Citation:
CHEN Shun-Yu, YANG E, LIU Zi-Sheng. Synthesis, Crystal Structure and Luminescent Property of a Cd(Ⅱ) Coordination Polymer Constructed by 2-Amino-1, 4-benzenedicarboxylate and 2-Imidazolidinone[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(11): 2485-2490.
doi:
10.3969/j.issn.1001-4861.2013.00.350
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Anew coordination polymer, namely [Cd(NH2bdc)(e-urea)]n (1) (H2NH2bdc=2-amino-1,4-benzenedicar-boxylic acid, e-urea=2-imidazolidinone) has been urothermally synthesized by using urea derivative 2-imidazoli-dinone as solvent and its structure and fluorescence property have also been investigated. The crystallography analysis reveals that the centric Cd(Ⅱ) ion is seven coordinated by carboxylate oxygen atoms from NH2bdc ligands and oxygen atoms of e-urea molecules forming a distorted pentagonal-bipyramidal coordination geometry. The adjacent Cd(Ⅱ) centers are bridged by oxygen atoms of e-urea molecules and carboxylate groups of NH2bdc ligands forming an infinite 1Dchain. Thus 1Dchains are further connected together by NH2bdc ligands into a 3D coordination framework with 1D tunnels. Luminescent study shows that complex 1 displays a strong blue emission at room temperature. CCDC: 902023.
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