Citation: CHEN Shun-Yu, YANG E, LIU Zi-Sheng. Synthesis, Crystal Structure and Luminescent Property of a Cd(Ⅱ) Coordination Polymer Constructed by 2-Amino-1, 4-benzenedicarboxylate and 2-Imidazolidinone[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2485-2490. doi: 10.3969/j.issn.1001-4861.2013.00.350 shu

Synthesis, Crystal Structure and Luminescent Property of a Cd(Ⅱ) Coordination Polymer Constructed by 2-Amino-1, 4-benzenedicarboxylate and 2-Imidazolidinone

  • Received Date: 6 March 2013
    Available Online: 13 June 2013

    Fund Project: 国家自然科学基金(No.60976019) (No.60976019)高等学校博士学科点专项科研基金(No.20093223110002) (No.20093223110002)福建师范大学优秀青年学者培养基金(No.FJSDJK2012063) (No.FJSDJK2012063)福建省教委基金(No.JB11002,JB10007)资助项目。 (No.JB11002,JB10007)

  • Anew coordination polymer, namely [Cd(NH2bdc)(e-urea)]n (1) (H2NH2bdc=2-amino-1,4-benzenedicar-boxylic acid, e-urea=2-imidazolidinone) has been urothermally synthesized by using urea derivative 2-imidazoli-dinone as solvent and its structure and fluorescence property have also been investigated. The crystallography analysis reveals that the centric Cd(Ⅱ) ion is seven coordinated by carboxylate oxygen atoms from NH2bdc ligands and oxygen atoms of e-urea molecules forming a distorted pentagonal-bipyramidal coordination geometry. The adjacent Cd(Ⅱ) centers are bridged by oxygen atoms of e-urea molecules and carboxylate groups of NH2bdc ligands forming an infinite 1Dchain. Thus 1Dchains are further connected together by NH2bdc ligands into a 3D coordination framework with 1D tunnels. Luminescent study shows that complex 1 displays a strong blue emission at room temperature. CCDC: 902023.
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    1. [1]

      [1] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112:869-932

    2. [2]

      [2] Eddaoud M, Kim J, Rosi N, et al. Science, 2002,295:469-472

    3. [3]

      [3] Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112:1001-1033

    4. [4]

      [4] Li Y M, Wu B L, Yuan D Q. Inorg. Chem. Commun., 2012, 22:120-122

    5. [5]

      [5] FU Feng(付峰), GUO Hai-Kang(郭海康), TANG Long(唐龙), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 28(12):2638-2642

    6. [6]

      [6] Ahmad M, Sharma M K, Das R, et al. Cryst. Growth Des., 2012,12:1571-1578

    7. [7]

      [7] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982-986

    8. [8]

      [8] Lin J B, Zhang J P, Chen X M. J. Am. Chem. Soc., 2010, 132:6654-6656

    9. [9]

      [9] Zhuang G L, Chen W X, Zheng J, et al. Inorg. Chem. Commun., 2012,22:18-21

    10. [10]

      [10]Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012,112: 1126-1162

    11. [11]

      [11]Xue M, Zhu G S, Zhang Y J, et al. Cryst. Growth Des., 2008,8:427-434

    12. [12]

      [12]Chen S C, Yu R M, Zhao Z G, et al. Cryst. Growth Des., 2010,10:1155-1160

    13. [13]

      [13]GAO Zhu-Qing(高竹青), LI Hong-Jin(李红晋), GU Jin-Zhong(顾金忠). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(12):2655-2659

    14. [14]

      [14]Wang L Y, Yang Y, Liu K, et al. Cryst. Growth Des., 2008, 8:3902-3904

    15. [15]

      [15]Perry J J, Perman J A, Zaworotko M J. Chem. Soc. Rev., 2009,38:1400-1417

    16. [16]

      [16]Sun Y G, Jiang B, Cui T F, et al. Dalton Trans., 2011,40: 11581-11590

    17. [17]

      [17]Ji W J, Zhai Q G, Hu M C, et al. Inorg. Chem. Commun., 2008,11:1455-1458

    18. [18]

      [18]Yang E, Liu Z S, Lin S, et al. Inorg. Chem. Commun., 2011, 14:1588-1590

    19. [19]

      [19]Li X M, Wang Q W, Liu B, et al. Chinese J. Struct. Chem., 2012,31:550-554

    20. [20]

      [20]Zhang J, Chen S M, Wu T, et al. Angew. Chem. Int. Ed., 2010,49:8876-8879

    21. [21]

      [21]Yang H, Li T H, Kang Y, et al. Inorg. Chem. Commun., 2011,14:1695-1697

    22. [22]

      [22]Kang Y, Chen S M, Wang F, et al. Chem. Commun., 2011, 47:4950-4952

    23. [23]

      [23]Hao X R, Wang X L, Su Z M, et al. Dalton Trans., 2009,40: 8562-8566

    24. [24]

      [24]Wang X F, Zhang Y B, Cheng X N, et al. CrystEngComm, 2008,10(6):753-758

    25. [25]

      [25]Zhang K L, Gao H Y, Qiao N, et al. Inorg. Chim. Acta, 2008,361(1):153-160

    26. [26]

      [26]Sheldrick G M. SHELXTL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

  • 加载中
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