Citation: WANG Kai, JI Bing-Cheng, HAN Mei-Jia, LI Li-Wei. Preparation of Nitrogen-Doped Graphene with Solid Microwave Method[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2105-2109. doi: 10.3969/j.issn.1001-4861.2013.00.328 shu

Preparation of Nitrogen-Doped Graphene with Solid Microwave Method

1.
1 School of Automation Engineering, Qingdao University, Qingdao, Shandong 266071, China;

Received Date: 13 March 2013
Available Online: 19 May 2013
Fund Project: 国家863高科技项目(No.2012AA110407) (No.2012AA110407)山东省科技发展计划(No.2011GGB01123)资助项目 (No.2011GGB01123)

Graphite oxide was synthesized via Hummers method with flake graphite as raw material. After centrifugation and washing to clean out the remnant slat, ethylenediamine (EDA) was added into the dispersion to react with graphene oxides giving rise to functional graphene sheets (FGS). The dried FGScan interact with microwaves strongly, producing superheating which results in decomposing the grafted EDAmolecules and in-situ doping graphene sheets. The morphology, structure, and components of the as-produced graphene were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), energy dispersion spectrum (EDS). The results showed that nitrogen-doped graphene sheets (NGS) can be successfully synthesized via this strategy. The synthesized nitrogen-doped graphene was transparent.
- graphene; nitrogen-doped; solid microwave
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沈阳化工大学材料科学与工程学院沈阳 110142