11862/CJIC.20250355

    8. [8]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    9. [9]

      Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012

    10. [10]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    11. [11]

      Yan Liu ,  Yuexiang Zhu ,  Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

    12. [12]

      Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two SmⅢ4 complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

    13. [13]

      Chengyan XU , Jiangnan YU , Yu LI , Xizhen PAN , Yinlin HOU , Wenmin WANG . Synthesis, structure, and bioactivity of a Ho4 complex bridged by azide group. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1453-1462. doi: 10.11862/CJIC.20260033

    14. [14]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    15. [15]

      Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141

    16. [16]

      Wenjuan SHI , Yuxuan LEI , Lei HOU , Yaoyu WANG . Synthesis, structure, and luminescence properties of trinucluear Cu(Ⅰ)-pyrazole complexes containing different substituent groups. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 543-550. doi: 10.11862/CJIC.20250270

    17. [17]

      Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    18. [18]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    19. [19]

      Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212

    20. [20]

      Xuhu GUO , Chuntao ZHANG , Jinshu LI , Yuanyuan TAN , Qaiowen CHANG , Juan YU . Structure and catalytic performance of [Pd(1, 5-cyclooctadiene)X2] (X=Cl, Br) modulated by organophosphine ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1247-1260. doi: 10.11862/CJIC.20250299

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(1286)
  • HTML views(191)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return