Citation: LIU Jian, WEI Zhen-Hong, ZHONG Wei, LIU Wen-Ming, LIU Xiao, LIU Xiao-Ming. Iron(Ⅱ) on Functionalised Micro/Nano Silica Gel: Surface Coordination Chemistry and Catalytic Performance for Degradation of 1,2-Dihydroxybenzene[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2205-2214. doi: 10.3969/j.issn.1001-4861.2013.00.327 shu

Iron(Ⅱ) on Functionalised Micro/Nano Silica Gel: Surface Coordination Chemistry and Catalytic Performance for Degradation of 1,2-Dihydroxybenzene

1.
1 Department of Chemistry, Nanchang University, Nanchang 330031, China;

Received Date: 24 April 2013
Available Online: 24 May 2013
Fund Project: 国家自然科学基金(No.20871064,21171073)资助项目 (No.20871064,21171073)

Micro/nano silica gel was functionalised with pyridinylthioether moiety. Two functionalised materials, Fe^C@L-NSiGand Fe^S@L-NSiG, were obtained by the coordination of the surface organic molecules with iron (Ⅱ) using FeCl₂ and FeSO₄ as the precursor, respectively. Both materials were characterised using FTIRand UV-Vis spectroscopies, TGAand SEMtechniques. Possible coordination chemistry of the iron(Ⅱ) on the surface functionalised materials and the catalytic performance of the title materials on the catalytic degradation of 1,2-dihydroxybenzene (catechol) by hydrogen peroxide were investigated. Aligand L, 2-(ethylthiomethyl)pyridine with “NS” donor set analogous to the organic functional group immobilised on the surface micro/nano silica gel, was synthesised for the study of the coordination chemistry around the iron (Ⅱ) centre of the two materials. The control complex, [Fe(L)₂Cl₂], used in the investigation was obtained by the reaction of the ligand Lwith FeCl₂. The structure of the complex was determined by using X-ray single crystal diffraction analysis. The results suggest that the material Fe^S@L-NSiGshows higher catalytic efficiency by about one-fold than that of Fe^C@L-NSiG. This better catalytic efficiency is because that the Fe^S@L-NSiGhas more labile ligand(s) around the metal centre compared to its analogue (Fe^C@L-NSiG) and hence makes the substrate easier accessed upon binding to the metal centre. CCDC: 866526.
- heterogeneous catalysis; functionalised micro/nano silica gel; iron(Ⅱ) complex; organic-inorganic hybrid composites; catechol degradation
1. [1]
  [1] Costas M, Mehn M P, Jensen M P, et al. Chem. Rev., 2004, 104(2):939-986 [2] Bugg T D H, Winfield C J. Nat. Prod. Rep., 1998,15(5):513- 530 [3] Bugg T D H, Lin G. Chem. Commun., 2001:941-952 [4] Que L, Ho R Y N. Chem. Rev., 1996,96(7):2607-2624 [5] Maldotti A, Molinari A, Varani G, et al. J. Catal., 2002,209 (1):210-216 [6] Marion R, Muthusamy G, Geneste F. J. Catal., 2012,286:266 -272 [7] Zhou H, Wang Y M, Zhang W Z, et al. Green Chem., 2011, 13(3):644-650 [8] Alvaro M, Baleizao C, Carbonell E, et al. Tetrahedron, 2005, 61(51):12131-12139 [9] Motokura K, Itagaki S, Iwasawa Y, et al. Green Chem., 2009, 11(11):1876-1880 [10]Park D W, Yu B S, Jeong E S, et al. Catal. Today, 2004,98 (4):499-504 [11]Sun D, Zhai H, Catal. Commun., 2007,8(7):1027-1030 [12]Xiao L F, Li F W, Xia C G. Appl. Catal. A-Gen., 2005,279 (1-2):125-129 [13]Huang S S, Fan Y, Cheng Z Y, et al. J. Phys. Chem. C, 2009,113(5):1775-1784 [14]Klichko Y, Liong M, Choi E, et al. J. Amer. Cer. Soc., 2009,92(1):S2-S10 [15]Burns A, Ow H, Wiesner U. Chem. Soc. Rev., 2006,35(11): 1028-1042 [16]Yao G, Wang L, Wu Y R, et al. Anal. Bioanal. Chem., 2006,385(3):518-524 [17]Arguello J, Leidens V L, Magosso H A, et al. Electrochim. Acta, 2008,54(2):560-565 [18]Boddi K, Takatsy A, Szabo S, et al. J. Sep. Sci., 2009,32(2): 295-308 [19]Peng Y, Li Z M, Zeng Y B, et al. Microchim. Acta, 2010, 170(1-2):17-26 [20]Hlatky G G. Chem. Rev., 2000,100(4):1347-1376 [21]Li K T, Dai C L, Kuo C W. Catal. Commun., 2007,8(8):1209- 1213 [22]Jin Y H, Li A Z, Hazelton S G, et al. Coord. Chem. Rev., 2009,253(23-24):2998-3014 [23]Bigi F, Moroni L, Maggi R, et al. Chem. Commun., 2002: 716-717 [24]Heravi M M, Sadjadi S, Oskooie H A, et al. Ultrason. Sonochem., 2009,16(6):718-720 [25]Ijuin R, Umezawa N, Higuchi T. Bioorgan. Med. Chem., 2006,14(10):3563-3570 [26]Sheldrick G. Acta Crystallogr. Sect. A, 2008,64:112-122 [27]Reisner E, Abikoff T C, Lippard S J. Inorg. Chem., 2007,46 (24):10229-10240 [28]van Bommel K J C, de Jong M R, Metselaar G A, et al. Chem. Eur. J., 2001,7(16):3603-3615 [29]Canovese L, Visentin F, Uguagliati P, et al. Inorg. Chim. Acta, 1998,275-276:385-394 [30]Remuzon P, Bouzard D, Dicesare P, et al. Tetrahedron, 1995,51(35):9657-9670 [31]Patra A, Sarkar S, Drew M G B, et al. Polyhedron, 2009,28 (7):1261-1264
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沈阳化工大学材料科学与工程学院沈阳 110142