Citation: ZHANG Xin-Cun, YUE Fan, HUANG Yan, CHENG Xiang, WEN Hong-Mei, HU Di, WANG Ji-De. Comparative Study for Oxygenation Properties of Cobalt Complexes with Hsitidine, Histidinol and Histamine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2387-2393. doi: 10.3969/j.issn.1001-4861.2013.00.353 shu

Comparative Study for Oxygenation Properties of Cobalt Complexes with Hsitidine, Histidinol and Histamine

1.
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China

Received Date: 19 December 2012
Available Online: 11 June 2013
Fund Project: 国家自然科学基金(No.20961010,21162027,21261022)资助项目。 (No.20961010,21162027,21261022)

Oxygenation of three complexes His-Co, Hio-Co and Hit-Co were determined by UV-Vis spectrophotometry and oxygen electrode, respectively. The curve of absorption change with pHshowed that the oxygenation reactions took place after pH6.0 for all three complexes. His-Co has two oxygenated species in pH6.0~10.0, whereas, Hio-Co and Hit-Co only formed one oxygenated species. The results obtained from the equimolar ratio method showed the molar ration for Co:His and Co:Hio is 1:2,whereas Co:Hit is 1:3. Oxygenation properties and anti-aging processes of three complexes were determined by UV-V is spectrophotometry at λ=384 nm in room temperature in pH 7.0, respectively. The results revealed that all three complexes can uptake dioxygen reversibly whereas there are obvious differences in their oxygenations, especially in the deoxygenation rate. His-Co kept 5% oxygenation capacity after 560 cycles/110 h continuous oxygenation, while Hio-Co and Hit-Co sustained 59 cycles/54 h and 5 cycles /10.2 h, respectively. The order of anti-aging rate of the complexes is His-Co>>Hio-Co>Hit-Co. The results suggested that the uptaking dioxygen reversibility of the complex with a ligand of three coordinating atoms is better than the complex with a ligand of two coordinating atoms, and the uptaking dioxygen reversibility of the aminoacid complex is better than that of alkamine complex.
- Co(Ⅱ) complex;oxygenated complex;UV-Vis spectrum;hsitidine;histidinol
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沈阳化工大学材料科学与工程学院沈阳 110142