Citation: YAN Li, WANG Mi-Jia. Synthesis, Crystal Structures and Fluorescence of Two Zn(Ⅱ) Complexes with Schiff Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2370-2374. doi: 10.3969/j.issn.1001-4861.2013.00.351 shu

Synthesis, Crystal Structures and Fluorescence of Two Zn(Ⅱ) Complexes with Schiff Base Ligands

YAN Li ,
WANG Mi-Jia

1.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Received Date: 20 January 2013
Available Online: 6 July 2013
Fund Project: 吉林省科技发展计划项目(No.20130522071JH)资助项目。 (No.20130522071JH)

We synthesized two novel Schiff-Base ligands by modificating the aromatic aldehyde: H₂L¹=N,N'-bis(2-oxy-acetate-3-methoxyl)benzylpropylene diamine, H₂L²=N,N'-bis(2-oxy-acetate-3-methoxyl)benzylpropylene (1,3-propane)diamine. [Zn(L¹)]·7H₂O (1) and [Zn(L²)]·7H₂O (2) complexes were prepared by the reaction between H₂L¹, H₂L² and zinc salts in the solvents of water. The two complexes were structurally characterized by elemental analysis, IR, HNMR and single-crystal X-ray diffraction. The X-ray diffraction results suggest that both the two complexes contain lattice water molecules. The complex 1 exhibits distorted tri-prism geometry and the complex 2 exhibits distorted octahedron geometry. There are lattice water molecules in the complex 1 and 2. In this paper, we research the solid luminescence of these two complexes. The results suggest that they have excellent photoluminescence and will be useful in the optical material. CCDC: 783660: 1;783330: 2.
- Schiff base;zinc complex;crystal structure;photoluminescent property
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