Citation: QIU Wen-Ge, DENG Fang, LIU Hu-Bing, ZI Xue-Hong, ZHANG Gui-Zhen, HE Hong, LI Jian-Rong. A sqc422-Type Coordination Polymer Based on Flexible Tetracarboxylate and 4,4'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2021-2026. doi: 10.3969/j.issn.1001-4861.2013.00.335 shu

A sqc422-Type Coordination Polymer Based on Flexible Tetracarboxylate and 4,4'-Bipyridine Ligands

1.
Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Received Date: 4 January 2013
Available Online: 27 May 2013
Fund Project: 国家自然科学基金(No.21007002)资助项目。 (No.21007002)

By using hydrothermal method, a cobalt complex, namely, [Co₂(L)(Bipy)₂]_n, (1), was synthesized based on flexible 1,3-bis[3,5-(dicarboxylate)phenoxy]-2-hydroxypropane(H4L) and 4,4'-bipyridine(Bipy). The complex 1 was characterized by infra-red spectrum (IR), UV-Vis spectrum, thermo-gravimetric analysis (TGA), single crystal X-ray diffraction, powder X-ray diffraction and elemental analysis. Complex 1 crystalizes in monoclinic system, space group C2/c. In complex 1, two six-coordinated cobalt atoms were connected by two bidentate carboxylic groups, forming an octahedral dimetallic cluster, which can be considered as a 6-connected node to connect four L ligand molecules and two other dimetallic clusters. The flexible tetracarboxylate ligand L can be considered as a tetrahedral 4-connected node to connect four dimetallic clusters. The two parallel Bipy molecules bridging two dimetallic clusters are transformed into edge during simplification. Thus, the framework of 1 features a sqc422 net. CCDC: 947285.
- 1,3-bis[3,5-(dicarboxylate)phenoxy]-2-hydroxypropane; 4,4'-bipyridine; cobalt complex; metal-organic frameworks; sqc422 net; π-π stacking interaction
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沈阳化工大学材料科学与工程学院沈阳 110142