Citation: MA De-Yun, QIN Liang, GUO Hai-Fu, LIU Huang, XU Jun. One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

MA De-Yun ¹ ,
QIN Liang ¹ ,
GUO Hai-Fu ¹ ,
LIU Huang ¹ ,
XU Jun ²

1.
1 School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;

Received Date: 13 April 2013
Available Online: 9 June 2013
Fund Project: 广东省教育厅育苗工程(2012LYM_0134) (2012LYM_0134)国家自然科学基金(No.81202461) (No.81202461)中国博士后基金(2013M531906)资助项目 (2013M531906)

A new 1Dcadmium(Ⅱ) coordination polymer, {[Cd(4',4-Hhbc)₂(bpp)₂]}_n (1, 4',4-Hhbc=4'-Hydroxyl-biphenyl-4-carboxylate, bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectroscopy, TGA, powder X-ray diffraction, UV-Vis and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure. Solid-state 1 emits the intensely indigotin photoluminescence with fluorescence lifetime of 3.2 ns (440 nm) at room temperature. CCDC: 854723.
- cadmium(Ⅱ) coordination polymer;hydrothermal synthesis;crystal structure;luminescence
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