Citation: TANG Si-Ping, ZHANG Shao-Hua, YANG Ying-Qun. Synthesis, Electrochemical, Fluorescent and Magnetic Properties of a Copper(Ⅱ) Complex with 2-Benzoylbenzoic Acid as a Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2465-2469. doi: 10.3969/j.issn.1001-4861.2013.00.356 shu

Synthesis, Electrochemical, Fluorescent and Magnetic Properties of a Copper(Ⅱ) Complex with 2-Benzoylbenzoic Acid as a Ligand

1.
1 Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China;

Received Date: 20 March 2013
Available Online: 11 June 2013
Fund Project: 国家自然科学基金(No.21102040) (No.21102040)湖南省自然科学基金(No.12JJ6013,11JJ9005,13JJ3112) (No.12JJ6013,11JJ9005,13JJ3112)湖南省科学技术厅科技计划项目(No.2012GK3030,2012FJ3020) (No.2012GK3030,2012FJ3020)湖南省教育厅科学研究项目(No.11C0186) (No.11C0186)衡阳市科技计划项目(NO.2011kG28) (NO.2011kG28)

Anew copper(Ⅱ) complex {[Cu₂(Phen)₄(NO₃)][Cu(Phen)₂(L)]₂(L)₂(NO₃)₃}·2H₂O (1) with 2-benzoylbenzoic acid (HL) and 1,10-phenanthroline (Phen) as ligands has been synthesized. Crystal data for the complex are as follows: triclinic, space group P1, a=1.13857(5) nm, b=1.19349(7) nm, c=2.61531(13) nm, α=89.4280(10)°, β=82.753(2)°, γ=74.5370(10)°, V=3.3968(3) nm³, D_c=1.408 g·cm^-3, Z=1, μ(Mo Kα)=0.700 mm^-1, F(000)=1480, final discrepancy factors R₁0.0571, wR₂=0.1334. In 1, there are two mononuclear cations [Cu(Phen)₂(L)]⁺ and one dinuclear cation [Cu₂(Phen)₄(NO₃)]³⁺, and the four central Cu(Ⅱ) ions are all penta-coordinated. The electrochemical, fluorescent and magnetic properties of 1 were investigated. The results show that the electron transfer in the electrode reaction of 1 is quasi reversible, and the electrode reaction corresponds to Cu(Ⅱ)/Cu(Ⅰ). When the exciting radiation set at 488 nm, 1 can give off strong fluorescence band at around 494 nm. In addition, 1 displays diamagnetic property in temperatures range of 300~52 K. CCDC: 929034.
- copper(Ⅱ) complex;2-benzoylbenzoic acid;crystal structure;electrochemical, fluorescent and magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142