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Citation: TANG Si-Ping, XU Zhi-Feng, FENG Yong-Lan, WANG Hai-Yang. Synthesis, Electrochemical, Magnetic and Fluorescent Properties of a Zinc(Ⅱ) Complex Zn(2-PMBBA)2(Phen)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2683-2687. doi: 10.3969/j.issn.1001-4861.2013.00.358 shu

Synthesis, Electrochemical, Magnetic and Fluorescent Properties of a Zinc(Ⅱ) Complex Zn(2-PMBBA)2(Phen)

  • 1.

    Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

  • Received Date: 5 March 2013
    Available Online: 11 June 2013

    Fund Project: 国家自然科学基金(No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)，湖南省重点学科基金资助项目。 (No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)

  • A new zinc(Ⅱ) complex Zn (2-PMBBA)2(Phen) with 2-(p-methylbenzoyl) benzoic acid (2-PMBBA) and 1, 10-phenanthroline (Phen) as ligands has been synthesized. Crystal data for this complex are as follows: orthorhombic, space group Pccn, a=1.371 6(4) nm, b=1.336 8(4) nm, c=1.928 7(5) nm, V=3.536 4(17) nm3, Dc=1.360 g·cm-3, Z=4, μ(Mo Kα)=0.746 mm-1, F(000)=1 496, final discrepancy factors R1=0.0358, wR2=0.086 1. In the title complex, it is less common that the central Zn(Ⅱ) ion is in a four-coordinated distorted tetrahedron coordination environment. The electrochemical, magnetic and fluorescent properties of the title complex were investigated. The results show that its electron transfer is irreversible in the cyclic voltammetric reaction corresponding to Zn(Ⅱ)/Zn(0), and it exhibits diamagnetic property in the temperature range of 300~7 K. In addition, it can give off fluorescent emission bands at around 450 and 472 nm, respectively, with the excitation wavelength of 224 nm. CCDC: 926215.
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