Citation: ZHANG Yong, HU Jia-Wei, ZHOU Xia, CHEN Shi-Ming, MA Zhi-Gang, CHEN Xue-Mei. Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2491-2496. doi: 10.3969/j.issn.1001-4861.2013.00.348 shu

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane

1.
1 School of Chemical and Materials Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China;

Received Date: 20 February 2013
Available Online: 3 May 2013
Fund Project: 国家自然科学基金(No.51173060)资助项目。 (No.51173060)

The title complex [Ni(DTPB)H₂Cl]Cl(BF4)₂·4H₂O (DTPB＝1, 1, 4, 7, 7-pentakis(1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane) has been synthesized and structurally characterized, and its superoxide dismutase (SOD) catalytic activity was investigated by UVspectra. The results showed that the title complex exhibited distorted octahedron geometry, it can inhibit pyrogallol oxidation, IC₅₀ of the complex was 29.8 mg·L^-1, and its SOD activity was affected by reaction temperatures and pH values. CCDC: 606551.
- nickel(Ⅱ) complex;benzimidazole;crystal structure;SOD activity
1. [1]
  [1] Youn H D, Kim E J, Roe J H, et al. Biochem. J., 1996,318: 889-896
2. [2]
  [2] Youn H D, Youn H, Lee J W, et al. Arch. Biochem. Biophys., 1996,334:341-348
3. [3]
  [3] Szilagyi R K, Bryngelson P A, Maroney M J, et al. J. Am. Chem. Soc., 2004,126:3018-3019
4. [4]
  [4] Fiedler A T, Bryngelson P A, Maroney M J, et al. J. Am. Chem. Soc., 2005,127:5449-5462
5. [5]
  [5] Pap J S, Kripli B, Váradi T, et al. J. Inorg. Biochem., 2011,105:911-918
6. [6]
  [6] Ramadan A E M. J. Mol. Struct., 2012,1015:56-66
7. [7]
  [7] Nakane D, Kuwasako S, Tsuge M, et al. Chem. Commun., 2010,46:2142-2144
8. [8]
  [8] Main F. Coord. Chem. Rev., 1992,120:325-359
9. [9]
  [9] Zhou X H, Ma H F, Wu H L. Chin. J. Synth. Chem., 2011, 19:473-475
10. [10]
  [10]Pap J S, Kripli B, Bányai V, et al. Inorg. Chim. Acta, 2011, 376:158-169
11. [11]
  [11]Timári S, Cerea R, Várnagy K. J. Inorg. Biochem., 2011, 105:1009-1017
12. [12]
  [12]Agotegaray M A, Dennehy M, Boeris M A, et al. Polyhedron, 2012,34:74-83
13. [13]
  [13]Meng X G, Liu L, Zhou C S, et al. Inorg. Chem., 2008,47: 6572-6574
14. [14]
  [14]Spek A L. Acta Cryst. A, 1990,46:c34
15. [15]
  [15]Qin S D, Feng S S, Zhang H M, et al. Acta Chim. Sinica, 2005,63:1155-1160
16. [16]
  [16]Birker P J M W L, Schierbeek A J, Verschoor G C, et al. J. Chem. Soc., Chem. Commun., 1981,1124-1125
17. [17]
  [17]Tamura M, Urano Y, Kikuchi K, et al. Chem. Pharm. Bull., 2000,48:1514-1518
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
7. [7]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
8. [8]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
9. [9]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
10. [10]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
11. [11]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
14. [14]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
17. [17]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
18. [18]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(185)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with1, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane